ChemicalBook > CAS DataBase List > 2,2,2-Trifluoroethyl trifluoromethanesulfonate
2,2,2-Trifluoroethyl trifluoromethanesulfonate
2,2,2-Trifluoroethyl trifluoromethanesulfonate
- CAS No.6226-25-1
- Chemical Name:2,2,2-Trifluoroethyl trifluoromethanesulfonate
- CBNumber:CB5142808
- Molecular Formula:C3H2F6O3S
- Formula Weight:232.1
- MOL File:6226-25-1.mol
2,2,2-Trifluoroethyl trifluoromethanesulfonate Property
- Boiling point 89-91°C
- Density 1,61 g/cm3
- refractive index 1.3037
- RTECS PB2775000
- Flash point >110°(230°F)
- storage temp. 2-8°C
- solubility Chloroform, Methanol (Slightly)
- form Liquid
- color Colorless to yellow
- Water Solubility Slightly soluble in water.
- Sensitive Moisture Sensitive
- InChIKey RTMMSCJWQYWMNK-UHFFFAOYSA-N
- CAS DataBase Reference 6226-25-1(CAS DataBase Reference)
- EPA Substance Registry System Methanesulfonic acid, trifluoro-, 2,2,2-trifluoroethyl ester (6226-25-1)
- UNSPSC Code 12352101
- NACRES NA.22
Safety
- Hazard Codes :Xi,T,C
- Risk Statements :36/37/38-34-23/25
- Safety Statements :26-36/37/39-45
- RIDADR :3265
- WGK Germany :3
- Hazard Note :Irritant
- HazardClass :TOXIC, CORROSIVE
- HazardClass :8
- PackingGroup :Ⅱ
- HS Code :29055900
-
NFPA 704:
1 3 0
-
Symbol(GHS)
- Signal wordDanger
- Hazard statements H301-H314-H330
- Precautionary statements P260-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
2,2,2-Trifluoroethyl trifluoromethanesulfonate Price
More Price(2)
- Brand: TCI Chemicals (India)
- Product number: T1604
- Product name : 2,2,2-Trifluoroethyl Trifluoromethanesulfonate
- Purity: min. 97.0 %
- Packaging: 5G
- Price: ₹10800
- Updated: 2022/05/26
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: T1604
- Product name : 2,2,2-Trifluoroethyl Trifluoromethanesulfonate
- Purity: min. 97.0 %
- Packaging: 25G
- Price: ₹31200
- Updated: 2022/05/26
- Buy: Buy
2,2,2-Trifluoroethyl trifluoromethanesulfonate Chemical Properties,Usage,Production
- Uses A fluorine-containing alkyl alkanesulfonate with cyctotoxity towards cultured leukemia L1210 cells.
- Uses 2,2,2-Trifluoroethyl trifluoromethanesulfonate is a powerful trifluoroethylating agent which is useful for synthesis of fluorinated amino acids. It is used as a reagent in thenantioselective preparation of cyclic N-aryl hydroxamic acids via phase-transfer catalyzed alkylation of nitrobenzyl bromides to give nirophenylalanines.
- Uses Reagent used in thenantioselective preparation of cyclic N-aryl hydroxamic acids via phase-transfer catalyzed alkylation of nitrobenzyl bromides to give nirophenylalanines
-
Synthesis
In a 100-ml flask equipped with a stirrer, a thermometer, a nitrogen introducing pipe, and a condenser, 50 ml (0.297 mol) of trifluoromethane sulfonic anhydride and 25 ml (0.342 moles) of 2,2,2-trifluoroethanol were placed at room temperature and stirred for 30 minutes in a nitrogen atmosphere, followed by reflux for 3 hours. After distillation, 50.3 g of 2,2,2-trifluoroethyl trifluoromethanesulfonate was obtained in a yield of 73%.
2,2,2-Trifluoroethyl trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
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6226-25-1, 2,2,2-Trifluoroethyl trifluoromethanesulfonateRelated Search:
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- 2,2,2-Trifluoroethyl trifluoromethanesulf
- 2,2,2-Trifluoroethyl Triflante
- 2,2,2-TRIFLUOROETHYL TRIFLATE 2,2,2-Trifluoroethyl Trifluoromethanesulfonate
- 2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULPHONATE
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- High purity CAS 6226-25-1 2,2,2-Trifluoroethyl trifluoromethanesulfonate in stock
- Methanesulfonic acid, 1,1,1-trifluoro-, 2,2,2-trifluoroethyl ester
- 1,1,1-Trifluoro-2,2,2-trifluoroethyl Ester Methanesulfonic Acid
- 2,2,2-Trifluoroethytrifluoromethanesulfonate
- Trifluoromethane sulfonate trifluoroethyl ester
- 2-Trifluoroethyl trifluoromethanesulfonate
- 2,2,2-Trifluoroethyl trifluoromethanesulfote
- 2,2,2-Trifluoroethyl Triflate Trifluoromethanesulfonic Acid 2,2,2-Trifluoroethyl Ester
- 2,2,2-Trifluoroethyl trifluoroMethylsulfonate
- 2,2,2-Trifluoroethanol TrifluoroMethanesulfonate
- 2,2,2-Trifluoroethyl trifluoromethanesulphonate 97%
- 2,2,2 Trifluoroethyl TrifluoroMathane sulfonate