ChemicalBook > CAS DataBase List > (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Structure
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
  • CAS No.148461-14-7
  • Chemical Name:(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
  • CBNumber:CB6159670
  • Molecular Formula:C24H24NOP
  • Formula Weight:373.43
  • MOL File:148461-14-7.mol
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Property
  • Melting point 85-90 °C
  • alpha -44° (c 1.4, CHCl3)
  • Boiling point 492.7±28.0 °C(Predicted)
  • storage temp. under inert gas (nitrogen or Argon) at 2-8°C
  • pka 4.31±0.70(Predicted)
  • form Powder
  • color white
  • optical activity [α]20/D 48±3°, c = 1% in chloroform
  • Sensitive air sensitive
  • BRN 5879302
  • UNSPSC Code 12352005
Safety
  • Hazard Codes  :Xi
  • Risk Statements  :36/37/38
  • Safety Statements  :37/39-26-24/25
  • WGK Germany  :3
  • F  :10-23
  • Hazard Note  :Irritant
  • HS Code  :29349990
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H302-H315-H319-H335
  • Precautionary statements P261-P280-P301+P312-P302+P352-P305+P351+P338

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Chemical Properties,Usage,Production

  • Chemical Properties White crystalline powder
  • Reactions
    1. Chiral ligand used in the asymmetric reduction of highly substituted olefins.
    2. Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
    3. Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
    4. Decarboxylative allylic alkylation.
    Reactions of 148461-14-7
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Preparation Products And Raw materials
Raw materials
Preparation Products
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Suppliers
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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Spectrum
148461-14-7, (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLERelated Search:
  • organophosphine ligand
  • PHOX Series
  • Chiral Phosphine
  • 有机试剂
  • 有机中间体
  • 配体
  • 有机配体
  • 有机磷
  • 膦配体
  • 手性配体、手性催化剂
  • 有机磷/膦配体
  • 有机砌块
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Privileged Ligands
  • PHOX
  • C24H24NOP
  • (S)-(-)-2-[2-(二苯基膦)苯基]-4-异丙基-2-唑啉,98%
  • (S)-2-(2-(二苯基膦基)苯基)-4-异丙基-4,5-二氢噁唑
  • (S)-2-(2-(二苯基膦基)苯基)-4-异丙基-4,5-二氢恶唑
  • (4S)-2-[2-(二苯基膦)苯基]-4,5-二氢-4-异丙基恶唑
  • 二氢二苯磷苯基-4-异丙噁唑
  • (4S)-2-(2-(二苯基膦基)苯基)-4-异丙基-4,5-二氢恶唑
  • (S)-(-)-2-[2-二苯基膦]苯基]-4-异丙基-2-噁唑啉
  • 二氢二苯磷苯基-4-异丙恶唑 1G
  • (S)-(-)-2-[(2-(二苯基膦)苯基]-4-(1-甲基乙基)-4,5-二氢噁唑
  • 二氢二苯磷苯基-4-异丙唑
  • (S)-(-)-2-[2-(二苯基膦)苯基]-4,5-二氢-4-异丙基唑
  • (S)-(-)-2-[2-(二苯基膦)苯基]-4-异丙基-2-唑啉
  • (4S)-(-)-4,5-二氢-2-[2'-(二苯基磷)苯基]-4-异丙基恶唑
  • 二氢二苯磷苯基-4-异丙恶唑
  • 148461-14-7
  • (S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole (S)-iPr-PHOX
  • (<i>S</i>)-(?)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline
  • (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydroo
  • (S)-iPr-Phox
  • (S)-2-(2-(diphenylphosphanyl)phenyl)-4-isopropyl-4,5-dihydrooxazole
  • (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
  • (4S)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e.
  • Oxazole,2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-, (4S)-
  • [2-[(4S)-4-isopropyl-4,5-Dihydrooxazol-2-yl]phenyl]-diphenyl-phosphane
  • (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN)
  • )-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline
  • (4S)-(-)-2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole
  • (4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-Oxazole
  • (S)-(-)-2-[(2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE,98%(S)-IPR-PHOX
  • 2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole
  • (-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97%
  • (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole,98%
  • (4S)-(-)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole,98%
  • Diphenylphosphinophenylmethylethyldihydrooxazole
  • (4S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
  • (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-
  • (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
  • (-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE
  • (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE
  • (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE
  • (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE

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