4-Aminoazobenzol

Bezeichnung:4-Aminoazobenzol

CAS-Nr60-09-3

Englisch Name:4-AMINOAZOBENZENE

CBNumberCB0380940

SummenformelC12H11N3

Molgewicht197.24

MOL-Datei60-09-3.mol

Synonyma

4-Aminoazobenzol

4-Aminoazobenzol physikalisch-chemischer Eigenschaften

Schmelzpunkt	123-126 °C(lit.)
Siedepunkt	>360 °C(lit.)
Dichte	1.2828 (rough estimate)
Brechungsindex	1.6500 (estimate)
Löslichkeit	Chloroform (Slightly), Methanol (Slightly)
Colour Index	11000
pka	2.82(at 25℃)
Farbe	Yellow crystals or orange needles with blue case from EtOH
Wasserlöslichkeit	29.59mg/L(25 ºC)
Merck	14,419
BRN	1913042
Stabilität	Stable. Incompatible with strong oxidizing agents.
CAS Datenbank	60-09-3(CAS DataBase Reference)
IARC	2B (Vol. 8, Sup 7) 1987
NIST chemische Informationen	Benzenamine, 4-(phenylazo)-(60-09-3)
EPA chemische Informationen	4-Aminoazobenzene (60-09-3)

Sicherheit

Kennzeichnung gefährlicher	T,N,Xi
R-Sätze:	45-50/53-36/37/38-20/21/22-46
S-Sätze:	53-45-60-61-36/37/39-26-22
RIDADR	UN 3077 9/PG 3
WGK Germany	3
RTECS-Nr.	BY8225000
HazardClass	IRRITANT
PackingGroup	III
HS Code	29270000
Giftige Stoffe Daten	60-09-3(Hazardous Substances Data)
Toxizität	LD50 intraperitoneal in mouse: 200mg/kg

Gefahreninformationscode (GHS)

4-AMINOAZOBENZENE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R45:Kann Krebs erzeugen.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
S-Sätze Betriebsanweisung:
S53:Exposition vermeiden - vor Gebrauch besondere Anweisungen einholen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Beschreibung
This azoic coloring can be reduced in paraphenylenediamine (PPD). It ean be found in some semipermanent hair dyes, and patch tests are frequently positive (about 30%) in hairdressers with hand dermatitis. Because of cross-sensitivity, the detection of sensitization to p-aminoazobenzene may be assumed by a PPD test.
Chemische Eigenschaften
powder
Chemische Eigenschaften
4-Aminoazobenzene forms yellow to tan crystals or orange needles.
Verwenden
as a dye for lacquer, varnish, wax products, oi! stains and styrene res ins; in insecticides; used as an intermediate in the manufacture of Acid Yellow, diazo dyes and indulines.
Verwenden
In form of its salts in dyeing; intermediate in manufacture of Acid Yellow, diazo dyes and indulines.
synthetische
commonly known as Aniline Yellow. (a) aniline?hydrochloride solution added to a aniline?diazonium salt, and slowly, until aniline?diazonium salt salt disappear so far. Then in contain a small amount of aniline?hydrochloride aniline?solution will product (Diazoaminobenzene) 30 ~ 40 ℃ heating 2 ~ 3 hours,??acidified to form 4-(Phenyldiazenyl)benzenamine??hydrochloride and crystalline precipitates. In order to obtain 4-(Phenyldiazenyl)benzenamine?times the company, and then 4-(Phenyldiazenyl)benzenamine hydrochloride dissolved in water and mercerized. (B) aniline?diazotization and coupling anilino-methanesulfonic acid, sodium hydroxide solution and then with boiled together, hydrolyzed mesylate.
Definition
ChEBI: Azobenzene substituted at one of the 4-positions by an amino group.
Allgemeine Beschreibung
Odorless brownish-yellow needles with bluish coating, or an orange powder.
Air & Water Reaktionen
Dust may form an explosive mixture in air. Insoluble in water.
Reaktivität anzeigen
4-AMINOAZOBENZENE can detonate, particularly if sensitized by the presence of metal salts or strong acids. May form toxic gases with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. May form flammable gases with alkali metals. May react explosively with strong oxidizing agents, metal salts, peroxides, and sulfides. Emits toxic fumes of oxides of nitrogen when heated to decomposition (over 350°C) [Sax, 2nd ed., 1965, p. 417].
Hazard
Possible carcinogen.
Brandgefahr
Flash point data for 4-AMINOAZOBENZENE are not available; however, 4-AMINOAZOBENZENE is probably combustible.
Kontakt-Allergie
This azoic coloring can be reduced in para-phenylenediamine (PPD). It can be found in some semi-permanent hair dyes and patch tests are frequently positive (about 30%) in hairdressers with hand dermatitis. Because of hydrolysis of the azo bond, the detection of sensitization to p-aminoazobenzene may be assumed by a PPD test.
Sicherheitsprofil
Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Poison by intraperitoneal route. An experimental teratogen. Mutation data reported. Used as a dye for lacquer, varnish, wax products, oil stains, and styrene resins. When heated to decomposition it emits toxic fumes of NOx. See also AMINES
mögliche Exposition
An azo compound used in form of salts in dyeing; used as intermediate in manufacture of acid yellow and diazo dyes; in insecticides, waxes, lacquers, varnishes, stains, styrene resins
Versand/Shipping
UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required
läuterung methode
Crystallise this dye from EtOH, CCl4, pet ether/*C6H6, or a MeOH/H2O mixture. [Beilstein 16 IV 445.]

Properties and Applications

green light yellow to red light yellow. Melting point is 127.5 ℃, its hydrochloride for blue crystal. Soluble in ethanol, slightly soluble in water for yellow. In concentrated sulfuric acid for brown, red after diluted solution; In hydrochloric acid solution for red, boil color disappear. Used for alcohol soluble paint, varnish, paraffin wax, oil, synthetic resin coloring.

Standard	Light Fastness	Heat-resistant(℃)		Water	Sodium Carbonate(5%)	Hydrochloric acid(5%)
		Melting point	Stable
ISO	Good	125	140	Good	Good	Good

Inkompatibilitäten
Dust may form explosive mixture with air. Azo compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. This chemicalis sensitive to prolonged exposure to heat. This chemical is incompatible with strong oxidizing agents

4-AMINOAZOBENZENE Upstream-Materialien And Downstream Produkte

4-Aminoazobenzol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

60-09-3, 4-AMINOAZOBENZENE Verwandte Suche:

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