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1-Nitronaphthalene

1-Nitronaphthalene Structure
1-Nitronaphthalene
  • CAS No.86-57-7
  • Chemical Name:1-Nitronaphthalene
  • CBNumber:CB2487528
  • Molecular Formula:C10H7NO2
  • Formula Weight:173.17
  • MOL File:86-57-7.mol
1-Nitronaphthalene Property
  • Melting point 56 °C
  • Boiling point 304 °C(lit.)
  • Density 1.223 g/mL at 25 °C(lit.)
  • refractive index 1.5200 (estimate)
  • Flash point 164 °C
  • storage temp. 2-8°C
  • solubility H2O: insoluble
  • form solid
  • color Light Yellow To Yellow
  • Specific Gravity 1.223
  • Water Solubility 0.022 g/L
  • Merck 14,6613
  • BRN 1867714
  • Stability Stable. Combustible. Incompatible with oxidizing agents, strong reducing agents. Mixtures with sulfuric or nitric acid are dangerous.
  • InChIKey RJKGJBPXVHTNJL-UHFFFAOYSA-N
  • CAS DataBase Reference 86-57-7(CAS DataBase Reference)
  • FDA UNII A51NP1DL2T
  • IARC 3 (Vol. 46) 1989
  • NIST Chemistry Reference Naphthalene, 1-nitro-(86-57-7)
  • EPA Substance Registry System 1-Nitronaphthalene (86-57-7)
  • UNSPSC Code 12352100
  • NACRES NA.22
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H228-H302-H411
  • Precautionary statements P210-P240-P241-P264-P273-P301+P312
1-Nitronaphthalene Price More Price(5)
  • Brand: Sigma-Aldrich(India)
  • Product number: 103594
  • Product name : 1-Nitronaphthalene
  • Purity: 99%
  • Packaging: 100G
  • Price: ₹5675.9
  • Updated: 2022/06/14
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  • Brand: TCI Chemicals (India)
  • Product number: N0212
  • Product name : 1-Nitronaphthalene
  • Purity: min. 98.0 %
  • Packaging: 25G
  • Price: ₹2200
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: N0212
  • Product name : 1-Nitronaphthalene
  • Purity: min. 98.0 %
  • Packaging: 500G
  • Price: ₹9600
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: ottokemi
  • Product number:  N 1855
  • Product name : 1-Nitro naphthalene
  • Purity: 98%
  • Packaging: 100gm
  • Price: ₹2196
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: ottokemi
  • Product number:  N 1855
  • Product name : 1-Nitro naphthalene
  • Purity: 98%
  • Packaging: 500gm
  • Price: ₹8919
  • Updated: 2022/05/26
  • Buy: Buy

1-Nitronaphthalene Chemical Properties,Usage,Production

  • Chemical Properties yellow crystalline solid
  • Uses Usually used to study excited state dynamics of 1-nitropthalene in nonpolar, aprotic and protic solvents.
  • Uses 1-Nitronaphthalene as a nitroaromatic compound is studied for mutagenicity, as nitroaromatics are used in everyday products from polmers, dyes to drugs.
  • Definition ChEBI: A mononitronaphthalene substituted by a nitro group at position 1.
  • Production Methods One method to product 1-Nitronaphthalene: Naphthalene is charged to sulfuric acid alternately with mixed acid at 40 – 50 ℃ over 8 h, with the final temperature being 55 ℃. The acid strength used allows the molten product to be separated as an oil and washed. Continuous operation at 50 – 60 ℃ with mixed acid (33/48/19) gives a comparable product. The crude reaction product is obtained in 90 – 95 % yield and is purified by vacuum distillation.
  • General Description 1-Nitronaphthalene is a mutagenic nitroaromatic compound present in diesel exhaust and it causes acute liver and lung toxicity in rodents. 1-Nitronaphthalene is a cytochrome P450-bioactivated, nonciliated bronchiolar epithelial (Clara) cell cytotoxicant .
  • Biochem/physiol Actions 1-Nitronaphthalene binds covalently to protein and forms adducts in the rat airway epithelium in vivo.
  • Safety Profile Poison by intraperitoneal route. Mutation data reported. A skin, eye, and mucous membrane irritant. Flammable solid and combustible liquid when exposed to heat or flame. To fight fire, use CO2, dry chemical, or water spray. Explosive reaction with nitric acid + sulfuric acid above 60°C. Forms a sensitive explosive mixture with tetranitromethane. When heated to decomposition it emits toxic fumes of NOx. See also 2-NITRONAPHTHALENE and NITRO COMPOUNDS OF AROMATIC HYDROCARBONS.
  • Purification Methods Fractionally distil 1-nitronaphthalene under reduced pressure, then crystallise it from EtOH, aqueous EtOH or heptane. Chromatograph it on alumina with *benzene/pet ether as eluent. It sublimes in vacuo. The 1:1 picrate complex has m 72o (from EtOH). [Beilstein 5 H 553, 5 III 1593, 5 IV 1673.]
1-Nitronaphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
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1-Nitronaphthalene Spectrum
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