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4-Bromomethyl-7-methoxycoumarin

4-Bromomethyl-7-methoxycoumarin Structure
4-Bromomethyl-7-methoxycoumarin
  • CAS No.35231-44-8
  • Chemical Name:4-Bromomethyl-7-methoxycoumarin
  • CBNumber:CB6345309
  • Molecular Formula:C11H9BrO3
  • Formula Weight:269.09
  • MOL File:35231-44-8.mol
4-Bromomethyl-7-methoxycoumarin Property
  • Melting point 213-215 °C (lit.)
  • Boiling point 385.3±42.0 °C(Predicted)
  • Density 1.552±0.06 g/cm3(Predicted)
  • storage temp. Keep in dark place,Inert atmosphere,2-8°C
  • solubility chloroform: soluble20mg/mL, clear, colorless to faintly yellow
  • form Powder and/or Chunks
  • color Off-white to light yellow or beige
  • Water Solubility insoluble
  • λmax 330 nm (MeOH)
  • BRN 187211
  • Stability Stable, but moisture and light-sensitive. Combustible. Incompatible with strong oxidizing agents.
  • Major Application Detection of nitrated explosives; measuring ultraviolet ray power; photoacid generators; polyurethane foams; photoresists silica nanoparticles
  • Biological Applications Analyzing/detecting carboxylic acids;analyzing/labeling fatty acids; detecting nitric oxide; detecting/separating bile acids; labeling pyrimidine nucleobases; anticancer agents; biomedical trace analysis; herbicides; as a substrate for measuring histone acetyltransferases (HATs) activity, peptidases activity, sirtuin activity
  • LogP 2.730 (est)
  • CAS DataBase Reference 35231-44-8(CAS DataBase Reference)
  • FDA UNII 4K32PB5K8Q
  • UNSPSC Code 12352100
  • NACRES NA.22
Safety
  • Hazard Codes  :Xi,Xn
  • Risk Statements  :36/37/38-22
  • Safety Statements  :26-36-37/39
  • RIDADR  :1759
  • WGK Germany  :3
  • HazardClass  :8
  • PackingGroup  :III
  • HS Code  :29322090
  • NFPA 704:
    0
    1 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H302-H315-H319-H335
  • Precautionary statements P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
4-Bromomethyl-7-methoxycoumarin Price More Price(4)
  • Brand: Sigma-Aldrich(India)
  • Product number: 235202
  • Product name : 4-Bromomethyl-7-methoxycoumarin
  • Purity: 97%
  • Packaging: 1G
  • Price: ₹9780
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 235202
  • Product name : 4-Bromomethyl-7-methoxycoumarin
  • Purity: 97%
  • Packaging: 5G
  • Price: ₹37960
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: A5551
  • Product name : Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) [for HPLC Labeling]
  • Purity: 
  • Packaging: 1G
  • Price: ₹7400
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: A5551
  • Product name : Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) [for HPLC Labeling]
  • Purity: 
  • Packaging: 5G
  • Price: ₹16300
  • Updated: 2022/05/26
  • Buy: Buy

4-Bromomethyl-7-methoxycoumarin Chemical Properties,Usage,Production

  • Chemical Properties Light Green-Yellow Crystals
  • Uses 4-Bromomethyl-7-methoxycoumarin has been used:
    • as derivatization reagent in determination of 5-fluorouracil (5-FU) in human plasma by HPLC-tandem mass spectrometry
    • as derivatization reagent in fluorescence detection of sodium monofluoroacetate (MFA-Na) in biological samples by HPLC
    • in the synthesis of new caged derivatives of hydrolysis-resistant 8-bromoadenosine cyclic 3′,5′-monophosphate (8-Br-cAMP) and 8-bromoguanosine cyclic 3′,5′-monophosphate (8-Br-cGMP)
    • in TLC and HPLC separation and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B2
  • Uses 4-Bromomethyl-7-methoxycoumarin can be used as fluorescent label for fatty acids. For derivatization, TLC and HPLC separation, and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B2.
  • Purification Methods The coumarin crystallises from boiling AcOH; the crystals are washed with AcOH, EtOH and dried in a vacuum; 1HNMR (TFA) 3.97s, 4.57s, 6.62s, 6.92-7.19m and 7.80d. [Secrist et al. Biochem Biophys Res Commun 45 1262 1971, Dünges Anal Chem 49 442 1977, Beilstein 18 III/IV 348.]
4-Bromomethyl-7-methoxycoumarin Preparation Products And Raw materials
Raw materials
Preparation Products
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4-Bromomethyl-7-methoxycoumarin Spectrum
35231-44-8, 4-Bromomethyl-7-methoxycoumarinRelated Search:
  • Analytical Chemistry
  • Coumarins
  • Fluorescent Labels and Indicators
  • Fluorescent Labels & Indicators
  • HPLC Labeling Reagents
  • Fluorescence Detection (HPLC Labeling Reagents)
  • Carboxyl Group Labeling Reagents for Fluorescence HPLC
  • 化学试剂
  • 抑制剂
  • 高端化学
  • 合成材料中间体
  • 合成
  • 植物提取物
  • BioChemical
  • Biochemicals and Reagents
  • Other Fluorescent Labels
  • Fluorescent Probes, Labels, Particles and Stains
  • Fluorescent Labels
  • Detection
  • Carboxyl Group Labeling Reagents for Fluorescence HPLC
  • Fluorescence Detection (HPLC Labeling Reagents)
  • HPLC Labeling Reagents
  • ESTER
  • C11H9BrO3
  • BR-MMC(=4-溴甲基-7-甲氧基香豆素)/用于高效液相色谱标记*5
  • PERFEMIKER]4-溴甲基-7-甲氧基香豆素,97%
  • 4-溴甲基-7-甲氧基香豆素(BRMMC)
  • BR-MMC(=4-溴甲基-7-甲氧基香豆素)[用于高效CHEMICALBOOK液相色谱标记]
  • 4-溴甲基-7-甲氧基苯并吡喃-2-酮
  • 4-溴甲基L-7-乙氧基香豆素
  • 4-溴甲基-7-甲氧基香豆素[用于高效液相色谱标记]
  • BR-MMC (=4-溴甲基-7-甲氧基香豆素)[用于高效液相色谱标记]
  • 4-溴甲基-7-甲氧基香豆素 (BRMMC))[用于高效液相色谱标记]
  • 溴甲基层- 甲氧基香醇
  • 4-溴甲基-7-甲氧基香豆素(97%)
  • 4-溴甲基-7-甲氧基香豆素
  • BR-MMC (=4-溴甲基-7-甲氧基香豆素)(>98.0%(T))
  • BR-MMC (=4-溴甲基-7-甲氧基香豆素)
  • 35231-44-8
  • Br-Mmc (=4-Bromomethyl-7-methoxycoumarin), for HPLC,≥ 98.0%
  • BMC
  • -7-methoxy-2H-chromen-2-one
  • 4-(bromomethyl)-7-methoxy-2H-chromene-2-one
  • 4-Bromomethyl-7-methoxycoumarin ISO 9001:2015 REACH
  • Br-Mmc (=4-Bromomethyl-7-methoxycoumarin)[for HPLC Labeling]&gt
  • 4-BROMOMETHYL-7-METHOXYCOUMARIN (BR-MMC)
  • 4-Bromomethyl-7-methoxycoumain
  • 4-BROMOMETHYL-7-METHOXYCOUMARIN, FOR FLU ORESCENCE
  • 4-BROMOETHYL-7-METHOXYCOUMARIN
  • 4-BROMOMETHYL-7-METHOXYCOUMARIN
  • BR-MMC
  • 4-(BroMoMethyl)-7-Methoxy-2H-chroMen-2-one
  • 4-BroMoMethyl-7-MethoxycouMarin 97%
  • 4-BroMoMethyl-7-MethoxycouMarine
  • 4-(BroMoMethyl)-7-MethoxycouMarin, 97% 1GR
  • BROMOMETHYL-7-METHOXYCOUMARIN, 4-(RG)
  • 4-Bromomethyl-7-methoxycoumarin (BrMMC) [for HPLC Labeling]
  • 4-Bromomethyl-7-methoxycoumarin,BMC, Br-Mmc