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N-Methyldiethanolamine

CAS No.105-59-9
Chemical Name:N-Methyldiethanolamine
CBNumber:CB3260193
Molecular Formula:C5H13NO2
Formula Weight:119.16
MOL File:105-59-9.mol

N-Methyldiethanolamine Property

Melting point -21 °C
Boiling point 246-248 °C(lit.)
Density 1.038 g/mL at 25 °C(lit.)
vapor density 4 (vs air)
vapor pressure 0.01 mm Hg ( 20 °C)
refractive index n20/D 1.469(lit.)
Flash point 260 °F
storage temp. Store below +30°C.
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
pka 14.41±0.10(Predicted)
color Clear colorless to light yellow
Odor Ammonical
PH Range 11.5 at 100 g/l at 20 °C
PH 11.5 (100g/l, H2O, 20℃)
explosive limit 0.9-8.4%(V)
Viscosity 99.05mm2/s
Water Solubility MISCIBLE
BRN 1734441
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey CRVGTESFCCXCTH-UHFFFAOYSA-N
LogP -1.16 at 23℃
Surface tension 33.5 mN/m at 303.15K
Indirect Additives used in Food Contact Substances N-METHYLDIETHANOLAMINE
CAS DataBase Reference 105-59-9(CAS DataBase Reference)
FDA UNII 3IG3K131QJ
NIST Chemistry Reference Methyldiethanolamine(105-59-9)
EPA Substance Registry System N-Methyldiethanolamine (105-59-9)
UNSPSC Code 12352104
NACRES NA.22

Safety

Hazard Codes :Xi
Risk Statements :36
Safety Statements :24
RIDADR :2735
WGK Germany :1
RTECS :KL7525000
Autoignition Temperature :770 °F
TSCA :Yes
HS Code :2922 17 00
HazardClass :8
PackingGroup :II
Hazardous Substances Data :105-59-9(Hazardous Substances Data)
Toxicity :LD50 orally in Rabbit: 4680 mg/kg

NFPA 704:

	1
1		0

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordWarning
Hazard statements H319
Precautionary statements P264-P280-P305+P351+P338-P337+P313

N-Methyldiethanolamine Price More Price(4)

Brand: Sigma-Aldrich(India)
Product number: 471828
Product name : N-Methyldiethanolamine
Purity: ≥99%
Packaging: 25ML
Price: ₹1948.5
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 471828
Product name : N-Methyldiethanolamine
Purity: ≥99%
Packaging: 250ML
Price: ₹1948.5
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 471828
Product name : N-Methyldiethanolamine
Purity: ≥99%
Packaging: 2L
Price: ₹9655.9
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 471828
Product name : N-Methyldiethanolamine
Purity: ≥99%
Packaging: 18L
Price: ₹52295.58
Updated: 2022/06/14
Buy: Buy

N-Methyldiethanolamine Chemical Properties,Usage,Production

Chemical Properties N-Methyldiethanolamine (MDEA) is a colorless to yellow viscous liquid with an ammonia-like odor. It is completely soluble in water. N-Methyldiethanolamine is an alkyl alkanolamine.It combines the chemical characteristics of both amines and alcohols so that it is capable of undergoing reactions typical of both alcohols and amines: forming quaternary amine salts, soaps, and esters.
Uses N-methyldiethanolamine is used as an intermediate in the synthesis of numerous products. Its unique chemistry has resulted in its use in diverse areas, including coatings, textile lubricants, polishes, detergents, pesticides, personal-care products, pharmaceuticals, urethane catalysts, and water-treatment chemicals. It is also used in absorption of acidic gases, catalyst for polyurethane foams, pH control agent.
Uses N-Methyldiethanolamine is a reagent used for protection of boronic acids as N-methyl-O,O-diethanolamine esters.
Preparation N-methyldiethanolamine is produced by the reaction between ethylene oxide and methylamine.
Synthesis Reference(s) Journal of the American Chemical Society, 107, p. 6659, 1985 DOI: 10.1021/ja00309a039
General Description Colorless liquid.
Air & Water Reactions Very water soluble .
Reactivity Profile N-Methyldiethanolamine is an aminoalcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. N-Methyldiethanolamine may react with oxidizing materials.
Health Hazard Exposure can cause irritation of eyes, nose and throat.
Fire Hazard Special Hazards of Combustion Products: Irritating vapors and toxic gases, such as nitrogen oxides and carbon monoxide, may be formed when involved in fire.
Flammability and Explosibility Non flammable
Environmental Fate N-methyldiethanolamine is readily biodegradable, and its bioconcentration potential is low. Releases to the environment would not persist and would degrade rapidly. The potential for mobility in soil is very high. It is slightly toxic to aquatic organisms on an acute basis.
storage N-methyldiethanolamine is stable under normal storage and use conditions, but elevated temperatures can cause it to decompose. Decomposition products depend upon temperature, air supply, and the presence of other materials. Avoid contact with nitrites, strong acids, and strong oxidizers. Avoid unintended contact with halogenated hydrocarbons. N-methyldiethanolamine can react with halogenated organics, resulting in temperature and/or pressure increases. It is corrosive when wet. Heating above 60°C (140°F) in the presence of aluminum can result in corrosion and generation of flammable hydrogen gas.
Toxics Screening Level The updated initial threshold screening level (ITSL) for methyldiethanolamine is 6 μg/m3 based on an annual averaging time.