865-34-9

Name LITHIUM METHOXIDE
CAS 865-34-9
EINECS(EC#) 212-737-7
Molecular Formula CH3LiO
MDL Number MFCD00036357
Molecular Weight 37.97
MOL File 865-34-9.mol

Chemical Properties

Appearance white powder
Melting point  500°C
Boiling point  64.6 °C
density  0.85 g/mL at 20 °C
Fp  52 °F
storage temp.  Flammables area
solubility  Soluble in methanol.
form  powder
color  White
Specific Gravity 0.85
Stability: Stable, but reacts violently with water. Highly flammable. Store under dry inert gas.
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Sensitive  Moisture Sensitive
BRN  3552389
InChI 1S/CH3O.Li/c1-2;/h1H3;/q-1;+1
InChIKey JILPJDVXYVTZDQ-UHFFFAOYSA-N
SMILES [Li+].C[O-]
CAS DataBase Reference 865-34-9(CAS DataBase Reference)
EPA Substance Registry System Methanol, lithium salt (865-34-9)

Safety Data

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
Signal word  Danger
Hazard statements  H251-H314
Precautionary statements  P235-P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338
Hazard Codes  F,T,C
Risk Statements 
R14:Reacts violently with water.
R17:Spontaneously flammable in air.
R34:Causes burns.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R36/38:Irritating to eyes and skin .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable.
Safety Statements 
S8:Keep container dry .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
RIDADR  UN 3274 3/PG 2
WGK Germany  3
3-10-23
TSCA  Yes
REACH Registrations Active
HazardClass  4.2
PackingGroup  II
HS Code  29051990
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
Hazard Classifications Self-heat. 1
Skin Corr. 1B

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