ChemicalBook > CAS DataBase List > (+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]

(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]

CAS No.180186-94-1
Chemical Name:(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
CBNumber:CB8327457
Molecular Formula:C21H18N2O2
Formula Weight:330.38
MOL File:180186-94-1.mol

(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Property

Melting point 225 °C
Boiling point 493.2±45.0 °C(Predicted)
Density 1.48
refractive index 360 ° (C=1, CH2Cl2)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form powder to crystal
pka 5.47±0.20(Predicted)
color White to Almost white
optical activity [α]22/D +353°, c = 3.7 in chloroform
UNSPSC Code 12352005
NACRES NA.22

Safety

Hazard Codes :Xi
Risk Statements :36/37/38
Safety Statements :26-36
WGK Germany :3
HS Code :29349990

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordWarning
Hazard statements H315-H319-H335
Precautionary statements P261-P264-P271-P280-P302+P352-P305+P351+P338

(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Price More Price(3)

Brand: Sigma-Aldrich(India)
Product number: 464155
Product name : [3aR-[2(3′aR*,8′aS*),3′aβ,8′aβ]]-(+)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
Purity: 98%
Packaging: 500MG
Price: ₹6500
Updated: 2022/06/14
Buy: Buy

Brand: TCI Chemicals (India)
Product number: M1401
Product name : (+)-2,2'-Methylenebis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
Purity:
Packaging: 100MG
Price: ₹2700
Updated: 2022/05/26
Buy: Buy

Brand: TCI Chemicals (India)
Product number: M1401
Product name : (+)-2,2'-Methylenebis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
Purity:
Packaging: 500MG
Price: ₹6800
Updated: 2022/05/26
Buy: Buy

(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Chemical Properties,Usage,Production

Chemical Properties White powder
Uses [3aR-[2(3′aR*,8′aS*),3′aβ,8′aβ]]-(+)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] is a C₂symmetric chiral ligand based on bis(oxazoline) moiety, which can be used in enantioselective catalysis. It easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals. Copper complex of this chiral ligand can be utilized as a reusable catalyst in the cyclopropanation reaction between styrene and ethyl diazoacetate.

(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Suppliers

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(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Spectrum

(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE](180186-94-1)IR

180186-94-1, (+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]Related Search:

(3aS,3a'S,8aR,8a'R)-2,2'-(1,3-Diphenylpropane-2,2-diyl)bis(8,8a-dihydro-3aH-indeno[1,2-d]oxazole) (3aS,3'aS,8aR,8'aR)-2,2'-Cyclopentylidenebis[3a,8a-dihydr o-8H-indeno[1,2-d]oxazole] (3aR,3'aR,8aS,8'aS)-2,2'-Cyclopentylidenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] (3aR,3'aR,8aS,8'a'S)-2,2'-cyclopropylidenebis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole (3aR,3a'R,8aS,8a'S)-2,2'-(1,3-diphenylpropane-2,2-diyl)bis(3a,8a-dihydro-8H-indeno[1,2-d]oxazole) (-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] (3aS,3'aS,8aR,8'a'R)-2,2'-cyclopropylidenebis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole CIS-1-AMINO-2-INDANOL (R,R)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) (1R,2S)-1-Amino-2-indanol (+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]

Privileged Ligands and Complexes
Chiral Catalysts, Ligands, and Reagents
BOX
Synthetic Organic Chemistry
Asymmetric Synthesis
Chiral Nitrogen
BOX series
高端化学
试剂
有机配体
氮配体
手性催化剂，配体和试剂
不对称合成
Asymmetric Synthesis
Chiral Catalysts, Ligands, and Reagents
BOX
Privileged Ligands
80186-94-1
(3AR,3'AR,8AS,8'AS)-2,2'-亚甲基双[3A,8A-二氢-8H-茚并[1,2-D]恶唑
(+)-2,2'-亚甲基双[(3AR,8AS)-3A,8A-二氢-8H-茚苯[1,2-D]并噁唑,98%
双[(3AR,8AS)-8,8A-二氢-3AH-茚并[1,2-D]噁唑-2-基]甲烷
3AR-[2(3'AR*,8'AS*),3'AΒ,8'AΒ]]-(+)-2,2'--亚甲基双[3A,8A-二氢-8H-茚并[1,2-D]噁唑
3AR-[2(3′AR*,8′AS*),3′AΒ,8′AΒ]]-(+)-2,2′-亚甲基双[3A,8A-二氢-8H-茚并[1,2-]噁唑
2,2'-亚甲基双[(3AR,8AS)-3A,8A-二氢-8H-茚苯[1,2-D]并恶唑
[3AR-[2(3AR*,8AS*),3AΒ,8AΒ]]-(+)-2,2--亚甲基双[3A,8A-二氢-8H-茚并[1,2-D]噁唑]BIS((3AR,8AS)-8,8A-DIHYDRO-3AH-INDENO[1,2-D]OXAZOL-2-YL)METHANE
(-)2,2'-亚甲基双(3Α,8Α-二氢-8H-茚并[1,2-D]F唑
(+)-2,2'-亚甲基双[(3AR,8AS)-3A,8A-二氢-8H-茚并[1,2-D]噁唑]
(+)-2,2'-亚甲基双[(3AR,8AS)-3A,8A-二氢-8H-吲哚[1,2-D]恶唑]
(+)-2,2'-亚甲基双[(3AR,8AS)-3A,8A-二氢-8H-茚并[1,2-D]恶唑]
(+)-2,2'-亚甲基双[(3AR,8AS)-3A,8A-二氢-8H-茚苯[1,2-D]并恶唑
(3AR,3'AR,8AS,8'AS)-2,2'-亚甲基双[3A,8A-二氢-8H-茚并[1,2-D]恶唑]
[3AR-[2(3'AR*,8'AS*),3'AΒ,8'AΒ]]-(+)-2,2'--亚甲基双[3A,8A-二氢-8H-茚并[1,2-D]噁唑]
[3AR-[2(3′AR*,8′AS*),3′AΒ,8′AΒ]]-(+)-2,2′-亚甲基双[3A,8A-二氢-8H-茚并[1,2-]唑]
(+)2,2'-亚甲基双(3Α,8Α-二氢-8H-茚并[1,2--D]噁唑
(+)-2,2'-亚甲基双[(3AR,8AS)-3A,8A-二氢-8H-茚苯[1,2-D]并噁唑
[3AR-[2(3′AR*,8′AS*),3′AΒ,8′AΒ]]-(+)-2,2′-亚甲基双[3A,8A-二氢-8H-茚并[1,2-]噁唑]
180186-94-1
[3aR-[2(3′aR*,8′aS*),3′aβ,8′aβ]]-(+)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
(3aR,3'aR,8aS,8'aS)-2,2'-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE
3aR-[2(3′aR*,8′aS*),3′aβ,8′aβ]]-(+)-2,2′-Methylenebis[3a,8a
3aR-[2(3`aR,8`aS),3`aβ,8`aβ]]-(+)-2,2`-methylenebis[3a,8a-dihydro-8H-indeno[1,2-]oxazole
Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)Methane
(+)-2,2'-Methylenebis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole] &gt
8H-Indeno[1,2-d]oxazole, 2,2'-methylenebis[3a,8a-dihydro-, (3aR,3'aR,8aS,8'aS)-
(+)-2,2-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE
3aR-[2(3′aR*,8′aS*),3′aβ,8′aβ]]-(+)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-...
[3aR-[2(3
(+)-2,2'-Methylenebis[(3AR,8AS)-3A,8A-Dihydro-8H-Indeno[1,2-D]Oxazole],98%
[3aR-[2(3'aR*,8'aS*),3'abeta,8'abeta]]-(+)-2,2'-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] 98%
(-)-2,2''-METHYLENEBIS-[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] EP
[3ar-[2(3'ar*,8'as*),3'aβ,8'aβ]]-(+)-2,2'-methylenebis[3a,8a-dihydro-8h-indeno[1,2-]oxazole]
[3aR-[2(3'aR*,8'aS*),3'aβ,8'aβ]]-(+)-2,2'-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
(3aR,3'aR,8aS,8'aS)-2,2'-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
[3aR-[2(3′aR*,8′aS*),3′aβ,8′aβ]]-(+)-2,2′-Methylenebis[3a,8a
(+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]

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