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1-METHYL-1-CYCLOHEXENE Structure

1-METHYL-1-CYCLOHEXENE

Chemical Properties

Melting point -119.4°C
Boiling point 110-111 °C (lit.)
Density  0.811 g/mL at 20 °C (lit.)
vapor pressure  27.4 at 20.2 °C, 36.4 at 25.0 °C (transpiration method, Verevkin et al., 2000)
refractive index  n20/D 1.45(lit.)
Flash point 25 °F
storage temp.  Sealed in dry,Room Temperature
solubility  Soluble in benzene and ether (Weast, 1986) and miscible with many hydrocarbons similar in chemical structure, e.g., cyclohexane, cyclohexene, etc.
form  Liquid
color  Clear colorless
Odor at 1.00 % in dipropylene glycol. lime citrus
Odor Type citrus
Water Solubility  52 mg/kg at 25 °C (shake flask-GC, McAuliffe, 1966)
BRN  1304483
Henry's Law Constant 8.86 x 10-2 atm?m3/mol at 25 °C (approximate - calculated from water solubility and vapor pressure)
Stability Stable, but may be prone to polymerization. May be stabilized by the addition of around 10 ppm hydroquinone. Highly flammable. Incompatible with strong oxidizing agents.
InChIKey CTMHWPIWNRWQEG-UHFFFAOYSA-N
LogP 3.333 (est)
CAS DataBase Reference 591-49-1(CAS DataBase Reference)
EPA Substance Registry System Cyclohexene, 1-methyl- (591-49-1)

Safety Information

Hazard Codes  F,Xn,Xi
Risk Statements  11-36/37/38-65
Safety Statements  16-26-36-62
RIDADR  UN 3295 3/PG 2
WGK Germany  2
Hazard Note  Irritant
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29021900

MSDS

Usage And Synthesis

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