클로르프로팜

한글명:클로르프로팜

카스 번호101-21-3

상품명:Chlorpropham

CBNumberCB3136324

분자식C10H12ClNO2

포뮬러 무게213.66

MOL 파일101-21-3.mol

동의어(한글)

클로프로팜

클로르프로팜

화학적 성질

녹는점	41°C
끓는 점	247°C
밀도	1.18
굴절률	nD20 1.5388
인화점	247°C
저장 조건	2-8°C
용해도	클로로포름(약간 용해됨), 메탄올(약간 용해됨)
물리적 상태	수정 같은
산도 계수 (pKa)	13.06±0.70(Predicted)
색상	베이지색
냄새	희미한 숯. 냄새
수용성	0.009g/100ml 매우 나쁨
분해온도	247 ºC
Merck	14,2187
BRN	2211397
노출 한도	An experimental carcinogen and neoplastigen
안정성	안정적인. 강산, 강염기, 강산화제와 호환되지 않습니다.
CAS 데이터베이스	101-21-3(CAS DataBase Reference)
IARC	3 (Vol. 12, Sup 7) 1987
NIST	Chlorpropham(101-21-3)
EPA	Chlorpropham (101-21-3)

위험 및 안전 성명

위험품 표기

Xn,N,F

위험 카페고리 넘버

22-51/53-36-20/21/22-11

안전지침서

61-36/37-26-16

유엔번호(UN No.)

UN 3077 9/PG 3

WGK 독일

RTECS 번호

FD8050000

HS 번호

2924.29.4300

위험 등급

포장분류

III

유해 물질 데이터

101-21-3(Hazardous Substances Data)

독성

LD50 orally in rats: 1.2 g/kg (Boyd, Carsky)

NFPA 704:

	0
2		0

그림문자(GHS)

클로르프로팜 MSDS

클로르프로팜 화학적 특성, 용도, 생산

화학적 성질
beige to brown solid
용도
Chlorpropham is particularly useful in agricultural settings. It is used in pesticide products for treatment of plants and soil.
정의
ChEBI: A carbamate ester that is the isopropyl ester of 3-chlorophenylcarbamic acid.
일반 설명
Brown chunky solid.
공기와 물의 반응
Insoluble in water.
반응 프로필
Chlorpropham is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.
위험도
Toxic by ingestion.
화재위험
Flash point data for Chlorpropham are not available, however Chlorpropham is probably combustible.
농업용
Herbicide, Plant growth regulator: Chlorpropham is a plant growth regulator that is used primarily in the U.S. to inhibit post-harvest potato sprouting. Other uses include pre-emergence control of grass weeds in alfalfa, beans, blueberries, cane berries, carrots, cranberries, ladino clover, garlic, seed grass, onions, spinach, sugar beets, tomatoes, safflower, soybeans, gladioli and woody nursery stock. It is used to control suckers in tobacco
상품명
ATLAS® CIPC 40; BEET-KLEEN® (with Fenuron® and isopropyl carbanilate); BUDNIP®; CAMPBELL’S® CIPC 40%; CHLORO IPC®; ELBANIL®; FASCO® WY-HOE; FURLOE®; FURLOE® 4EC; JACK WILSON® CHLORO 51 (OIL); LIRO METOXON®; MIRVALE®; MORCRAN® (with n-1-naphthylphthalamic acid); MSS® CICP; NEXOVAL®; PREVENOL® 56; PREVENTOL®; PREVENTOL® 56; PREWEED®; RESIDUREN®; RESIDUREN® EXTRA; SPROUT NIP®; SPROUT-NIP® EC; SPUDNIC®; SPUD-NIE®; STOPGERME®-S; TATERPEX®; TRIPEC® (with carbamic acid, phenyl-, 1-methylethyl ester); TRIHERBICIDE® CIPC; UNICROP® CIPC; WAREFOG®; Y3®
환경귀착
Soil. Hydrolyzes in soil forming 3-chloroaniline (Bartha, 1971; Hartley and Kidd, 1987; Smith, 1988; Rajagopal et al., 1989). In soil, Pseudomonas striata Chester, a Flavobacterium sp., an Agrobacterium sp. and an Achromobacter sp. readily degraded chlorpropham to 3-chloroaniline and 2-propanol. Subsequent degradation by enzymatic hydrolysis yielded carbon dioxide, chloride ions and unidentified compounds (Kaufman, 1967; Rajagopal et al., 1989). Hydrolysis products that may form in soil and in microbial cultures include N-phenyl-3-chlorocarbamic acid, 3-chloroaniline, 2-amino-4-chlorophenol, monoisopropyl carbonate, 2-propanol, carbon dioxide and condensation products (Rajagopal et al., 1989). The reported half-lives in soil at 15 and 29°C are 65 and 30 days, respectively (Hartley and Kidd, 1987)
Plant. Chlorpropham is rapidly metabolized in plants (Ashton and Monaco, 1991). Metabolites identified in soybean plants include isopropyl-N-4-hydroxy-3-chlorophenylcarbamate, 1-hydroxy-2-propyl-3′-chlorocarbanilate and isopropyl-N-5-chloro-2-hy
Photolytic. The photodegradation rate of chlorpropham in aqueous solution was enhanced in the presence of a surfactant (TMN-10) (Tanaka et al., 1981). In a later study, Tanaka et al. (1985) studied the photolysis of chlorpropham (50 mg/L) in aque
Chemical/Physical. Emits toxic phosgene fumes when heated to decomposition (Sax and Lewis, 1987). In a 0.50 N sodium hydroxide solution at 20°C, chlorpropham was hydrolyzed to aniline derivatives. The half-life of this reaction was 3.5 days (El-Dib and Aly, 1976). Simple hydrolysis leads to the formation of 3-chlorophenylcarbamic acid and 2-propanol. The acid is very unstable and is spontaneously converted to 3-chloroaniline and carbon dioxide (Still and Herrett, 1976)

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