Reaction
ChemicalBook > CAS DataBase List > (3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN

(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN

Reaction
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Structure
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
  • CAS No.610304-81-9
  • Chemical Name:(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
  • CBNumber:CB1777828
  • Molecular Formula:C52H48P2
  • Formula Weight:734.89
  • MOL File:610304-81-9.mol
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Property
  • Melting point >300 °C (dec.)(lit.)
  • form Powder
  • color white to light yellow
  • Sensitive air sensitive
  • CAS DataBase Reference 610304-81-9
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal word
  • Hazard statements
  • Precautionary statements

(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Chemical Properties,Usage,Production

  • Reaction
    1. Rhodium complex used in asymmetric hydroformylation reactions.
    2. Ligand-palladium complex used in enantioselective carbonyl-ene reactions.
    3. Nickel-catalyzed asymmetric transfer hydrogenation of olefins for the synthesis of αand βamino acids.
    4. Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines.
    5. Nickel/ligand catalyst used in the enantioselective reductive amination of ketones with both arylamines and benzhydrazide,
    6. Rh-Binapine and Pd-Binapine complexes form excellent catalysts for asymmetric (transfer) hydrogenation of aryl substituted olefins to form β-amino acids.
    Reactions of 610304-81-9_1
    Reactions of 610304-81-9_2
    Reactions of 610304-81-9_3
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Preparation Products And Raw materials
Raw materials
Preparation Products
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Suppliers
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(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Spectrum
610304-81-9, (3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPINRelated Search:
  • Asymmetric Synthesis
  • ChiralQuest Ligands
  • Chiral Catalysts, Ligands, and Reagents
  • Privileged Ligands
  • (3S,3'S)-4,4'-二叔丁基-4,4',5,5'-四氢-3H,3'H-3,3'-联萘[2,1-C:1',2'-E]膦
  • 联苯胺(混合物)
  • 二叔丁基四氢联二萘磷
  • 610304-81-9
  • (3S,3'S)-4,4'-di-tert-butyl-4,4',5,5'-tetrahydro-3H,3'H-3,3'-bidinaphtho[2,1-c:1',2'-e]phosphepine
  • BINAPINE (Mixture)
  • (3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin,97%(S)-BINAPINE
  • (S)-BINAPINE
  • (3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
  • (3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin (S)-BINAPINE

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