1,3,5-TRIBENZYLHEXAHYDRO-1,3,5-TRIAZINE Struktur

1,3,5-Tribenzylhexahydro-1,3,5-triazin

Bezeichnung:1,3,5-Tribenzylhexahydro-1,3,5-triazin

CAS-Nr2547-66-2

Englisch Name:1,3,5-TRIBENZYLHEXAHYDRO-1,3,5-TRIAZINE

CBNumberCB3431861

SummenformelC24H27N3

Molgewicht357.49

MOL-Datei2547-66-2.mol

Synonyma

1,3,5-Tribenzylhexahydro-1,3,5-triazin

1,3,5-Tribenzylhexahydro-1,3,5-triazin physikalisch-chemischer Eigenschaften

Schmelzpunkt	49-51 °C(lit.)
Siedepunkt	100 °C0.005 mm Hg(lit.)
Dichte	113
Brechungsindex	1.6270 (estimate)
Flammpunkt	>230 °F
storage temp.	Sealed in dry,Room Temperature
pka	5.46±0.20(Predicted)
InChIKey	VWVZIRPJPFJGFE-UHFFFAOYSA-N

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	36/37/38
S-Sätze:	26-37/39
WGK Germany	3
HS Code	29336990

Gefahreninformationscode (GHS)

1,3,5-TRIBENZYLHEXAHYDRO-1,3,5-TRIAZINE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Verwenden
1,3,5-Tribenzylhexahydro-1,3,5-triazine is used as a reagent in the synthesis of phosphinic acid based NAALADase inhibitors which may potentially be used for the treatment of both neurodegenerative disorders and peripheral neuropathies.
Verwenden
1,3,5-Tribenzylhexahydro-1,3,5-triazine was used:
- in the synthesis of alkyl β-aminocarboxylates via trifluoromethanesulfonic acid catalyzed reaction with ketene silyl acetals
- as ligand to study the assembling process of a heterogeneous Cr-based single-site ethylene trimerization catalyst by X-ray absorption spectroscopy
- as ligand during conversion of Phillips Cr/SiO₂ polymerisation catalyst to ethylene trimerisation catalyst after assembling new active sites on the silica surface
Application
1,3,5-Tribenzylhexahydro-1,3,5-triazine was used:in the synthesis of alkyl β-aminocarboxylates via trifluoromethanesulfonic acid catalyzed reaction with ketene silyl acetals;as ligand to study the assembling process of a heterogeneous Cr-based single-site ethylene trimerization catalyst by X-ray absorption spectroscopy;as ligand during conversion of Phillips Cr/SiO2 polymerisation catalyst to ethylene trimerisation catalyst after assembling new active sites on the silica surface.
Synthese

To a round-bottomed flask (125 mL) equipped with a reflux condenser was added theappropriate amine (0.05 mmol), toluene (40 mL) and formaldehyde (37%, 4.1 mL).The solution was brought to reflux using an external oil bath and kept stirring for 30min. Then, the toluene was evaporated under reduced pressure, and the residue wasdissolved in ethyl acetate and washed with a saturated aqueous solution of sodiumchloride. After evaporation of the solvent under reduced pressure in a rotaryevaporator, the residue was purified by silica gel column chromatography usinghexane/ethyl acetate 9:1 as the eluent.

1,3,5-TRIBENZYLHEXAHYDRO-1,3,5-TRIAZINE Upstream-Materialien And Downstream Produkte

1,3,5-Tribenzylhexahydro-1,3,5-triazin Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

2547-66-2, 1,3,5-TRIBENZYLHEXAHYDRO-1,3,5-TRIAZINE Verwandte Suche:

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