Reaction
ChemicalBook > CAS DataBase List > (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

Reaction
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Structure
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • CAS No.443965-10-4
  • Chemical Name:(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • CBNumber:CB6285478
  • Molecular Formula:C19H20NO2P
  • Formula Weight:325.34
  • MOL File:443965-10-4.mol
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Property
  • Melting point: :95-96°C
  • alpha  :-502° (c 0.5, CH2Cl2)
  • Boiling point: :429.6±55.0 °C(Predicted)
  • storage temp.  :-20°C
  • pka :2.19±0.20(Predicted)
  • form  :solid
  • color  :white
  • Sensitive  :moisture sensitive
Safety
  • HS Code  :29252900
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal word
  • Hazard statements
  • Precautionary statements
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Price More Price(2)
  • Brand: Strem Chemicals
  • Product number: 15-5151
  • Product name : (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (S)-SIPHOS
  • Purity: 
  • Packaging: 100mg
  • Price: $91
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: Strem Chemicals
  • Product number: 15-5151
  • Product name : (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (S)-SIPHOS
  • Purity: 
  • Packaging: 500mg
  • Price: $364
  • Updated: 2021/03/22
  • Buy: Buy

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties,Usage,Production

  • Reaction
    1. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
    2. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
    3. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
    4. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
    5. Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
    6. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes. 


  • Chemical Properties White to light yellow powder
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Preparation Products And Raw materials
Raw materials
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443965-10-4, (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINERelated Search:
  • (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
  • N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
  • (R)-SIPHOS
  • (S)-SIPHOS
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(S)-SIPHOS
  • N-DIMETHYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (S)-SIPHOS
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-dimethylamine, N-Dimethyl-[(S)-1,1μ-spirobiindane-7,7μ-diyl]phosphoramidite
  • N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98%
  • Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-dimethyl-, (11aS)- (9CI)
  • N,N-Dimethylphosphoramidousacid (1S)-(2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl) ester
  • (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine
  • (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,99%e.e.
  • (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (S)-SIPHOS
  • 1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • SF120132
  • Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-dimethyl-, (11aS)-
  • 443965-10-4
  • Chiral Phosphine
  • Chiral Spiro Ligand
  • CPN