865-49-6

Name	CHLOROFORM-D
CAS	865-49-6
EINECS(EC#)	212-742-4
Molecular Formula	CCl3D
MDL Number	MFCD00000827
Molecular Weight	120.38
MOL File	865-49-6.mol

Synonyms

CHLOROFORM-D CHLOROFORM-D1 DEUTEROCHLOROFORM TRICHLOROMETHANE-D Deuterotrichloromethane Trichloro(2H)methane trichloro-deuterio-methane trichlorodeutriomethane chloroform-D 99.8 atom % D*contains 1% tms Chloroformdiosotopicpurity Chloroformdisotopicpuritytetramethylsilane (2H)chloroform CHLOROFORM-D, 99.8 ATOM % D, STABILIZEDWITH 0.5 WT. % SILVER FOIL CHLOROFORM-D >99.5 % WITH 1% (V/V) TMS& CHLOROFORM-D, 99.8 ATOM % D CHLOROFORM-D+0.05% TMS (V/V) (AMGEN) CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)STABILIZED WITH 0.5 WT. % SILVER WIRE CHLOROFORM-D 99.8 ATOM% D CONTAINS 0.05% (V/V) TMS CHLOROFORM, 1000MG, NEAT CHLOROFORM-D EXTRA (MIN. 99.996 ATOM &

Chemical Properties

Appearance	colourless liquid
Melting point	−64 °C(lit.)
Boiling point	60.9 °C(lit.)
density	1.500 g/mL at 25 °C(lit.)
vapor pressure	211 hPa (20 °C)
refractive index	n20/D 1.444(lit.)
Fp	62°C
storage temp.	Store at +2°C to +8°C.
solubility	Miscible with organic solvents, ethyl acetate and acetone.
form	Liquid In Prescored Ampoules, (0.75Ml/ampoule)
color	White to beige
Specific Gravity	1.505
Stability:	Stable. Incompatible with strong bases, alkali metals, aluminium, magnesium, strong oxidizing agents.
Sensitive	Moisture Sensitive
Detection Methods	HPLC
BRN	1697633
Exposure limits	ACGIH: TWA 10 ppm OSHA: Ceiling 50 ppm(240 mg/m3) NIOSH: IDLH 500 ppm; STEL 2 ppm(9.78 mg/m3)
InChIKey	HEDRZPFGACZZDS-MICDWDOJSA-N
LogP	1.5-1.6 at 20-23℃ and pH9
Surface tension	72.3mN/m at 998.5mg/L and 20℃
CAS DataBase Reference	865-49-6(CAS DataBase Reference)
Storage Precautions	Moisture sensitive;Store under inert gas;Light sensitive
EPA Substance Registry System	Chloroform-d (865-49-6)

Safety Data

Hazard Codes	Xn,T
Risk Statements	R22:Harmful if swallowed. R38:Irritating to the skin. R40:Limited evidence of a carcinogenic effect. R48/20/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed . less more
Safety Statements	S36/37:Wear suitable protective clothing and gloves . less more
RIDADR	UN 1888 6.1/PG 3
WGK Germany	2
HazardClass	6.1
PackingGroup	III
HS Code	28459000
Toxicity	LD50 orally in Rabbit: 695 mg/kg LD50 dermal Rabbit > 3980 mg/kg less more

Raw materials And Preparation Products

Hazard Information

Questions And Answer

Water peak
The position of the water peak in different deuterated reagents is not the same. The water peak of heavy water is about 4.67 ppm. There is a trend that the more water the low field.
Chloroform-D is less soluble with water and the water content is low, so its water peak near 1.59 ppm. Deuterated acetone is about 2.8 ppm and the deuterated dimethylsulfoxide has a water peak of about 3.4 ppm. If water is added to deuterated acetone, the water peak will gradually move to a low field and eventually stop at about 4.7 ppm.;
Application
Chloroform-d has been employed as solvent in a 1H NMR (Proton Nuclear Magnetic Resonance) spectroscopic study. It has been employed as solvent during the 31PNMR (Phosphorus-31 nuclear magnetic resonance) spectral investigation of triphenyl phosphate and tris(2-chloroethyl) phosphate. It has also been used as the deuterated solvent in the 1H NMR spectral studies of 2-(4-bromobenzyl)-3-hydroxypropanoic acid and 3-hydroxy-2-(4-methoxybenzyl)propanoic acid. It has also been used as the deuterated solvent for the 1HNMR spectral studies of 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxy-phenyl) hexafluoropropane dianhydride (6FDA) polyimide.Chloroform-d has been employed as solvent in a 1H NMR (Proton Nuclear Magnetic Resonance) spectroscopic study. It has been employed as solvent during the 31PNMR (Phosphorus-31 nuclear magnetic resonance) spectral investigation of triphenyl phosphate and tris(2-chloroethyl) phosphate. It has also been used as the deuterated solvent in the 1H NMR spectral studies of 2-(4-bromobenzyl)-3-hydroxypropanoic acid and 3-hydroxy-2-(4-methoxybenzyl)propanoic acid. It has also been used as the deuterated solvent for the 1HNMR spectral studies of 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxy-phenyl) hexafluoropropane dianhydride (6FDA) polyimide.;

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Water peak

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