3-Iodpropen

Bezeichnung:3-Iodpropen

CAS-Nr556-56-9

Englisch Name:ALLYL IODIDE

CBNumberCB6186678

SummenformelC3H5I

Molgewicht167.98

MOL-Datei556-56-9.mol

Synonyma

3-Iodpropen

3-Iodpropen physikalisch-chemischer Eigenschaften

Schmelzpunkt	-99 °C
Siedepunkt	102103°C
Dichte	1.837 g/mL at 25 °C(lit.)
Brechungsindex	n20/D 1.554
Flammpunkt	65 °F
storage temp.	2-8°C
Löslichkeit	alcohol: miscible(lit.)
Aggregatzustand	Liquid
Farbe	Clear yellow to orange, red or red-brown
Wasserlöslichkeit	Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water.
Sensitive	Air & Light Sensitive
Merck	14,294
BRN	1697594
Henry's Law Constant	3.8×10^-3 mol/(m³Pa) at 25℃, Hilal et al. (2008)
Dielectric constant	6.1（19℃）
Expositionsgrenzwerte	ACGIH: TWA 0.01 ppm
InChI	1S/C3H5I/c1-2-3-4/h2H,1,3H2
InChIKey	HFEHLDPGIKPNKL-UHFFFAOYSA-N
SMILES	ICC=C
CAS Datenbank	556-56-9(CAS DataBase Reference)
EPA chemische Informationen	1-Propene, 3-iodo- (556-56-9)

Sicherheit

Kennzeichnung gefährlicher	C,T,F
R-Sätze:	10-34-11
S-Sätze:	7-26-45-16
RIDADR	UN 1723
WGK Germany	1
RTECS-Nr.	UD0450000
F	8-13
TSCA	TSCA listed
HazardClass	3
PackingGroup	II
HS Code	29033990
Speicherklasse	3 - Flammable liquids
Hazard Classifications	Acute Tox. 2 Oral Eye Dam. 1 Flam. Liq. 2 Skin Corr. 1B

Gefahreninformationscode (GHS)

ALLYL IODIDE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R10:Entzündlich.
R34:Verursacht Verätzungen.
S-Sätze Betriebsanweisung:
S7:Behälter dicht geschlossen halten.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Chemische Eigenschaften
clear orange, red or red-brown liquid
Verwenden
Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.
Synthesis Reference(s)
Synthetic Communications, 20, p. 41, 1990 DOI: 10.1080/00397919008054613
Allgemeine Beschreibung
A yellow liquid with a pungent odor. Denser than water and insoluble in water. Hence sinks in water. Vapors are heavier than air. Flash point is less than 75°F. Very irritating to skin, eyes and mucous membranes. Poisonous by ingestion and inhalation. Used to make other chemicals.
Air & Water Reaktionen
Highly flammable. Darkens on exposure to light and air liberating Iodine [Merck 11th ed. 1989]. Insoluble in water.
Reaktivität anzeigen
ALLYL IODIDE is moderately reactive. Incompatible with strong oxidizing and reducing agents. Also, incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
Health Hazard
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Brandgefahr
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Sicherheitsprofil
Poison by inhalation and ingestion. Mutation data reported. A powerful irritant. A flammable liquid. Incompatible with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits hghly toxic fumes of I-. See also ALLYL COMPOUNDS and IODIDES.
läuterung methode
Purify allyl iodide in a dark room by washing with aqueous Na2SO3 to remove free iodine, then dry with MgSO4 and distil at 43o/90 mm or at atmospheric pressure to give a very pale yellow liquid. (This material, dissolved in hexane, can be stored in a light-protected tight container at -5o for up to three months before free iodine could be detected, by its colour in the solution.) Store it away from light. [Sibbett & Noyes J Am Chem Soc 75 761 1953, Beilstein 1 H 202, 1 I 84, 1 II 172, 1 III 714, 1 IV 761.]

ALLYL IODIDE Upstream-Materialien And Downstream Produkte

3-Iodpropen Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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