Uses
1,3-Cyclopentanediol was used in the synthesis of 1,3-cyclopentanediol
bis(4-methylbenzenesulfonate) and β-hydroxy-substituted cyclic carbonyl compounds. It was also used in direct enantiomer resolution of diols without derivatization on a chiral polysiloxane by capillary gas chromatography.
References
[1] LI G, LI N, ZHENG M, et al. Industrially scalable and cost-effective synthesis of 1,3-cyclopentanediol with furfuryl alcohol from lignocellulose[J]. Green Chemistry, 2016, 12: 3607-3613. DOI:
10.1039/C6GC00341A.
[2] KOUJI. NAKAMURA. Direct resolution of enantiomeric diols by capillary gas chromatography on a chiral polysiloxane derived from (R,R)-tartramide[J]. Analytical Chemistry, 1990, 62 5: 539-541. DOI:10.1021/ac00204a022.
[3] ANNE PAJU . Direct asymmetric α-hydroxylation of 2-hydroxymethyl ketones[J]. Tetrahedron, 2002, 58 36: Pages 7321-7326. DOI:
10.1016/S0040-4020(02)00760-3.
[4] NOORDZIJ G J, DIETZ C H J T, LEONé N, et al. Small-scale screening of novel biobased monomers: the curious case of 1,3-cyclopentanediol[J]. RSC Advances, 2018, 70: 39818-39828. DOI:10.1039/C8RA08811J.
[5] R. HENLY . The influence of protecting groups on lipase catalyzed transesterifications: Enzymatic resolution of racemic cis-1,3-cyclopentanediol derivatives[J]. Tetrahedron Letters, 1993, 34 18: Pages 2923-2926. DOI:
10.1016/S0040-4039(00)60482-3.
