Bariumsulfid

Bezeichnung:Bariumsulfid

CAS-Nr21109-95-5

Englisch Name:BARIUM SULFIDE

CBNumberCB9220421

SummenformelBaHS

Molgewicht170.4

MOL-Datei21109-95-5.mol

Synonyma

Bariumsulfid

Bariumsulfid physikalisch-chemischer Eigenschaften

Schmelzpunkt

1200°C

Dichte

4.25 g/mL at 15 °C(lit.)

Aggregatzustand

Powder

Wichte

4.25

Farbe

Pale gray to yellow

Wasserlöslichkeit

Soluble in water but insoluble in alcohol.

Sensitive

Moisture Sensitive

Crystal Structure

NaCl type

crystal system

Cube

Merck

14,995

Space group

Fm3m

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.6388	0.6388	0.6388	90	90	90	0.2607

Stabilität

Stable, but decomposes on heating. Incompatible with acids, oxidizing agents, water.

CAS Datenbank

21109-95-5(CAS DataBase Reference)

NIST chemische Informationen

Barium sulfide(21109-95-5)

EPA chemische Informationen

Barium sulfide (21109-95-5)

Sicherheit

Kennzeichnung gefährlicher	Xn,N,Xi,C
R-Sätze:	20/22-31-50-36/37/38-41-35
S-Sätze:	28-61
RIDADR	UN 2813 4.3/PG 2
WGK Germany	2
TSCA	Yes
HazardClass	4.3
PackingGroup	III
HS Code	2830908500

Gefahreninformationscode (GHS)

BARIUM SULFIDE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R20/22:Gesundheitsschädlich beim Einatmen und Verschlucken.
R31:Entwickelt bei Berührung mit Säure giftige Gase.
R50:Sehr giftig für Wasserorganismen.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Chemische Eigenschaften
colourless crystals, or white to grey-brown powder,
Physikalische Eigenschaften
Colorless crystalline solid; density 4.25 g/cm³; refractive index 2.155; melts at 1,200°C; soluble in water (decomposes); insoluble in alcohol.
Occurrence
Barium sulfide occurs in the form of black ash, which is a gray to black impure product obtained from high temperature carbonaceous reduction of barite. It is the starting material in the manufacture of most barium compounds including barium chloride and barium carbonate. It is used in luminous paints; for dehairing hides; as a flame retardant; and for generating H2S.
Verwenden
Barium sulfide has different characters, so it is used in a variety of ways, such as in electronics, paint pigments, dehairing hides, flame retardant, luminous paints, and generating pure hydrogen sulfide. Barium sulfide can deviate X-rays and helps to give clearly image of the soft tissue. Barium sulfide is a precursor to other barium compounds and also used as a short wavelength emitters for electronic displays.
Verwenden
As depilatory; in luminous paints; manufacture of lithopone; vulcanizing rubber, generating H2S.
synthetische
Barium sulfide can be prepared by the direct reaction of the elements, calcined in an inert atmosphere, at a 1:1.05 molecular ratio:
Ba＋S＋heat→BaS
Barium sulfide is prepared commercially by heating barite (BaO) with coal or petroleum coke in a rotary kiln at 1000°C to 1250°C in an oxygen-free atmosphere. The product, black ash, is a gray or black powder containing carbonaceous impurities and unreacted barite. Barium sulfide is separated from impurities by extraction with hot water and filtration. Barium sulfide may also be made by high temperature reduction of barium sulfate with methane.
Vorbereitung Methode
Barium sulfide is grayish-white solid, formed by heating barium sulfate and carbon, reactive with H2O to form barium hydrosulfide, Ba(SH)2, solution. The latter is also made by saturation of barium hydroxide solution with H2S. Barium polysulfides are formed by boiling barium hydrosulfide with sulfur.
Allgemeine Beschreibung
Barium sulfide (BaS) is an inorganic compound that is used as a precursor in the production of barium compounds. These compounds can be used in a variety of applications, such as ceramics, luminous paints, additives, and flame retardants.
Hazard
Highly toxic by ingestion (see Barium).
Flammability and Explosibility
Non flammable
Sicherheitsprofil
A poison. Flammable by spontaneous chemical reaction, air, moisture, or acid fumes may cause it to ignite. For explosion and disaster hazards, see SULFIDES. To fight fire, use CO2, dry chemical. Reacts violently with phosphorus(V) oxide. Mxtures with lead dioxide, potassium chlorate, or potassium nitrite explode when heated. Incompatible with Cl2O, Ca(NO3)2, r(NO3)2, Ca(ClO3)2, Sr(ClO3)2, (ClO3)2. See also BARIUM COMPOUNDS (soluble) and SULFIDES.

BARIUM SULFIDE Upstream-Materialien And Downstream Produkte

Bariumsulfid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

21109-95-5, BARIUM SULFIDE Verwandte Suche:

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