ChemicalBook > CAS DataBase List > (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL

(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL

(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL Structure
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
  • CAS No.38345-66-3
  • Chemical Name:(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
  • CBNumber:CB0251222
  • Molecular Formula:C19H25NO
  • Formula Weight:283.41
  • MOL File:38345-66-3.mol
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL Property
Safety
  • WGK Germany  :3
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H302
  • Precautionary statements P264-P270-P301+P312-P330-P501
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL Price More Price(2)
  • Brand: Sigma-Aldrich(India)
  • Product number: 227404
  • Product name : Chirald®
  • Purity: 99%
  • Packaging: 10G
  • Price: ₹31035.28
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 227404
  • Product name : Chirald®
  • Purity: 99%
  • Packaging: 50G
  • Price: ₹105597.88
  • Updated: 2022/06/14
  • Buy: Buy

(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL Chemical Properties,Usage,Production

  • Uses Reducing reagent in organic synthesis.
  • Purification Methods Purify the hydrochloride by dissolving 1.5g in 13.5 mL of 5N HCl, heat to boiling and evaporate in a vacuum. Recrystallise the hydrochloride three times from MeOH/EtOAc giving m 189-190o, []D -33.7o (c 1, H2O) {enantiomer has +34.2o}. The hydrochloride in the minimum volume of water is basified with aqueous 5N NaOH and extracted with Et2O. The extract is dried (K2CO3) and evaporated, leaving a residue which is stored in a desiccator over solid KOH as a low melting solid. It can be recovered using these procedures from asymmetric reductions with LAH, and re-used. [Pohland & Sullivan J Am Chem Soc 77 3400 1955, Sullivan et al. J Org Chem 28 2483 1963, Beilstein 13 IV 2221.]
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL Preparation Products And Raw materials
Raw materials
Preparation Products
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(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL Spectrum
38345-66-3, (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOLRelated Search:
  • 高端化学
  • Amino Alcohols
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Organic Building Blocks
  • 右丙氧芬杂质A(EP) 标准品
  • (2S,3R)-(+)-4-二甲基氨基-1,2-二苯基-3-甲基-2-丁醇
  • (2S,3R)-(+)-4-二甲氨基-1,2-二苯基-3-甲基-2-丁醇
  • 38345-66-3
  • (+)-(2S,3R)-4-dimethylamino-3-methyl-1,2 -diphenyl-2-butanol
  • Chirald<sup><sup>?</sup></sup>
  • Codeine Phosphate Impurity 14
  • Dextropropoxyphene Hydrochloride EP Impurity A
  • (2S,3R)-4-(dimethylamino)-1,2-diphenyl-3-methyl-butan-2-ol (oxyphene),
  • Propoxyphene USP Related Compound A
  • Dextropropoxyphene EP Impurity A
  • Benzeneethanol, α-[(1R)-2-(dimethylamino)-1-methylethyl]-α-phenyl-, (αS)-
  • (2S,3R)-4-(Dimethylamino)-1,2-diphe
  • (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol, (2S,3R)-(+)-4-Dimethylamino-3-methyl-1,2-diphenyl-2-butanol, Dextrocarbinol base
  • (2S,3R)-4-(dimethylamino)-3-methyl-1,2-diphenylbutan-2-ol
  • CHIRALD(R)
  • DEXTROCARBINOL BASE
  • (+)-(2S,3R)-4-DIMETHYLAMINO-3-METHYL-1,2-DIPHENYL-2-BUTANOL
  • (2S,3R)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
  • (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
  • Oxiphene
  • Mosher'S reagent
  • Einecs 253-893-6
  • Darvon alcohol
  • α-(+)-Oxyphene
  • (αS)-α-Phenyl-α-[(R)-1-(dimethylaminomethyl)ethyl]benzeneethanol
  • (αS)-α-[(1R)-2-(Dimethylamino)-1-methylethyl]-α-phenylbenzeneethanol
  • (2S,3R)-1,2-Diphenyl-3-methyl-4-(dimethylamino)-2-butanol
  • Dextrocarbinol base, (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol
  • Dextrocarbinol base, (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol, (2S,3R)-(+)-4-Dimethylamino-3-methyl-1,2-diphenyl-2-butanol
  • (2S,3R)-4-(DIMETHYLAMINO)-3-METHYL-1,2-DIPHENYLBUTAN-2-OL, TOLUENE SOLUTION
  • D-OXYPHENE
  • chirald tm
  • DEXTROOXYPHENE
  • [S-(R*,S*)]-alpha-[2-(dimethylamino)-1-methylethyl]-alpha-phenylphenethyl alcohol
  • chirald
  • 2-S-3-R-plus-4-dimethylamino-1-2-*diphenyl-3-meth