Supplier Related Products Identification Chemical Properties Safety Data Hazard Information Questions And Answer Spectrum Detail Well-known Reagent Company Product Information
WebSite >  CAS DataBase List  > 13462-88-9

13462-88-9

Supplier Related Products Identification Chemical Properties Safety Data Hazard Information Questions And Answer Spectrum Detail Well-known Reagent Company Product Information

Product Image

Identification

Name
NICKEL BROMATE
CAS
13462-88-9
Synonyms
NICKEL BROMATE
NiBr2
Nickel bromide (NiBr2)
Nickel(II)-bromid
Nickel(II)-bromidwasserfrei
nickelbromide(nibr2)
Nickelbromideanhydrousyellowgreenpowder
Nickelbromidehydrateyellowgreenxtl
NICKEL(II)BROMIDE,ANHYDROUS,POWDER,99.9+%
NICKEL(II) BROMIDE, ANHYDROUS, POWDER, 9 9.99+%
Nickel(II) bromide anhydrous
Nickel(Ⅱ) bromide
Nickel(II)bromide,anhydrous(99+%-Ni)
Nickel-bromid
Nickel Bromide, Anhydrous
Dibromonickel(II)
Nickel(II) dibromide
Nickeleus bromide
EINECS(EC#)
236-665-0
Molecular Formula
Br2NiO6
MDL Number
MFCD00049991
Molecular Weight
314.5
MOL File
13462-88-9.mol

Chemical Properties

Appearance
Brownish powder
mp 
963 °C(lit.)

density 
5.098 g/mL at 25 °C(lit.)

form 
powder

Stability:
Stable. Incompatible with strong oxidizing agents.
Sensitive 
Hygroscopic
Merck 
14,6502
CAS DataBase Reference
13462-88-9(CAS DataBase Reference)

Safety Data

Hazard Codes 
T,N,Xi
Risk Statements 
R45:May cause cancer.
R22:Harmful if swallowed.
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
Safety Statements 
S53:Avoid exposure-obtain special instruction before use .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR 
UN 3077 9/PG 3

WGK Germany 
3

HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
28275900

Hazard Information

General Description
Yellowish-green odorless solid. Sinks in and mixes with water.
Reactivity Profile
NICKEL BROMIDE(13462-88-9) is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes NICKEL BROMIDE(13462-88-9) produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition NICKEL BROMIDE(13462-88-9) emits toxic bromide fumes. [M. K.]
Air & Water Reactions
Deliquescent. Soluble in water.
Health Hazard
Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin.
Fire Hazard
Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire.

Questions And Answer

Description
Nickel bromide (chemical formula: NiBr2) is the nickel salt of hydrobromic acid. It is a weak reducing agent made by the reaction of nickel, nickel oxide, nickel carbonate or nickel hydroxide with hydrobromic acid, or the reaction between nickel and bromine. Nickel bromide has many kinds of applications. It is mostly an electron acceptor, being capable of catalyze organic structure such as carbonamides, and convert aryl bromides into aryl phosphines. It can also be used as a catalyst in cross-coupling reactions. It is also applied for bonding to other ligands. For example, graphene supported NrBr2 is used in a condensation reaction consisting of aromatic aldehyde, acetoacetate and urea for manufacturing 3, 4- dihydropyrimidiones.
References
https://en.wikipedia.org/wiki/Nickel(II)_bromide

Spectrum Detail

Well-known Reagent Company Product Information

SupplierMore