ChemicalBook > CAS DataBase List > (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
- CAS No.55700-44-2
- Chemical Name:(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
- CBNumber:CB8478872
- Molecular Formula:C26H28FeNP10*
- Formula Weight:441.33
- MOL File:55700-44-2.mol
(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Property
- Melting point 141-143 °C(lit.)
- alpha -355 º (C=0.6 IN ETOH)
- storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
- form solid
- color Light yellow to Yellow to Orange
- optical activity [α]20/D 355°, c = 0.6 in ethanol
- Water Solubility Insoluble in water.
- Sensitive Air Sensitive
- UNSPSC Code 12352005
Safety
- Hazard Codes :Xn
- Risk Statements :20/21/22-36/37/38
- Safety Statements :26-36-36/37/38
- RIDADR :3288
- WGK Germany :3
- HazardClass :6.1
- PackingGroup :III
- HS Code :29319090
-
NFPA 704:
0 2 0
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H302-H312-H315-H319-H332-H335
- Precautionary statements P261-P280-P305+P351+P338-P280a-P304+P340-P405-P501a
(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Price
More Price(4)
- Brand: ALFA India
- Product number: ALF-L19685-ME
- Product name : (R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%
- Purity:
- Packaging: 500mg
- Price: ₹16751
- Updated: 2022/05/26
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-L19685-MC
- Product name : (R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%
- Purity:
- Packaging: 100mg
- Price: ₹5820
- Updated: 2022/05/26
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: D2535
- Product name : (R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine
- Purity:
- Packaging: 100MG
- Price: ₹4800
- Updated: 2022/05/26
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-L19685-04
- Product name : (R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%
- Purity:
- Packaging: 2g
- Price: ₹65343
- Updated: 2022/05/26
- Buy: Buy
(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Chemical Properties,Usage,Production
- Chemical Properties Yellow solid
- Uses Ligand used in the enantioselective vinylation of aldehydes.
- Application (R)-N,N-dimethyl-1-[(s)-2-(diphenylphosphino)ferrocenyl]ethylamine is an effective chiral phosphine ligand for nickel- or palladium-catalyzed asymmetric cross-couplings of organomagnesium or zinc reagents with alkenyl bromides and for palladium-catalyzed asymmetric hydrosilylations of 1,3-dienes.
-
reaction suitability
reaction type: Asymmetric synthesis
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings - storage stable in air for years, but best kept sealed in a refrigerator.
(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Preparation Products And Raw materials
Raw materials
Preparation Products
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55700-44-2, (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINERelated Search:
- (-)-(R)-N,N-DIMETHYL-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE (+)-(S)-N,N-DIMETHYL-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE,(S)-N,N-DIMETHYL-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Dichloro[(S)-N,N-dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine]palladium(II) (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (R)-(S)-BPPFA (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(2-METHYLPHENYL)PHOSPHINO]FERROCENE (R,R)-1-[ALPHA-(DIMETHYLAMINO)-2-(DIPHENYLPHOSPHINO)BENZYL]-2-(DIPHENYLPHOSPHINO)FERROCENE
- Other Chiral Ligands
- Chiral Catalysts, Ligands, and Reagents
- Asymmetric Synthesis
- Transition Metal Compounds
- Synthetic Organic Chemistry
- Phosphine Ligands
- Metallocenes
- Ferrocenes
- Fe (Iron) Compounds
- Classes of Metal Compounds
- Asymmetric Synthesis
- Chiral Phosphine
- 高端化学
- 配体
- 金属催化剂
- 有机化学
- 化工原料
- 有机砌块
- 有机磷
- 膦配体
- 有机贵金属催化剂
- 有机配体
- Fe (Iron) Compounds
- Metallocenes
- Phosphine Ligands
- Classes of Metal Compounds
- Transition Metal Compounds
- Ferrocenes
- Asymmetric Synthesis
- Other Chiral Ligands
- Chiral Catalysts, Ligands, and Reagents
- (R)-N,N-二甲基-1-[(SP)-2-(二苯基膦基)二茂铁基]乙胺
- (SP)-1-[(1R)-1-(二甲基氨基)乙基]-2-(二苯基膦)二茂铁
- (R)-N,N-二甲基-1-[(S)-(2-二苯基膦)二茂铁]乙胺
- (R)-N,N-二甲基-1-[(R)-2-(二苯基膦基)二茂铁基]乙胺
- (R)-N,N-二甲基-1-[(S)-2-二苯基膦基)二茂铁基]乙胺, 用于合成
- (R)-NN-二甲基-1-((S)-2-二苯基磷)二茂铁)乙胺(-)-(R)-N,N-DIMETHYL-1-((S)-2-(DIPHENYL-PHOSPHINO
- (R)-(-)-N,N-二甲基-1-[(S)-2-(2-联苯膦基)二茂铁]乙胺
- (R)-N,N-二甲基-1-[(S)-2-双(二苯基膦基)二茂铁基]乙胺
- (R)-(-)-N,N-二甲基-1-(2-联苯膦基)二茂铁乙胺,97%
- (R)-N,N-二甲基-1-[(S)-2-(二苯基膦基)二茂铁基]乙胺
- (R)-(-)-N,N-二甲基-1-(2-二苯膦基)二茂铁乙胺
- (R)-NN-二甲基-1-((S)-2-二苯基磷)二茂铁)乙胺
- (R)-(-)-N,N-二甲基-1-(2-联苯膦基)二茂铁乙胺
- 55700-44-2
- (R)-N,N-Dimethyl-1-((S)-2-diphenylphosphino)ferrocene)amine
- (<i>R</i>)-(?)-<i>N,N</i>-Dimethyl-1-[(<i>S</i>)-2-(diphenylphosphino)ferrocenyl]ethylamine
- (R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine,98%
- (Sp)-1-[(1R)-1-(Dimethylamino)ethyl]-2-(diphenylphosphino)ferrocene
- (2R)-1-[(1R)-1-(Dimethylamino)ethyl]-2-(diphenylphosphino)ferrocene
- (R)-N,N-Dimethyl-1-[(Sp)-2-(diphenylphosphino)ferrocenyl]ethylamine
- Josiphos
- (R)-(S)-PPFA
- (R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%,
- (R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethy...
- (1R)-1-(2-diphenylphosphanylcyclopentyl)-N,N-dimethylethanamine
- (S)-1-[(R)-1-(Dimethylamino)ethyl]-2-(diphenylphosphino) ferrocene
- (R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 96%, for synthesis