ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Other esters 2-Phenoxyethyl Acrylate

2-Phenoxyethyl Acrylate

Product Name2-Phenoxyethyl Acrylate
CAS48145-04-6
MFC11H12O3
MW192.21
EINECS256-360-6
MOL File48145-04-6.mol

Chemical Properties

Melting point	-74 °C
Boiling point	84 °C/0.2 mmHg (lit.)
Density	1.11
vapor pressure	0.25Pa at 25℃
refractive index	1.52
Flash point	141 °C
storage temp.	2-8°C
solubility	Practically insoluble in water
form	clear liquid
color	Colorless to Almost colorless
Water Solubility	525mg/L at 25℃
BRN	2102773
Cosmetics Ingredients Functions	NAIL CONDITIONING
InChI	1S/C11H12O3/c1-2-11(12)14-9-8-13-10-6-4-3-5-7-10/h2-7H,1,8-9H2
InChIKey	RZVINYQDSSQUKO-UHFFFAOYSA-N
SMILES	C=CC(=O)OCCOc1ccccc1
LogP	2.58 at 25℃
CAS DataBase Reference	48145-04-6(CAS DataBase Reference)
EPA Substance Registry System	2-Phenoxyethyl acrylate (48145-04-6)

Safety Information

Hazard Codes	Xi,N
Risk Statements	36/37/38-51/53
Safety Statements	26-28-61
RIDADR	UN 3082 9 / PGIII
WGK Germany	2
RTECS	KM0700000
TSCA	TSCA listed
HazardClass	9
PackingGroup	III
HS Code	2916129000
Storage Class	10 - Combustible liquids
Hazard Classifications	Aquatic Chronic 2 Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

MSDS

Provider	Language
SigmaAldrich	English
ALFA	English

Usage And Synthesis

Description

2-Phenoxyethyl acrylate is a nonflammable, low-volatility liquid with moderate solubility in water. 2-Phenoxyethyl acrylate is a monofunctional acrylic monomer that free radicals can polymerize. In particular, this compound is designed for ultraviolet and electron beam curing applications and used in U.V &E.B cured coatings, inks, and adhesives.

Uses

Ethylene glycol phenyl ether acrylate (PA) monomer may be used to fabricate polymerization induced grating pattern on photopolymer films.

Uses

2-Phenoxyethyl Acrylate is used as a monomer in multifunctional and shape memory polymers.

General Description

Ethylene glycol phenyl ether acrylate (PA) is a monofunctional acrylate.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by skin contact. Mdly toxic by ingestion. A skin irritant. A combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes

Synthesis

1) Measured phenol, ring-opening polymerization catalyst into the stainless steel high-pressure reactor, vacuum, heating to the appropriate reaction temperature, dropwise addition of ethylene oxide, temperature control reaction to the completion of the dropwise addition of ethylene oxide, and then held until the end of the reaction, cooling out of the material, to get the 2-phenoxyethanol intermediate.

2) The 2-phenoxyethanol intermediate was added to the homemade vacuum distillation device for vacuum distillation, and 2-phenoxyethanol was obtained by component separation.

3) The measured 2-phenoxyethanol, acrylic acid, p-toluenesulfonic acid, copper chloride dihydrate, p-hydroxyanisole, and cyclohexane were added to a four-necked flask consisting of a force-increasing electric mixer, a 2000 mL Four-necked flask, temperature-regulated heating jacket, water separator, condenser and other components of the esterification water splitting device for esterification reaction, the crude ester, and then the crude ester were used with a 5% aqueous solution of soda ash, respectively. 5% aqueous soda ash solution, water for neutralization and washing, after removing cyclohexane and water to get 2-phenoxyethyl acrylate.