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Hafnium(IV) chloride Structure

Hafnium(IV) chloride

  • Product NameHafnium(IV) chloride
  • CAS13499-05-3
  • CBNumberCB0731544
  • MFCl4Hf
  • MW320.3
  • EINECS236-826-5
  • MDL NumberMFCD00011034
  • MOL File13499-05-3.mol

Chemical Properties

Melting point: 432 °C (lit.)
Boiling point: 315.47°C (estimate)
Density  1.89 g/cm3
vapor pressure  1 mm Hg ( 190 °C)
storage temp.  Inert atmosphere,Room Temperature
solubility  Soluble in methanol and acetone.
form  Powder
color  White
Water Solubility  Soluble in water, methanol and acetone.
Specific Heat Capacity Cp(crystal): 0.38 J/(g·K), at 25℃
Sensitive  Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Merck  14,4588
crystal system Monoclinic
Space group P2/c
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.63270.73770.6290109.05900.2735
Exposure limits ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
InChI 1S/4ClH.Hf/h4*1H;/q;;;;+4/p-4
InChIKey PDPJQWYGJJBYLF-UHFFFAOYSA-J
SMILES Cl[Hf](Cl)(Cl)Cl
CAS DataBase Reference 13499-05-3(CAS DataBase Reference)
EPA Substance Registry System Hafnium chloride (HfCl4), (T-4)- (13499-05-3)

Safety

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H290-H314
Precautionary statements  P234-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3260 8/PG 2
WGK Germany  3
F  9-21
TSCA  TSCA listed
HazardClass  8
PackingGroup  II
HS Code  28273985
Storage Class 8B - Non-combustible corrosive hazardous materials
Hazard Classifications Eye Dam. 1
Met. Corr. 1
Skin Corr. 1B
REACH Registrations Active
Limited Quantities 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704:
0
3 0
W

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