ChemicalBook > CAS DataBase List > NICKEL BROMATE

NICKEL BROMATE

Description References

NICKEL BROMATE

CAS No.13462-88-9
Chemical Name:NICKEL BROMATE
CBNumber:CB2669337
Molecular Formula:Br2Ni
Formula Weight:218.5
MOL File:13462-88-9.mol

NICKEL BROMATE Property

Melting point 963 °C (lit.)
Density 5.098 g/mL at 25 °C (lit.)
storage temp. Inert atmosphere,Room Temperature
solubility H2O: slightly soluble(lit.)
form powder
color Brown
Specific Gravity 5.098
Water Solubility Soluble in water, alcohol and ether.
Sensitive Hygroscopic
Merck 14,6502
Exposure limits ACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability Stable. Incompatible with strong oxidizing agents.
InChIKey IPLJNQFXJUCRNH-UHFFFAOYSA-L
CAS DataBase Reference 13462-88-9(CAS DataBase Reference)
FDA UNII 41SGH8A2S6
EPA Substance Registry System Nickel(II) bromide (13462-88-9)
UNSPSC Code 12352302
NACRES NA.23

Safety

Hazard Codes :T,N,Xi
Risk Statements :45-22-43-50/53-68-48/23-42/43-61-49
Safety Statements :53-36/37-45-60-61
RIDADR :UN 3077 9/PG 3
WGK Germany :3
TSCA :Yes
HazardClass :6.1(b)
PackingGroup :III
HS Code :28275900

NFPA 704:

	0
2		0

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordDanger
Hazard statements H317-H334-H341-H350-H360-H372-H410
Precautionary statements P201-P273-P280-P302+P352-P308+P313

NICKEL BROMATE Price More Price(7)

Brand: Sigma-Aldrich(India)
Product number: 561142
Product name : Nickel(II) bromide
Purity: anhydrous, powder, ≥99.9% trace metals basis
Packaging: 2G
Price: ₹7393.48
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 561142
Product name : Nickel(II) bromide
Purity: anhydrous, powder, ≥99.9% trace metals basis
Packaging: 10G
Price: ₹20166.98
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 449156
Product name : Nickel(II) bromide
Purity: anhydrous, powder, ≥99.99% trace metals basis
Packaging: 1G
Price: ₹7166.15
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 217891
Product name : Nickel(II) bromide
Purity: 98%
Packaging: 10G
Price: ₹2110.88
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 217891
Product name : Nickel(II) bromide
Purity: 98%
Packaging: 50G
Price: ₹9363.63
Updated: 2022/06/14
Buy: Buy

NICKEL BROMATE Chemical Properties,Usage,Production

Description Nickel bromide (chemical formula: NiBr2) is the nickel salt of hydrobromic acid. It is a weak reducing agent made by the reaction of nickel, nickel oxide, nickel carbonate or nickel hydroxide with hydrobromic acid, or the reaction between nickel and bromine. Nickel bromide has many kinds of applications. It is mostly an electron acceptor, being capable of catalyze organic structure such as carbonamides, and convert aryl bromides into aryl phosphines. It can also be used as a catalyst in cross-coupling reactions. It is also applied for bonding to other ligands. For example, graphene supported NrBr2 is used in a condensation reaction consisting of aromatic aldehyde, acetoacetate and urea for manufacturing 3, 4- dihydropyrimidiones.
References https://en.wikipedia.org/wiki/Nickel(II)_bromide
Chemical Properties Brownish powder
Uses Nickel(II) Bromide, is used as a source of bromide ion. It is also an important raw material used in various chemical synthesis and also as a catalyst in cross-coupling reactions.
General Description Yellowish-green odorless solid. Sinks in and mixes with water.
Air & Water Reactions Deliquescent. Soluble in water.
Reactivity Profile NICKEL BROMATE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes NICKEL BROMATE produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition NICKEL BROMATE emits toxic bromide fumes. [M. K.]
Health Hazard Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin.
Fire Hazard Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire.
reaction suitability reagent type: catalyst
core: nickel
Purification Methods Crystallise it from dilute HBr (0.5mL/g) by partial evaporation in a desiccator. The anhydrous salt is yellow, but the trihydrate is green.