시스-1,3-디클로로-1-프로펜

한글명:시스-1,3-디클로로-1-프로펜

카스 번호10061-01-5

상품명:CIS-1,3-DICHLOROPROPENE

CBNumberCB9680157

분자식C3H4Cl2

포뮬러 무게110.97

MOL 파일10061-01-5.mol

동의어(한글)

시스-1,3-디클로로-1-프로펜

시스-1,3-디클로로-1-프로펜(CIS-1,3-DICHLORO-1-PROPENE)

CIS-1,3-디클로로프로펜

화학적 성질

녹는점	-50 °C
끓는 점	104 °C(lit.)
밀도	1.225 g/mL at 25 °C(lit.)
증기압	111.6 at 50 °C, 687.8 at 100 °C (Wilding et al., 2002)
굴절률	n20/D 1.4675(lit.)
인화점	75 °F
저장 조건	0-6°C
용해도	클로로포름, 메탄올(약간)에 용해됨
물리적 상태	기름
색상	무색
수용성	1.071g/L(30℃)
Merck	14,3075
Henry's Law Constant	1.23 x 10^-3 atm?m³/molat 20 °C, 2.77 at 40 °C (static headspace-GC, Kim et al., 2003)
노출 한도	ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted).
안정성	안정적인. 가연성. 강력한 산화제, 알루미늄 및 그 합금, 활성 금속, 할로겐, 일부 금속염과 호환되지 않습니다. 빛에 민감할 수 있습니다.
LogP	1.82 at 20℃ and pH5.83-7.78
표면장력	69.6mN/m at 976.8mg/L and 20.2℃
CAS 데이터베이스	10061-01-5(CAS DataBase Reference)
NIST	1-Propene, 1,3-dichloro-, (Z)-(10061-01-5)
EPA	cis-1,3-Dichloropropene (10061-01-5)

위험 및 안전 성명

위험품 표기	T,N,F
위험 카페고리 넘버	10-20/21-25-36/37/38-43-50/53-52/53-39/23/24/25-23/24/25-11-65-24/25-20
안전지침서	36/37-45-60-61-16-7
유엔번호(UN No.)	UN 2047 3/PG 2
WGK 독일	3
RTECS 번호	UC8325000
위험 등급	3.2
포장분류	III
유해 물질 데이터	10061-01-5(Hazardous Substances Data)
독성	LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats is 713 and 470 mg/kg, respectively (Verschueren, 1983).

그림문자(GHS)

시스-1,3-디클로로-1-프로펜 화학적 특성, 용도, 생산

화학적 성질
colourless to amber liquid
물리적 성질
Clear, colorless to amber-colored liquid with a pungent and irritating, chloroform-like odor. Evaporates quickly when spilled. The average least detectable odor threshold concentration in water at 60 °C for mixed isomers of 1,3-dichloropropylene was 0.12 mg/L (Alexander et al., 1982).
용도
The isomeric mixture is used as a soil fumigant and a nematocide.
정의
ChEBI: The (Z)-isomer of 1,3-dichloropropene.
일반 설명
Colorless to amber liquid with a sweetish odor.
공기와 물의 반응
Highly flammable. Insoluble in water.
반응 프로필
CIS-1,3-DICHLOROPROPENE may be sensitive to light. Reacts with aluminum, aluminum alloys, other active metals and some metal salts and halogens. Can react vigorously with oxidizing materials.
화재위험
Flash point data for CIS-1,3-DICHLOROPROPENE are not available, however literature sources indicate that CIS-1,3-DICHLOROPROPENE is flammable.
Safety Profile
Confirmed carcinogen with experimental neoplastigenic data. Human mutation data reported. A dangerous fire hazard when exposed to heat, flame, or oxidzers. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS , ALIPHATIC .
잠재적 노출
Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.
환경귀착
Biological. cis-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen- 1-ol and can be biologically oxidized to 3-chloropropenoic acid, which is further oxidized to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors et al., 1990). The isomeric mixture showed significant degradation with gradual adaptation in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to volatilization (Tabak et al., 1981).
Soil. Hydrolyzes in wet soil forming cis-3-chloroallyl alcohol (Castro and Belser, 1966).
Chemical/Physical. Hydrolyzes in distilled water at 25°C forming 2-chloro-3-propenol and hydrochloric acid. The half-life was 1 day (Milano et al., 1988; Kollig, 1993). Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation of dichloropropylene at about 23°C and 730 mmHg. Chloroacetaldehyde and formyl chloride also formed from the reaction of dichloropropylene with hydroxyl radicals (Tuazon et al., 1984).
The evaporation half-life of cis-1,3-dichloropropylene (1 mg/L) from water at 25°C using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 29.6 minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic phosgene (Sittig, 1985).
운송 방법
UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.
비 호환성
Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.
폐기물 처리
Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

시스-1,3-디클로로-1-프로펜 준비 용품 및 원자재

시스-1,3-디클로로-1-프로펜 공급 업체

시스-1,3-디클로로-1-프로펜 관련 검색

Send Inquriy