(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
- Product Name(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
- CAS135616-40-9
- MFC36H54N2O2
- MW546.84
- EINECS
- MOL File135616-40-9.mol
Chemical Properties
| Melting point | 205-207 °C(lit.) |
| alpha | -315° (c 1, CH2Cl2) |
| Boiling point | 619.74°C (rough estimate) |
| Density | 1.0110 (rough estimate) |
| refractive index | 1.5300 (estimate) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform (Slightly), Dichloromethane (Slightly) |
| pka | 13.06±0.40(Predicted) |
| form | Powder |
| color | Yellow |
| optical activity | [α]20/D 315±15°, c = 1 in methylene chloride |
| λmax | 328nm(CH3CN)(lit.) |
| BRN | 5464823 |
| InChIKey | FYNXDGNCEBQLGC-LQWPWIHBSA-N |
| SMILES | C(C1C=C(C(C)(C)C)C=C(/C=N/[C@@H]2CCCC[C@H]2/N=C/C2C=C(C(C)(C)C)C=C(C(C)(C)C)C=2O)C=1O)(C)(C)C |&1:12,17,r| |
Safety Information
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
| HS Code | 29222900 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
2. Enantioselective conjugate cyanation of unsaturated imides.
3. Cobalt catalyzed enantioselective alpha chlorination and fluorination of beta-ketoesters.
