PCN-250(Fe)金属有机骨架

配位金属	Fe
配体	3,3’,5,5’-azobenzenetetracarboxylic（CAS：365549-33-3）
孔径	1nm
孔容	0.5cm3/g
比表面	BET比表面1200-1400m2/g

PCN-250在空气中稳定，在水溶液和弱碱性条件下较稳定；热分解温度大于300℃ 气体（如二氧化碳）和污染物吸附 [1] Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks. https://doi.org/10.1038/ncomms6723
[2] Iron(iii) metal–organic frameworks as solid Lewis acids for the isomerization of α-pinene oxide. https://doi.org/10.1039/C2CY00376G
[3] Maintaining the configuration of a light-responsive metal-organic framework: LiYGeO₄:Bi³⁺-incorporation-induced long-term bending through short-time light irradiation. https://doi.org/10.1039/d3ta01241g
[4] Iron-Based Metal-Organic Frameworks (MOF) as Photocatalysts for Radical and Cationic Polymerizations under Near UV and Visible LEDs (385–405 nm). https://doi.org/10.1002/macp.201600352
[5] Water-Based Synthesis of a Stable Iron-Based Metal−Organic Framework for Capturing Toxic Gases. https://doi.org/10.1021/acsmaterialslett.0c00264