3-(3,5-다이클로로페닐)-5-에텐일-5-메틸-2,4-옥사졸리딘다이온

한글명:3-(3,5-다이클로로페닐)-5-에텐일-5-메틸-2,4-옥사졸리딘다이온

카스 번호50471-44-8

상품명:VINCLOZOLIN

CBNumberCB8108814

분자식C12H9Cl2NO3

포뮬러 무게286.11

MOL 파일50471-44-8.mol

동의어(한글)

3-(3,5-다이클로로페닐)-5-에텐일-5-메틸-2,4-옥사졸리딘다이온

빈클로졸린

화학적 성질

녹는점	108℃
끓는 점	131℃ (0.05mmHg)
밀도	1.51 g/cm³
증기압	1.3 x 10^-4 Pa (20 °C)
굴절률	1.6100 (estimate)
인화점	2 °C
저장 조건	APPROX 4°C
용해도	DMF: 30 mg/ml,DMSO: 30 mg/ml,Ethanol: 30 mg/ml,Ethanol:PBS(pH 7.2) (1:1): 0.5 mg/ml
수용성	3.4mg l^-1(20°C)
산도 계수 (pKa)	-3.43±0.40(Predicted)
Merck	13,10046
BRN	8331312
EPA	Vinclozolin (50471-44-8)

위험 및 안전 성명

위험품 표기	T,N,Xn,F
위험 카페고리 넘버	60-61-40-43-51/53-36-20/21/22-11
안전지침서	53-45-61-36-26-16-36/37
유엔번호(UN No.)	UN3077 9/PG 3
WGK 독일	3
RTECS 번호	RP8530000
HS 번호	29349990
유해 물질 데이터	50471-44-8(Hazardous Substances Data)
독성	LD50 orally in rats: 10 g/kg (Hess, Locher)

그림문자(GHS)

3-(3,5-다이클로로페닐)-5-에텐일-5-메틸-2,4-옥사졸리딘다이온 화학적 특성, 용도, 생산

용도
Vinclozolin is a non-systemic, contact fungicide that controls fruit rot, brown rot, mould and blight caused by Botrytis spp., Sclerotinia spp., Monilia spp., etc. in vines, fruits, vegetables, oilseed rape, ornamentals, hops, turf and strawberries. Vinclozolin exhibits both preventive and curative activities.
일반 설명
Colorless crystals with slight aromatic odor. Used as a fungicide.
공기와 물의 반응
Hydrolysis rapidly occurs under alkaline conditions
반응 프로필
A halogenated dicarboximide. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
농업용
Fungicide: Vinclozolin is a non-systemic fungicide which has been used on vines (such as grapes), strawberries, raspberries, chicory grown for Belgian endive, lettuce, kiwi, canola, succulent beans, and dry bulb onions. Import tolerances have been established to permit. Not approved for use in EU countries . Registered for use in the U.S.
상품명
BAS-352-F®; BAS-35204-F®; CURALAN®; FLOTILLA®; FUMITE RONALIN®; MASCOT® contact turf fungicide; ORNALIN®[C]; POWERDRIVE®; RONILAN®; RONILAN-DF®; RONALINE-FL®; TOUCHE®; VINCHLOZOLINE®; VINCLOZOLINE®; VORLAND®
Safety Profile
Low toxicity by ingestion and inhalation. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cland NOx.
신진 대사 경로
The fungicides, chlozolinate, vinclozolin, and procymidone, are added to wine after fermentation and the degradation products are isolated and identified. Chlozolinate undergoes a rapid hydrolytic loss of the ethoxycarbonyl substituent to give an oxazolidine that further undergoes hydrolytic cleavage to give 3' ,5' -dichloro-2-hydroxypropanilide. The oxazolidine ring of vinclozolin undergoes a similar hydrolysis reaction to give the corresponding anilide, 3' ,5'-dichloro-2-hydroxy-2-methylbut-3-eneanilide. Both of these anilides are stable in wine for 150 days. A different degradation behavior is observed with procymidone and leads to the formation of 3,5- dichloroaniline, which, in turn, breaks down in wine.
Purification Methods
Crystallise the fungicide from Me2CO/H2O. Its solubility at 20o (w/w%) is 44 (Me2CO), 32 (CHCl3), 25 (EtOAc) and 10 (H2O). It irritates the eyes and skin. [GP 2,207,576 1973, Chem Abstr 79 137120 1973.]

3-(3,5-다이클로로페닐)-5-에텐일-5-메틸-2,4-옥사졸리딘다이온 준비 용품 및 원자재

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