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그림문자(GHS)

• 그림문자(GHS)

  

• 신호 어

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• 유해·위험 문구

  H228：인화성 고체

  H315：피부에 자극을 일으킴

  H319：눈에 심한 자극을 일으킴

  H332：흡입하면 유해함

  H335：호흡 자극성을 일으킬 수 있음

  H373：장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음

  H413：장기적 영향에 의해 수생생물에 유해의 우려가 있음

• 예방조치문구

  P210：열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.

  P240：용기와 수용설비를 접지 및 접합시키시오.

  P241：폭발 방지용 장비[전기적/환기/조명/...]을(를) 사용하시오.

  P260：분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.

  P261：분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.

  P280：보호장갑/보호의/보안경/안면보호구를 착용하시오.

  P304+P340：흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.

  P305+P351+P338：눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

  P314：불편함을 느끼면 의학적인 조치·조언을 구하시오.

  P403+P233：용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.

  P405：밀봉하여 저장하시오.

로듐 화학적 특성, 용도, 생산

• 개요

  Rhodium is one of the platinum group elements, and is found at very low concentrations in the Earths crust. Rhodium was discovered by William Hyde Wollaston (England) in 1804. The origin of the name comes from the Greek word rhodon, meaning rose. The plated solid is very corrosion resistant and exceptionally hard. While inert in air and acids, it can produce a violent reaction to chlorine, bromine pentafluoride, bromine trifluoride, and fluorine monoxide.

• 화학적 성질

  Rhodium, together with platinum, palladium, iridium, ruthenium, and osmium, is one of the platinum-group metals in Group VIII of the Periodic Table. Rhodium metal is a white, hard, ductile, malleable solid with a bluish-gray luster. soluble in ether, alcohol, and water. The alloys of rhodium can also be used in high temperature conditions (i.e., thermocouples and crucibles). It also can be used in electroplating glass products due to its reflective properties.
  

• 물리적 성질

  Rhodium is a hard shiny-white metal that resists corrosion from oxygen, moisture, andacids at room temperatures. As a member of group 8 (VIII), ₄₅Rh shares many chemical andphysical properties with cobalt (₂₇Co) just above it and iridium (₇₇Ir) below it in the verticalgroup. Therefore, it is considered one of the elements that are transitory between metals andnonmetals. It is rare and only found in combination with platinum ores.
  Rhodium’s melting point is 1,966°C, its boiling point is 3,727°C, and its density is 12.41g/cm³.

• Isotopes

  There are 52 isotopes of rhodium, ranging from Rh-89 to Rh-122. All are producedartificially with relatively short half-lives except one stable isotope, Rh-103, whichconstitutes 100% of the element’s existence in the Earth’s crust.

• Origin of Name

  Named after the Greek word rhodon, which means “rose,” because of the reddish color of its salt compounds.

• 출처

  Rhodium is rare, but not as rare as ruthenium. It makes up only 1 part in 20 million of theelements found in the Earth’s crust. Even so, it is considered the 79th most abundant elementand is found mixed with platinum ore, and to a lesser extent, it is found with copper andnickel ores. It is found in Siberia, South Africa, and Ontario, Canada.
  Rhodium is recovered from platinum and other ores by refining and purification processesthat start by dissolving the other platinum group metals and related impurities with strongacids that do not affect the rhodium itself. Any remaining platinum group elements areremoved by oxidation and bathing the mixture in chlorine and ammonia.
  Rhodium is usually produced as a powder and can be formed by either casting or powdermetallurgy.

• Characteristics

  Rhodium is one of the six platinum transition elements that include Ru, Rh, Pd, Os, Ir, andPt. Of these metals, rhodium has the highest electrical and thermal conductivity. Although arelatively scarce metal, rhodium makes an excellent electroplated surface that is hard, wearswell, and is permanently bright—ideal for plating the reflectors in automobile headlights.

• 역사

  Wollaston discovered rhodium in 1803-4 in crude platinum ore he presumably obtained from South America. Rhodium occurs native with other platinum metals in river sands of the Urals and in North and South America. It is also found with other platinum metals in the copper-nickel sulfide ores of the Sudbury, Ontario region. Although the quantity occurring here is very small, the large tonnages of nickel processed make the recovery commercially feasible. The annual world production of rhodium in 1999 was only about 9000 kg. The metal is silvery white and at red heat slowly changes in air to the sesquioxide. At higher temperatures it converts back to the element. Rhodium has a higher melting point and lower density than platinum. Its major use is as an alloying agent to harden platinum and palladium. Such alloys are used for furnace windings, thermocouple elements, bushings for glass fiber production, electrodes for aircraft spark plugs, and laboratory crucibles. It is useful as an electrical contact material as it has a low electrical resistance, a low and stable contact resistance, and is highly resistant to corrosion. Plated rhodium, produced by electroplating or evaporation, is exceptionally hard and is used for optical instruments. It has a high reflectance and is hard and durable. Rhodium is also used for jewelry, for decoration, and as a catalyst. Fifty-two and isomers are now known. Rhodium metal (powder) costs about $180/g (99.9%).isotopes

• 용도

  Rhodium is a transition metal catalyst used in a multitude of inorganic synthesis.

• 생산 방법

  Pure rhodium is prepared by the reduction of its ammonium salt (dichloropentaaminorhodium).

• 정의

  A rare silvery hard transition metal. It is difficult to work and highly resistant to corrosion. Rhodium occurs native but most is obtained from copper and nickel ores. It is used in protective finishes, alloys, and as a catalyst. Symbol: Rh; m.p. 1966°C; b.p. 3730°C; r.d. 12.41 (20°C); p.n. 45; r.a.m. 102.90550.

• 일반 설명

  This product has been enhanced for energy efficiency.

• 위험도

  The powder and dust of rhodium metal are flammable in air. Some of the compounds maycause skin irritations. It is best to use approved laboratory procedures when handling any ofthe six elements in the platinum family of metals.

• 건강위험

  There are no data demonstrating acute or chronic rhodium-related diseases; irritation and sensitization have occasionally been reported in humans from exposure to the salts of rhodium. Solutions of insoluble salts splashed in the eye may cause mild irritation.

• 공업 용도

  Metallic rhodium is the whitest of the platinum metals and does not tarnish under atmospheric conditions. It is insoluble in most acids, including aqua regia, but is attacked by chlorine at elevated temperatures and by hot fuming sulfuric acid. Liquid rhodium dissolves oxygen, and ingots are made by argon-arc melting. At temperatures above 1200 C, rhodium reacts with oxygen to form rhodium oxide, Rh2O3. Rhodium is used to make the nibs of writing pens, to make resistance windings in high-temperature furnaces, for high-temperature thermocouples, as a catalyst, and for laboratory dishes. It is the hardest of the platinum-group metals; the annealed metal has a Brinell hardness of 135. Rhodium is also valued for electroplating jewelry, electric contacts, hospital and surgical instruments, and especially reflectors.
  The most important alloys of rhodium are rhodium platinum. They form solid solutions in any proportion, but alloys of more than 40% rhodium are rare. Rhodium is not a potent hardener of platinum but increases its high-temperature strength. It is easily workable and does not tarnish or oxidize at high temperatures. These alloys are used for thermocouples and in the glass industry.

• Safety Profile

  Handle carefully. It may be a sensitizer but not to the same extent as platinum. Most rholum compounds have only moderate toxicity by ingestion. Flammable when exposed to heat or flame. Violent reaction with chlorine, bromine pentafluoride, bromine trifluoride, and OF2. A catalytic metal

• 잠재적 노출

  Rhodium has few applications by itself, as in rhodium plating of white gold jewelry or plat- ing of electrical parts, such as commutator slip rings, but, mainly, rhodium is used as a component of platinum alloys. Rhodium-containing catalysts have been proposed for use in automotive catalytic converters for exhaust gas cleanup.

• Carcinogenicity

  Chick embryos exposed to rhodium on the eighth day of incubation were stunted; mild reduction of limb size and feather growth inhibition were also observed. A number of rhodium compounds have tested positive in bacterial assays for genetic altering capability.

• 환경귀착

  The most common route by which rhodium enters the environment is as a component of automobile exhaust resulting from use of catalytic converters. Rhodium is insoluble in water and all acids, with the exception that very finely separated material may be dissolved in concentrated sulfuric acid and aqua regia.
  Being largely inert, rhodium can undergo long-range transport, and particulate phase matter generally leaves the atmosphere by wet or dry deposition. In an aqueous environment, rhodium can form complexes with halide and nitrogen donor ligands, which may be water soluble, but reactions can be dictated by pH, redox potential, and what material is available for creating ligands. Reactions in soil can depend on these same factors, as well as chloride concentrations, and rhodium is seen to be mobile only in highly acidic soils.
  Rhodium has been seen to bioaccumulate in both fresh and salt water species, and has the potential to biomagnify.

• 운송 방법

  Flammable powder, Hazard Class: 4.1; Labels: 4.1-Flammable solid.

• 비 호환성

  Flammable as a dust, fume, or powder may form explosive mixture with air. Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanga- nates, perchlorates, chlorine, bromine, fluorine, etc.); con- tact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, bromine pentafluoride, and bromine trifluoride; chlorine trifluoride; oxygen difluoride.

• 폐기물 처리

  Recovery in view of the high economic value. Recovery techniques for recycling of rhodium in plating wastes and spent catalysts have been described in the literature.

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