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(-)-Camphanic acid chloride

(-)-Camphanic acid chloride Structure
(-)-Camphanic acid chloride
  • CAS No.39637-74-6
  • Chemical Name:(-)-Camphanic acid chloride
  • CBNumber:CB0352910
  • Molecular Formula:C10H13ClO3
  • Formula Weight:216.66
  • MOL File:39637-74-6.mol
(-)-Camphanic acid chloride Property
  • Melting point 71-73 °C(lit.)
  • alpha -18 º (c=2, CCl4)
  • Boiling point 310.92°C (rough estimate)
  • Density 1.2072 (rough estimate)
  • refractive index 1.5390 (estimate)
  • storage temp. 2-8°C
  • solubility soluble in Dichloromethane, Ether, Ethyl Acetate, Methanol
  • form Powder
  • color Yellow to orange-brown
  • optical activity [α]23/D 18°, c = 2 in carbon tetrachloride
  • Water Solubility decomposes
  • Sensitive Moisture Sensitive
  • BRN 3590860
  • InChIKey PAXWODJTHKJQDZ-RGURZIINSA-N
  • CAS DataBase Reference 39637-74-6(CAS DataBase Reference)
  • UNSPSC Code 23151817
  • NACRES NA.22
Safety
  • Hazard Codes  :C,Xi
  • Risk Statements  :34-29
  • Safety Statements  :26-36/37/39-45-8-27
  • RIDADR  :UN 3261 8/PG 2
  • WGK Germany  :3
  • F  :10-21
  • HazardClass  :8
  • PackingGroup  :II
  • HS Code  :29322090
  • NFPA 704:
    1
    3 2
    W
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H314
  • Precautionary statements P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
(-)-Camphanic acid chloride Price More Price(8)
  • Brand: Sigma-Aldrich(India)
  • Product number: 226173
  • Product name : (1S)-(−)-Camphanic chloride
  • Purity: 98%
  • Packaging: 1G
  • Price: ₹1677.88
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 226173
  • Product name : (1S)-(−)-Camphanic chloride
  • Purity: 98%
  • Packaging: 5G
  • Price: ₹7122.85
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 21287
  • Product name : (1S)-(−)-Camphanic chloride
  • Purity: for chiral derivatization, LiChropur?, ≥98.0%
  • Packaging: 5G
  • Price: ₹17363.3
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: C1022
  • Product name : (-)-Camphanic Chloride
  • Purity: min. 96.0 %
  • Packaging: 1G
  • Price: ₹2700
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: C1022
  • Product name : (-)-Camphanic Chloride
  • Purity: min. 96.0 %
  • Packaging: 5G
  • Price: ₹4400
  • Updated: 2022/05/26
  • Buy: Buy

(-)-Camphanic acid chloride Chemical Properties,Usage,Production

  • Chemical Properties Off-White Powder
  • Uses (1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
  • Uses An optically active resolving agent
  • Uses (1S)-(-)-Camphanic chloride may be used in esterification of enantiomers in volatiles releasedf from wheat, in order to determine the proportion of enantiomers and also in quantifying the esters.
  • General Description (1S)-(-)-Camphanic chloride is a chiral derivatizing agent. It can be prepared by reacting (-)-(1S,4R)-camphanic acid with thionyl chloride.
  • Purification Methods It is soluble in toluene (50g/100mL at 0o) and crystallises from pet ether (b 40-60o). It sublimes at 70o/5mm, Store it dry at 0o, max (CCl4) 1805s and 1780m cm-1. Armarego et al. J Chem Soc, Perkin Trans I 2229 1976, Gerlach Helv Chim Acta 51 1587 1968, Gerlach Helv Chim Acta 68 1815 1985, Beilstein 18/8 V 101.]
(-)-Camphanic acid chloride Preparation Products And Raw materials
Raw materials
Preparation Products
(-)-Camphanic acid chloride Suppliers
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(-)-Camphanic acid chloride Spectrum
39637-74-6, (-)-Camphanic acid chlorideRelated Search:
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  • C10H13O3Cl
  • C10H13ClO3
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  • (-)-氯代樟脑酸, 试剂级
  • (-)-CAMPHANIC CHLORIDE (-)-莰烷酰氯
  • (1S)-4,7,7-三甲基-3-氧代-2-氧双环[2.2.1]庚烷-1-碳酰氯
  • (1S)-(-)-莰烷氯
  • (-)-樟脑酸氯化物
  • (-)-(1S,4R)-坎烷酰氯
  • (1S)-3-氧代-4,7,7-三甲基-2-氧杂双环[2.2.1]庚烷-1-甲酰氯
  • (1S)-(-)-莰烷酰氯
  • (-)-樟脑酸氯
  • 莰烷氯
  • 氯代樟脑酸
  • (1S)-(-)-莰烷氯,95%
  • (-)-莰烷酰氯
  • (-)-氯代樟脑酸
  • (-)莰烷酰氯
  • (-)-(1S,4R)-坎烷酰氯,98%
  • (-)-CAMPHANOYL CHLORIDE氯代樟脑酸
  • (1S)-(-)-莰烷酸氯化物
  • (+)-(1R,4S)-莰烷酰氯
  • 39637-74-6
  • (1<i>S</i>)-(?)-Camphanic chloride
  • (-)-(1S,4R)-Camphanoyl Chloride
  • (-)-Camphanic Chloride
  • (4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carbonyl chloride

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