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CIS-1,3-DICHLOROPROPENE

CAS No.10061-01-5
Chemical Name:CIS-1,3-DICHLOROPROPENE
CBNumber:CB9680157
Molecular Formula:C3H4Cl2
Formula Weight:110.97
MOL File:10061-01-5.mol

CIS-1,3-DICHLOROPROPENE Property

Melting point -50 °C
Boiling point 104 °C(lit.)
Density 1.225 g/mL at 25 °C(lit.)
vapor pressure 111.6 at 50 °C, 687.8 at 100 °C (Wilding et al., 2002)
refractive index n20/D 1.4675(lit.)
Flash point 75 °F
storage temp. 0-6°C
solubility Chloroform (Soluble), Methanol (Slightly)
form Oil
color Colourless
Water Solubility 1.071g/L(30 ºC)
Merck 14,3075
Henry's Law Constant 1.23 x 10^-3 atm?m³/molat 20 °C, 2.77 at 40 °C (static headspace-GC, Kim et al., 2003)
Exposure limits ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted).
Stability Stable. Flammable. Incompatible with strong oxidizing agents, aluminium and its alloys, active metals, halogens, some metal salts. May be light sensitive.
LogP 1.82 at 20℃ and pH5.83-7.78
Surface tension 69.6mN/m at 976.8mg/L and 20.2℃
CAS DataBase Reference 10061-01-5(CAS DataBase Reference)
FDA UNII 411B9UAH6H
NIST Chemistry Reference 1-Propene, 1,3-dichloro-, (Z)-(10061-01-5)
EPA Substance Registry System cis-1,3-Dichloropropene (10061-01-5)
UNSPSC Code 12162002
NACRES NA.23

Safety

Hazard Codes :T,N,F
Risk Statements :10-20/21-25-36/37/38-43-50/53-52/53-39/23/24/25-23/24/25-11-65-24/25-20
Safety Statements :36/37-45-60-61-16-7
RIDADR :UN 2047 3/PG 2
WGK Germany :3
RTECS :UC8325000
HazardClass :3.2
PackingGroup :III
Hazardous Substances Data :10061-01-5(Hazardous Substances Data)
Toxicity :LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats is 713 and 470 mg/kg, respectively (Verschueren, 1983).

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordDanger
Hazard statements H226-H301+H311+H331-H304-H315-H317-H319-H335-H410
Precautionary statements P210-P273-P280-P301+P310-P303+P361+P353-P331

CIS-1,3-DICHLOROPROPENE Price More Price(3)

Brand: Sigma-Aldrich
Product number: 377414
Product name : cis-1,3-Dichloropropene
Purity: 97%
Packaging: 1ML
Price: ₹4209.45
Updated: 2022/06/14
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Brand: Sigma-Aldrich(India)
Product number: 377414
Product name : cis-1,3-Dichloropropene
Purity: 97%
Packaging: 1ML
Price: ₹4209.45
Updated: 2022/06/14
Buy: Buy

Brand: TCI Chemicals (India)
Product number: D2792
Product name : cis-1,3-Dichloropropene
Purity: min. 98.0 %
Packaging: 25G
Price: ₹10700
Updated: 2022/05/26
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CIS-1,3-DICHLOROPROPENE Chemical Properties,Usage,Production

Chemical Properties 1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.
Chemical Properties colourless to amber liquid
Physical properties Clear, colorless to amber-colored liquid with a pungent and irritating, chloroform-like odor. Evaporates quickly when spilled. The average least detectable odor threshold concentration in water at 60 °C for mixed isomers of 1,3-dichloropropylene was 0.12 mg/L (Alexander et al., 1982).
Uses The isomeric mixture is used as a soil fumigant and a nematocide.
Definition ChEBI: The (Z)-isomer of 1,3-dichloropropene.
General Description Colorless to amber liquid with a sweetish odor.
Air & Water Reactions Highly flammable. Insoluble in water.
Reactivity Profile CIS-1,3-DICHLOROPROPENE may be sensitive to light. Reacts with aluminum, aluminum alloys, other active metals and some metal salts and halogens. Can react vigorously with oxidizing materials.
Fire Hazard Flash point data for CIS-1,3-DICHLOROPROPENE are not available, however literature sources indicate that CIS-1,3-DICHLOROPROPENE is flammable.
Safety Profile Confirmed carcinogen with experimental neoplastigenic data. Human mutation data reported. A dangerous fire hazard when exposed to heat, flame, or oxidzers. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS , ALIPHATIC .
Potential Exposure Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.
Environmental Fate Biological. cis-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen- 1-ol and can be biologically oxidized to 3-chloropropenoic acid, which is further oxidized to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors et al., 1990). The isomeric mixture showed significant degradation with gradual adaptation in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to volatilization (Tabak et al., 1981).
Soil. Hydrolyzes in wet soil forming cis-3-chloroallyl alcohol (Castro and Belser, 1966).
Chemical/Physical. Hydrolyzes in distilled water at 25°C forming 2-chloro-3-propenol and hydrochloric acid. The half-life was 1 day (Milano et al., 1988; Kollig, 1993). Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation of dichloropropylene at about 23°C and 730 mmHg. Chloroacetaldehyde and formyl chloride also formed from the reaction of dichloropropylene with hydroxyl radicals (Tuazon et al., 1984).
The evaporation half-life of cis-1,3-dichloropropylene (1 mg/L) from water at 25°C using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 29.6 minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic phosgene (Sittig, 1985).
Solubility in organics Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.
Solubility in water Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.
Shipping UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.
Incompatibilities Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.
Waste Disposal Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.