10061-01-5

Colorless to amber liquid with a sweetish odor.

CIS-1,3-DICHLORO-1-PROPENE(10061-01-5) may be sensitive to light. Reacts with aluminum, aluminum alloys, other active metals and some metal salts and halogens. Can react vigorously with oxidizing materials.

Highly flammable. Insoluble in water.

Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.

Flash point data for this chemical are not available, however literature sources indicate that this material is flammable.

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.

1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.

colourless to amber liquid

Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

Clear, colorless to amber-colored liquid with a pungent and irritating, chloroform-like odor. Evaporates quickly when spilled. The average least detectable odor threshold concentration in water at 60 °C for mixed isomers of 1,3-dichloropropylene was 0.12 mg/L (Alexander et al., 1982).

The isomeric mixture is used as a soil fumigant and a nematocide.

ChEBI: The (Z)-isomer of 1,3-dichloropropene.

Biological. cis-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen- 1-ol and can be biologically oxidized to 3-chloropropenoic acid, which is further oxidized to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors et al., 1990). The isomeric mixture showed significant degradation with gradual adaptation in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to volatilization (Tabak et al., 1981).
Soil. Hydrolyzes in wet soil forming cis-3-chloroallyl alcohol (Castro and Belser, 1966).
Chemical/Physical. Hydrolyzes in distilled water at 25°C forming 2-chloro-3-propenol and hydrochloric acid. The half-life was 1 day (Milano et al., 1988; Kollig, 1993). Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation of dichloropropylene at about 23°C and 730 mmHg. Chloroacetaldehyde and formyl chloride also formed from the reaction of dichloropropylene with hydroxyl radicals (Tuazon et al., 1984).
The evaporation half-life of cis-1,3-dichloropropylene (1 mg/L) from water at 25°C using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 29.6 minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic phosgene (Sittig, 1985).

Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.

Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.