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5292-43-3
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Chemical Properties
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Identification
Name
tert-Butyl bromoacetate
CAS
5292-43-3
Synonyms
2-BROMOACETIC ACID-TERT-BUTYL ESTER
BROMOACETIC ACID TERT-BUTYL ESTER
BUTYLBROMOACETATE-TERT
T-BUTYL 2-BROMOACETATE
T-BUTYL BROMOACETATE
TERT-BUTYL 2-BROMOACETATE
TERT-BUTYL BROMOACETATE
1-Butylbromoacetate
Acetic acid, bromo-, tert-butyl ester
aceticacid,bromo-,1,1-dimethylethylester
BrCH2C(O)OC(CH3)3
bromoacetic acid T-butyl ester
tertiary butyl bromoacetate
2-Bromoacetic acid-t-butylester
#ntert.-Butyl bromoacetate
tert-Butylbromoacetate,98%
tert-Butyl bromoacetate 98%
2-BROMOACETICACIDTERT-BUTYLESTER(TERT-BUTYLBROMOACETATE)
tert-Butyl bromoacetate, 99 %
1,1-Dimethylethyl 2-bromoacetate
EINECS(EC#)
226-133-6
Molecular Formula
C6H11BrO2
MDL Number
MFCD00000188
Molecular Weight
195.05
MOL File
5292-43-3.mol
tert-Butyl bromoacetate
CAS
5292-43-3
Synonyms
2-BROMOACETIC ACID-TERT-BUTYL ESTER
BROMOACETIC ACID TERT-BUTYL ESTER
BUTYLBROMOACETATE-TERT
T-BUTYL 2-BROMOACETATE
T-BUTYL BROMOACETATE
TERT-BUTYL 2-BROMOACETATE
TERT-BUTYL BROMOACETATE
1-Butylbromoacetate
Acetic acid, bromo-, tert-butyl ester
aceticacid,bromo-,1,1-dimethylethylester
BrCH2C(O)OC(CH3)3
bromoacetic acid T-butyl ester
tertiary butyl bromoacetate
2-Bromoacetic acid-t-butylester
#ntert.-Butyl bromoacetate
tert-Butylbromoacetate,98%
tert-Butyl bromoacetate 98%
2-BROMOACETICACIDTERT-BUTYLESTER(TERT-BUTYLBROMOACETATE)
tert-Butyl bromoacetate, 99 %
1,1-Dimethylethyl 2-bromoacetate
EINECS(EC#)
226-133-6
Molecular Formula
C6H11BrO2
MDL Number
MFCD00000188
Molecular Weight
195.05
MOL File
5292-43-3.mol
Chemical Properties
Appearance
clear colorless to yellow liquid
Melting point
44-47 °C
Boiling point
50 °C10 mm Hg(lit.)
bp
50 °C10 mm Hg(lit.)
density
1.338
refractive index
n20/D 1.445(lit.)
Fp
121 °F
storage temp.
0-6°C
form
Liquid
color
Clear colorless to yellow
Specific Gravity
1.333 (20/4℃)
Water Solubility
Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.
Sensitive
Lachrymatory
Detection Methods
GC,NMR
BRN
1753010
InChIKey
BNWCETAHAJSBFG-UHFFFAOYSA-N
CAS DataBase Reference
5292-43-3(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
EPA Substance Registry System
5292-43-3(EPA Substance)
clear colorless to yellow liquid
Melting point
44-47 °C
Boiling point
50 °C10 mm Hg(lit.)
bp
50 °C10 mm Hg(lit.)
density
1.338
refractive index
n
Fp
121 °F
storage temp.
0-6°C
form
Liquid
color
Clear colorless to yellow
Specific Gravity
1.333 (20/4℃)
Water Solubility
Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.
Sensitive
Lachrymatory
Detection Methods
GC,NMR
BRN
1753010
InChIKey
BNWCETAHAJSBFG-UHFFFAOYSA-N
CAS DataBase Reference
5292-43-3(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
EPA Substance Registry System
5292-43-3(EPA Substance)
Safety Data
Hazard Codes
Xi,F
Risk Statements
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Statements
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S24/25:Avoid contact with skin and eyes .
S16:Keep away from sources of ignition-No smoking .
RIDADR
UN 1993 3/PG 3
WGK Germany
3
F
19
Hazard Note
Irritant/Flammable/Lachrymatory
TSCA
T
HazardClass
3
PackingGroup
III
HS Code
29159080
Xi,F
Risk Statements
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Statements
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S24/25:Avoid contact with skin and eyes .
S16:Keep away from sources of ignition-No smoking .
RIDADR
UN 1993 3/PG 3
WGK Germany
3
F
19
Hazard Note
Irritant/Flammable/Lachrymatory
TSCA
T
HazardClass
3
PackingGroup
III
HS Code
29159080
Raw materials And Preparation Products
Preparation Products
(S)-4-BOC-MORPHOLINE-3-CARBOXYLIC ACID-->TERT-BUTYL 2-(N-(3-AMINOBENZYL)-N-METHYLAMINO)ACETATE-->trans-3,4-Difluorocinnamic acid-->(4-ACETYL-PIPERAZIN-1-YL)-ACETIC ACID-->MORPHOLIN-4-YL-ACETIC ACID-->DIETHYLAMINO-ACETIC ACID-->TRI-TERT-BUTYL 1 4 7 10-TETRAAZACYCLODOD
(S)-4-BOC-MORPHOLINE-3-CARBOXYLIC ACID-->TERT-BUTYL 2-(N-(3-AMINOBENZYL)-N-METHYLAMINO)ACETATE-->trans-3,4-Difluorocinnamic acid-->(4-ACETYL-PIPERAZIN-1-YL)-ACETIC ACID-->MORPHOLIN-4-YL-ACETIC ACID-->DIETHYLAMINO-ACETIC ACID-->TRI-TERT-BUTYL 1 4 7 10-TETRAAZACYCLODOD
Material Safety Data Sheet(MSDS)
Hazard Information
Chemical Properties
clear colorless to yellow liquid
Uses
tert-Butyl Bromoacetate is a halogenated t-butyl acetate commonly used as an alkylating agent. tert-Butyl Bromoacetate is used in the synthesis of collagenase inhibitors.
General Description
Purification Methods
Dissolve the ester in Et2O, wash it well with ice cold 10% aqueous K2CO3, dry it over CaCl2, filter and evaporate the Et2O, then fractionate it through a Vigreux column (p 11) in a vacuum. LACHRYMATORY. [Abramovitch et al. J Am Chem Soc 64 2274 1942, Abramovitch & Hauser J Am Chem Soc 65 986 1943, Beilstein 2 III 482.]
clear colorless to yellow liquid
Uses
tert-Butyl Bromoacetate is a halogenated t-butyl acetate commonly used as an alkylating agent. tert-Butyl Bromoacetate is used in the synthesis of collagenase inhibitors.
General Description
tert-Butyl bromoacetate serves as building blocks during the synthesis of model N-substituted oligoglycines (peptoids) containing an N-linked lactoside side-chain.
Purification Methods
Dissolve the ester in Et2O, wash it well with ice cold 10% aqueous K2CO3, dry it over CaCl2, filter and evaporate the Et2O, then fractionate it through a Vigreux column (p 11) in a vacuum. LACHRYMATORY. [Abramovitch et al. J Am Chem Soc 64 2274 1942, Abramovitch & Hauser J Am Chem Soc 65 986 1943, Beilstein 2 III 482.]
Spectrum Detail
Spectrum Detail
tert-Butyl bromoacetate(5292-43-3)MS
tert-Butyl bromoacetate(5292-43-3)1HNMR
tert-Butyl bromoacetate(5292-43-3)13CNMR
tert-Butyl bromoacetate(5292-43-3)IR1
tert-Butyl bromoacetate(5292-43-3)MS
tert-Butyl bromoacetate(5292-43-3)1HNMR
tert-Butyl bromoacetate(5292-43-3)13CNMR
tert-Butyl bromoacetate(5292-43-3)IR1
Well-known Reagent Company Product Information
Acros Organics
tert-Butyl bromoacetate, 99%(5292-43-3)
Alfa Aesar
tert-Butyl bromoacetate, 98%(5292-43-3)
Sigma Aldrich
5292-43-3(sigmaaldrich)
TCI AMERICA
tert-Butyl Bromoacetate,>98.0%(GC)(5292-43-3)
tert-Butyl bromoacetate, 99%(5292-43-3)
Alfa Aesar
tert-Butyl bromoacetate, 98%(5292-43-3)
Sigma Aldrich
5292-43-3(sigmaaldrich)
TCI AMERICA
tert-Butyl Bromoacetate,>98.0%(GC)(5292-43-3)
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