(1-BROMOVINYL)TRIMETHYLSILANE

Safety Information

Symbol(GHS)

Signal word

Danger

Hazard statements

H225：Highly Flammable liquid and vapour

Precautionary statements

P210：Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

Description

Numerous nucleophiles react with (1-bromovinyl)trimethylsilane in the presence of palladium complexes. The bromine has been substituted by phenylthio,vinyl,and aryl groups. This approach gives reasonable yields of the desired products. However, the substitution reactions sometimes lack regiospecificity. For example, a mixture of regioisomers was obtained in eq 6. Two mechanisms have been proposed for the formation of the β-substituted product. One involves an elimination step to give trimethylsilylacetylene as an intermediate, which then undergoes catalyzed additions with the nucleophile at either the α- or β-positions.The other mechanism involves the formation of a pentacoordinated palladium intermediate, leading to the formation of isomeric products.

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Suppliers and manufacturers

• career henan chemical co
  

  $9.80/1.79999995231628KG

  (1-BROMOVINYL)TRIMETHYLSILANE

  CAS:13683-41-5
• Shanghai Daken Advanced Materials Co.,Ltd
• ATK CHEMICAL COMPANY LIMITED
• Win-Win Chemical CO., Limited
• Alchem Pharmtech,Inc.
• Antai Fine Chemical Technology Co.,Limited
• Neostar United (Changzhou) Industrial Co., Ltd.
• Hefei TNJ Chemical Industry Co.,Ltd.
• Win-Win chemical CO., Limited
• HANGZHOU CLAP TECHNOLOGY CO.,LTD

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