CB3715673

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 危険有害性情報

  H315：皮膚刺激

  H317：アレルギー性皮膚反応を起こすおそれ

  H319：強い眼刺激

• 注意書き

  P261：粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。

  P264：取扱い後は皮膚をよく洗うこと。

  P264：取扱い後は手や顔をよく洗うこと。

  P272：汚染された作業衣は作業場から出さないこと。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P302+P352：皮膚に付着した場合：多量の水と石鹸で洗うこと。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

CB3715673 価格

CB3715673 化学特性,用途語,生産方法

• 外観

  無色〜わずかにうすい黄色, 澄明の液体

• 定義

  本品は、次の化学式で表されるテルペンアルデヒドである。

• 溶解性

  水に微溶, エタノール, エーテル, クロロホルムに可溶。エタノールに溶け、水にほとんど溶けない。

• 解説

  シトロネラール，シトロネラ油には，(R)-(＋)-シトロネラールが含まれている．還元すればシトロネロールを生じる．沸点47 ℃(0.13 kPa)．[α]_D＋11.5°．

  森北出版「化学辞典（第2版）
  

• 用途

  柑橘様香気を有する食品、化粧品香料に使用するが、アルカリ、空気、光に対する不安定さのために、単品として使われることは少ない。

• 化粧品の成分用途

  香料

• 製造

  シトロネラール，非環状セスキテルペンアルデヒド．イネ科コウセンガヤChloris radiataから得られる．

• 化学的特性

  (?)-Citronellal occurs in Java citronella oil at a concentration of 35%. Racemic citronellal is the main constituent of E. citriodora oil with a content of up to 85%.
  Pure citronellal is a colorless liquid with a refreshing odor, reminiscent of lemon balm. Upon catalytic hydrogenation, citronellal yields dihydrocitronellal, citronellol, or dihydrocitronellol, depending on the reaction conditions. Protection of the aldehyde group, followed by addition of water to the double bond in the presence of mineral acids or ion-exchange resins results in the formation of 3,7-dimethyl-7-hydroxy-octan-l-al (hydroxydihydrocitronellal). Acid-catalyzed cyclization to isopulegol is an important step in the synthesis of (?)-menthol.

• 天然物の起源

  The d-form of citronellal has been reported in the oil of citronella (Ceylon, Jammus, Kaschmis), in the oil from leaves of Barosma pulchella, in the oil from roots of Phebalium nudum and in the oils of Eucalyptus citriodora, Leptospermum citratum and Baeckea citriodora. The /-form is present in the oils of Backhousia citriodora var. A, E. citriodora, Litsea cubeba (fruits) and lemongrass. Citronellal is generally present also in the oils of lemon, mandarin, Lavandula delphinensis, Ocimum canum f. citrata and many others (Fenarolis Handbook of Flavor Ingredients, 1971).

• 使用

  rac-Citronellal is a monoterpenoid and the major isolate in citronella oil. Citronella oil is an essential oil bearing insecticidal properties. rac-Citronellal is also often used as a fragrance ingred ient.

• 製造方法

  Citronellal is still isolated from essential oils in considerable quantities; it is also produced synthetically.
  1) Isolation from essential oils:(+)-Citronellal is obtained from citronella oils by fractional distillation. Racemic citronellal is isolated from E. citriodora oil; when necessary, it is purified by using an addition compound, for example, the bisulfite derivative.
  2) Synthesis from geraniol or nerol: Racemic citronellal can be obtained by vaporphase rearrangement of geraniol or nerol in the presence of, for example, a barium-containing copper–chromium oxide catalyst.
  3) Synthesis from citronellol: Racemic citronellal can also be obtained by dehydrogenation of citronellol under reduced pressure with a copper chromite catalyst.
  4) Synthesis from citral: Selective hydrogenation of citral to citronellal can be accomplished in the presence of a palladium catalyst in an alkaline alcoholic reaction medium. A continuously operating process for the hydrogenation on a palladium catalyst in the presence of trimethylamine has been developed.
  5) Synthesis from myrcene: (+)- and (?)-Citronellal are available from myrcene via geranyldiethylamine, which is enantioselectively isomerized to (+)- or (?)-citronellalenamine. Hydrolysis yields pure (+)- or (?)-citronellal; see monograph menthol.

• 定義

  ChEBI: A monoterpenoid, the main component of citronella oil which gives it its distinctive lemon aroma.

• 精油の成分

  Citronella oil contains a number of fragrant fractions of which citronellal, geraniol and citronellol are the major components. Ceylon citronella oil contains 55 to 65% total acetylizable alcohols (calculated as citronellol) and 7 to 15% total aldehyde (calculated as citronellal). The main constituents are geraniol (18 to 20%), citronellol (6.4 to 8.4%), citronellal (5 to 15%), geranyl acetate (2%); limonene (9 to 11%) and methyl isoeugenol (7.2 to 11.3%). Other constituents are camphene, caryophyllene, linalool, citral (neral and geranial), methylheapenone, methyleugenol, l-borneol, nerol, eugenol and farnesol.* Java citronella oil contains not less than 35% alcohols (calculated as citronellol) and not less than 35% aldehydes (calculated as citronellal). The Java type appears to have higher concentrations of citronellol (35%) and geraniol (21%) than does the Ceylon type (citronellol 10% and geraniol 18%).

• 一般的な説明

  (±)-Citronellal was studied for its fumigant antifungal activity against Pyricularia (Magnaporthe) grisea.

• 化学性质

  サンザシ様

• 代謝

  Feeding 50 g citronellal to rabbits was followed by the isolation of 13 g of a crystalline glucuronide, which proved to be p-menthane-3.8-diol-D-glucuronide. The citronellal appeared to have been cyclized and the glucuronide obtained was identical with that obtained on feeding p-menthane-3,8-diol (menthoglycol) (Kühn & Low, 1938). However, evidence was produced to show that the cyclization was not, strictly speaking, a biological reaction, but a chemical one which took place in the stomach under the influence of the gastric hydrochloric acid. The conjugation of the menthoglycol with glucuronic acid was, of course, a purely biological reaction. It was found that on shaking 20 g citronellal with 200 ml 0-5% HCl for 48 hr at 37 C, 12 g menthoglycol was formed (Kühn & Low, 1938).

CB3715673 上流と下流の製品情報

CB3715673 生産企業

Global(451)Suppliers

CB3715673 スペクトルデータ(¹HNMR、¹³CNMR、IR1、MS、Raman)

106-23-0, CB3715673 キーワード