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FEMA 2860

CAS No.94-47-3
Chemical Name:FEMA 2860
CBNumber:CB1283363
Molecular Formula:C15H14O2
Formula Weight:226.27
MOL File:94-47-3.mol

FEMA 2860 Property

Boiling point 182 °C12 mm Hg(lit.)
Density 1.093 g/mL at 25 °C(lit.)
vapor pressure 0.015Pa at 25℃
refractive index n20/D 1.56(lit.)
FEMA 2860 | PHENETHYL BENZOATE
Flash point >230 °F
solubility Insoluble in water, soluble in alcohol and oils.
form Liquid
color Clear colorless
Odor at 100.00 %. soft rose balsam honey floral
Odor Type floral
biological source synthetic
Viscosity 27.738mm2/s
Water Solubility 207.21mg/L at 25℃
LogP 3.815 at 25℃
CAS DataBase Reference 94-47-3
Substances Added to Food (formerly EAFUS) PHENETHYL BENZOATE
FDA 21 CFR 172.515
EWG's Food Scores 1
FDA UNII 0C143929GK
EPA Substance Registry System Benzoic acid, 2-phenylethyl ester (94-47-3)
UNSPSC Code 12164502
NACRES NA.21

Safety

WGK Germany :2
RTECS :DH6288000
HS Code :29163100
Toxicity :The acute oral LD₅₀ in rats was reported to be 5 g/kg and the acute dermal LD₅₀ in rabbits exceeded 5 g/kg (Wohl 1974).

NFPA 704:

	1
1		0

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordWarning
Hazard statements H411
Precautionary statements P273-P391-P501

FEMA 2860 Price More Price(2)

Brand: Sigma-Aldrich(India)
Product number: W286001
Product name : Phenethyl benzoate
Purity: ≥99%, FG
Packaging: 1SAMPLE-K
Price: ₹5141.88
Updated: 2022/06/14
Buy: Buy

Brand: ottokemi
Product number: P 1659
Product name : Phenyl ethyl benzoate
Purity:
Packaging: 500gm
Price: ₹2979
Updated: 2022/05/26
Buy: Buy

FEMA 2860 Chemical Properties,Usage,Production

Chemical Properties Phenethyl benzoate has a sweet, rose and honey-like odor. It is used in trace quantities for fixation of honey, strawberry and other fruit preserves.
Chemical Properties Clear colorless liquid
Occurrence Reported found in the essential oil from flowers of rose and orange, in bilberry, cinnamon leaf, cassia leaf, malay apple and sea buckthorn.
Uses Phenethyl Benzoate is a building block used in the synthetic preparation of esters using Bi(OTf)3 catalyzed acylation of alcohols with acid anhydrides.
Preparation From phenethyl alcohol and benzoyl chloride in the presence of NaOH; from phenylethyl alcohol and methylbenzoate; by esterification of phenylethyl acohol with benzoic acid.
Definition ChEBI: Phenethyl benzoate is a benzoate ester resulting from the formal condensation of the carboxy group of benzoic acid with the hydroxy group of 2-phenylethanol. It has a role as a plant metabolite and a volatile oil component. It is functionally related to a benzoic acid and a 2-phenylethanol.
Application Phenylethyl Benzoate is used in Carnation, Neroli, Rose and Oriental bases mostly as a fixative and a blender/modifier in the heavier portion of the fragrance. It is a good base for Peony and other delicate florals and blends well with most of the conventional “middle notes”. This material is also used in flavour compositions in minute traces for fixation of Honey, Strawberry and various fruit types. The concentration is normally as low as 1 to 4 ppm in the finished product.
Flammability and Explosibility Not classified
Metabolism The metabolism of benzoic acid has been extensively studied in more than 20 species, including man (Williams, 1959). Depending on species and other factors, such as availability of glycine, benzoic acid may be excreted in the urine as hippuric acid, benzoyl glucuronide or other compounds (see, for example, Bridges. French. Smith & Williams, 1970; Irjala, 1972; Kato, 1972; Martin, 1966; Runyan, 1971; Strahl & Barr, 1971; Wan & Riegelman, 1972). The major route of biotransformation of benzoic acid in man is conjugation with glycine to form hippuric acid, the rate-limiting factor in this reaction being the availability of glycine (Amsel & Levy. 1969). In man at a dose of 1 mg/kg, benzoic acid is excreted entirely as hippuric acid (Bridges et al. 1970). Phenylethyl alcohol is oxidized almost entirely to phenylacetic acid (Williams, 1959). In rabbits, a small amount of benzoic acid is also formed; the phenylacetic acid is excreted mainly as phenaceturic acid (Smith, Smithies & Williams, 1954).