2-메틸-2-Adamantyl 메타아크릴레이트

한글명:2-메틸-2-Adamantyl 메타아크릴레이트

카스 번호177080-67-0

상품명:2-Methacryloyloxy-2-methyladamantane

CBNumberCB31483683

분자식C15H22O2

포뮬러 무게234.33

MOL 파일177080-67-0.mol

동의어(한글)

2-메틸-2-Adamantyl메타아크릴레이트

2-메틸-2-아다아만틸메타아크릴레이트

2-메틸-2-아다만틸메타크릴레이트

화학적 성질

끓는 점	301.3±11.0 °C(Predicted)
밀도	1.06±0.1 g/cm3(Predicted)
굴절률	1.5050 to 1.5090
인화점	120°C(lit.)
저장 조건	2-8°C
물리적 상태	투명한 액체
색상	무색 내지 거의 무색
Specific Gravity	1.06
감도	Heat Sensitive
InChI	InChI=1S/C15H22O2/c1-9(2)14(16)17-15(3)12-5-10-4-11(7-12)8-13(15)6-10/h10-13H,1,4-8H2,2-3H3
InChIKey	FDYDISGSYGFRJM-UHFFFAOYSA-N
SMILES	C(OC1(C)C2CC3CC1CC(C3)C2)(=O)C(C)=C

위험 및 안전 성명

HS 번호

2902190000

NFPA 704:

	1
0		0

그림문자(GHS)

2-메틸-2-Adamantyl 메타아크릴레이트 화학적 특성, 용도, 생산

화학적 성질
Off-white powder.
주요 응용
2-Methacryloyloxy-2-methyladamantane as a guest molecule can be introduced onto the silicon substrate by interacting with β-cyclodextrin (β-CD) to construct supramolecular composite surfaces. After the assembly of hydrophilic guest molecules on the main surface, the wettability, water lubrication and resistance to algal cell adhesion of the supramolecular composite surface were improved. This host-guest interface supramolecule provides a new way to prepare water-based lubrication and antifouling materials^[2].
Synthesis
The synthesis of 2-Methyl-2-adamantylmethacrylate is as follows:Add 3546ml of n-heptane in the 5L four-necked flask equipped with stirring paddle, condenser tube and thermometer, turn on stirring, add 126.3g of 2-methyladamantanol to the system, and slowly add 0.022g polymerization inhibitor tetrachlorobenzoquinone to the reaction, add 110.8g basic ion exchange resin, adjust pH=7-8, cool down to -13°C, slowly add 110.8g vinyl methacrylate dropwise to the reaction system, keep the reaction for 7h, monitor the reaction progress, and take samples for detection After the reaction was completed, 1000 ml of water was added to the reaction system, and the mixture was stirred and extracted for phase separation. The organic phase was dried, concentrated under reduced pressure and evaporated to dryness to obtain 167 g of 2-methyl-2-adamantyl methacrylate (2-Methacryloyloxy-2-methyladamantane) product with a yield of 93.78%.
참고 문헌
[1] M. Maríc. “Nitroxide‐mediated polymerization of adamantyl‐functional methacrylates for 193 nm photoresists.” Canadian Journal of Chemical Engineering 95 1 (2017): 708–716.
[2] RONGNIAN XU. Promoting Lubricity and Antifouling Properties by Supramolecular-Recognition-Based Surface Grafting[J]. Langmuir, 2018. DOI:10.1021/acs.langmuir.8b02375.

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