4-Brombiphenyl

Bezeichnung:4-Brombiphenyl

CAS-Nr92-66-0

Englisch Name:4-Bromobiphenyl

CBNumberCB2489092

SummenformelC12H9Br

Molgewicht233.1

MOL-Datei92-66-0.mol

Synonyma

4-Brombiphenyl

4-Brombiphenyl physikalisch-chemischer Eigenschaften

Schmelzpunkt	82-86 °C(lit.)
Siedepunkt	310 °C(lit.)
Dichte	0.9327
Brechungsindex	1.6565 (estimate)
Flammpunkt	143 °C
storage temp.	Sealed in dry,Room Temperature
Löslichkeit	dioxane: soluble1g/10 mL, clear, colorless to very faintly yellow
Aggregatzustand	Crystalline Flakes
Farbe	Almost white to slightly yellow
Wasserlöslichkeit	Insoluble
BRN	1907453
Stabilität	Stable. Incompatible with oxidizing agents.
InChIKey	PKJBWOWQJHHAHG-UHFFFAOYSA-N
CAS Datenbank	92-66-0(CAS DataBase Reference)
NIST chemische Informationen	1,1'-Biphenyl, 4-bromo-(92-66-0)
EPA chemische Informationen	4-Bromobiphenyl (92-66-0)

Sicherheit

Kennzeichnung gefährlicher	Xi,N,Xn
R-Sätze:	36/37/38-50/53-41-37/38-22
S-Sätze:	22-24/25-37/39-26-61-60-39
RIDADR	UN 3152 9/PG 2
WGK Germany	3
RTECS-Nr.	DV1750100
TSCA	T
HazardClass	IRRITANT
PackingGroup	Ⅲ
HS Code	29036990

Gefahreninformationscode (GHS)

4-Bromobiphenyl Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
White powder
Verwenden
4-Bromobiphenyl is used as a reagent in the synthesis of spirooxindole derivatives for use as AMPK activators. It is also used as a reagent in the preparation of indenoindole derivatives as organic electroluminescent device materials.
Verwenden
4-Bromobiphenyl is used as halogenated hydrocarbon and Intermediates of Liquid Crystals. It is also used in used in the synthesis of 4-biphenylthiolate.
Allgemeine Beschreibung
Colorless crystals. Insoluble in water.
Air & Water Reaktionen
Insoluble in water.
Reaktivität anzeigen
4-Bromobiphenyl may be sensitive to light, and it can react with oxidizing materials.
Brandgefahr
Combustible.
Synthese
Into a 250 ml reactor equipped with magnetic agitation means, a condenser, a dropping funnel, and a thermometer, the following materials were introduced:
(i) 15.4 g biphenyl (0.1 M);
(ii) 100 ml solvent
at ambient temperature Then, over 10 min, the bromine was poured therein (39.2 g/0.22 M), whereupon the mixture was agitated for a varying period of time at ambient temperature. Upon completion of the reaction, the excess bromine was consumed by sodium or potassium sulfite or bisulfite. The organic phase was washed, dried and diluted to a given volume, and analyzed by CPG to give 4-Bromobiphenyl.
läuterung methode
Crystallise the biphenyl from abolute EtOH and dry it in vacuo.[Beilstein 5 IV 1819.]

4-Bromobiphenyl Upstream-Materialien And Downstream Produkte

4-Brombiphenyl Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

92-66-0, 4-Bromobiphenyl Verwandte Suche:

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