(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE

Reaction

1. Ligand for Iridium-catalyzed enantio- and diastereoselective reductive aldol reactions
2. Ligand for Scandium-catalyzed asymmetric Nazarov reactions
3. Ligand for Scandium-catalyzed enantioselective pyrrole alkylations of α,β-unsaturated 2-acyl imidazoles
4. Ligand for Scandium-catalyzed enantioselective Friedel-Crafts Alkylations
5. Ligand for Nickel-catalyzed asymmetric cross-couplings of racemic propargyl groups with arylzinc reagents
6. Ligand for Scandium-catalyzed enantioselective intramolecular carbonyl-ene reaction, the synthesis of (+)-triptophenolide
7. Ligand for Scandium-catalyzed asymmetric synthesis of substituted 3-hydroxy-2-oxindoles
8. Ligand for Indium-catalyzed enantio- and regioselective addition of pyrroles to isatins
9. Ligand for Scandium-catalyzed asymmetric [3+2] annulation of allylsilanes with isatins in the synthesis of spirooxindoles
10. Ligand for Scandium-catalyzed enantioselective allylation of isatins using allylsilanes
11. Ligand for Scandium-catalyzed enantioselective carboannulation with allylsilanes

Chemical Properties

Uses

• Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
• Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
• Chiral N,N,N-tridentate pybos and pyboxazine ligands