ChemicalBook CAS DataBase List N-Methyl-4-nitroaniline

N-Methyl-4-nitroaniline

Product NameN-Methyl-4-nitroaniline
CAS100-15-2
CBNumberCB1387643
MFC7H8N2O2
MW152.15
EINECS202-823-2
MDL NumberMFCD00007305
MOL File100-15-2.mol
MSDS FileSDS

Chemical Properties

Melting point	149-151 °C(lit.)
Boiling point	294.61°C (rough estimate)
Density	1.2010
vapor density	5.25 (vs air)
refractive index	1.6276 (estimate)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Solid
pka	0.56±0.12(Predicted)
color	Yellow to Very Dark Yellow
Water Solubility	<0.1 g/100 mL at 19 ºC
BRN	637920
Stability	Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey	XIFJZJPMHNUGRA-UHFFFAOYSA-N
CAS DataBase Reference	100-15-2(CAS DataBase Reference)
FDA UNII	J836WLV9BW
NIST Chemistry Reference	Benzenamine, N-methyl-4-nitro-(100-15-2)
EPA Substance Registry System	N-Methyl-p-nitroaniline (100-15-2)

Safety

Symbol(GHS)

Signal word

Danger

Hazard statements

H301+H311+H331-H373-H412

Precautionary statements

P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314

Hazard Codes

T,Xi

Risk Statements

23/24/25-33-36/37/38

Safety Statements

28-36/37/39-45-26

RIDADR

2811

WGK Germany

Hazard Note

Highly Toxic/Irritant

TSCA

Yes

HazardClass

6.1

PackingGroup

III

HS Code

29214200

NFPA 704:

	1
3		0

N-Methyl-4-nitroaniline Price

Product number	Packaging	Price	Product description	Buy
Sigma-Aldrich 269638	25g	$51.5	N-Methyl-4-nitroaniline 97%	Buy
Sigma-Aldrich 269638	100g	$161	N-Methyl-4-nitroaniline 97%	Buy
Alfa Aesar A15548	5g	$37.3	N-Methyl-4-nitroaniline, 97%	Buy
Alfa Aesar A15548	25g	$133	N-Methyl-4-nitroaniline, 97%	Buy
Alfa Aesar A15548	100g	$439	N-Methyl-4-nitroaniline, 97%	Buy

N-Methyl-4-nitroaniline Chemical Properties,Usage,Production

Uses

N-methyl-4-nitroaniline is a stabilizer for gunpowder, a desensitizing agent for molten cast explosive TNAZ, a widely used organic intermediate, and N-methyl-4-nitroaniline can be used as a reference substance by its polarizing properties.
N-methyl-4-nitroaniline is an attractive candidate for its appealing capability to retain the nitrogen oxides, good thermal stability, and facile synthesis from abundant and inexpensive starting materials.

Biodegradation

N-Methyl-4-nitroaniline is used as an additive to lower the melting temperature of energetic materials in the synthesis of insensitive explosives. Although the biotransformation of N-Methyl-4-nitroaniline under anaerobic condition has been reported, its aerobic microbial degradation has not been documented yet. A soil microcosms study showed the efficient aerobic degradation of N-Methyl-4-nitroaniline by the inhabitant soil microorganisms.

Chemical Properties

brownish-yellow crystalline powder

Uses

N-Methyl-4-nitroaniline is a versatile reactant used in the synthesis of oxindoles using Pd-catalyzed cyclization of chloroacetanilides.

General Description

Brownish-yellow prisms with violet reflex (from ethanol) or yellow powder.

Air & Water Reactions

N-Methyl-4-nitroaniline may be sensitive to prolonged exposure to air. Insoluble in water.

Reactivity Profile

N-Methyl-4-nitroaniline has a vigorous exothermic reaction with carbaryl sulfate when heated above 167° F.

Fire Hazard

Flash point data for N-Methyl-4-nitroaniline are not available; however, N-Methyl-4-nitroaniline is probably combustible.

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Yingrui Biopharma Co.,Ltd	21-33585366	export01@shyrchem.com	CHINA	1319	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5857	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5889	58
Hebei Weibang Biotechnology Co., Ltd	+8617732866630	bess@weibangbio.com	China	18151	58
Anhui Ruihan Technology Co., Ltd	+8617756083858	daisy@anhuiruihan.com	China	973	58
hebei hongtan Biotechnology Co., Ltd	+86-86-1913198-3935 +8617331935328	sales03@chemcn.cn	China	970	58
Hebei Zhuanglai Chemical Trading Co Ltd	+86-16264648883 +86-16264648883	niki@zlchemi.com	China	3001	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
Hangzhou FandaChem Co.,Ltd.	+8615858145714	FandaChem@Gmail.com	China	8936	55

N-Methyl-4-nitroaniline

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N-Methyl-4-nitroaniline Chemical Properties,Usage,Production

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