Monoperoxyphthalic acid magnesium salt hexahydrate Struktur

Monoperoxyphthalic acid magnesium salt hexahydrate

Bezeichnung:Monoperoxyphthalic acid magnesium salt hexahydrate

CAS-Nr84665-66-7

Englisch Name:Monoperoxyphthalic acid magnesium salt hexahydrate

CBNumberCB6457365

SummenformelC16H11MgO11-

Molgewicht403.56

MOL-Datei84665-66-7.mol

Monoperoxyphthalic acid magnesium salt hexahydrate physikalisch-chemischer Eigenschaften

Schmelzpunkt	93 °C (dec.)(lit.)
storage temp.	Sealed in dry,Room Temperature
Löslichkeit	DMSO, Methanol
Aggregatzustand	Solid
Farbe	White to Off-White
InChI	InChI=1S/2C8H6O5.Mg.H2O/c29-7(10)5-3-1-2-4-6(5)8(11)13-12;;/h21-4,12H,(H,9,10);;1H2/q;;+2;/p-3
InChIKey	WWOYCMCZTZTIGU-UHFFFAOYSA-L
SMILES	C(C1C=CC=CC=1C1O[O-][Mg+2]2([O-]OC(C3C=CC=CC=3C(=O)[O-])=O2)O=1)(=O)[O-].[H+].O
CAS Datenbank	84665-66-7(CAS DataBase Reference)

Sicherheit

Kennzeichnung gefährlicher	O,Xi
R-Sätze:	8-36/37/38
S-Sätze:	26
WGK Germany	3
HS Code	29173990

Gefahreninformationscode (GHS)

Monoperoxyphthalic acid magnesium salt hexahydrate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R8:Feuergefahr bei Berührung mit brennbaren Stoffen.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
White Granules
Verwenden
Reagent for:
- Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
- Oxidation rections under mild conditions
- Epoxidation of unsaturated steroids
- Synthesis of ring-B oxygenated steroids as anticancer agents
Verwenden
Monoperoxyphthalic acid magnesium salt hexahydrate is used as disinfectant for hard surfaces (hospital, food industrial, institution).
Allgemeine Beschreibung
Magnesium monoperoxyphthalate hexahydrate is an organic peroxide used in many oxidation reactions. It exhibits non-deflagrating and non-shock-sensitive properties and also used as a surface disinfectant.
läuterung methode
MMPP is a safer reagent than m-chloroperbenzoic acid for oxidation reactions because it is not as explosive and has advantages of solubility. It is soluble in H2O, low-molecular-weight alcohols, i-PrOH and DMF. The product of reaction, Mg phthalate, is soluble in H2O. It has been used in aqueous phase to oxidise compounds in e.g. CHCl3 and using a phase transfer catalyst, e.g. methyltrioctylammonium chloride [Brougham Synthesis 1015 1987]. The oxidising activity can be checked (as for perbenzoic acid in Silbert et al. Org Synth Coll Vol V 906 1973], and if found to be low it would be best to prepare afresh from phthalic anhydride (1mol), H2O2 (1mol) and MgO at 20-25o to give MMPP. [Hignett, European Pat Appl 27 693 1981, Chem Abstr 95 168810 1981, Beilstein 9 IV 3260.]

Monoperoxyphthalic acid magnesium salt hexahydrate Upstream-Materialien And Downstream Produkte

Monoperoxyphthalic acid magnesium salt hexahydrate Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

84665-66-7, Monoperoxyphthalic acid magnesium salt hexahydrate Verwandte Suche:

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