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5292-43-3

Supplier Related Products Identification Chemical Properties Safety Data Raw materials And Preparation Products Material Safety Data Sheet(MSDS) Hazard Information Spectrum Detail Well-known Reagent Company Product Information

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Identification

Name
tert-Butyl bromoacetate
CAS
5292-43-3
Synonyms
2-BROMOACETIC ACID-TERT-BUTYL ESTER
BROMOACETIC ACID TERT-BUTYL ESTER
BUTYLBROMOACETATE-TERT
T-BUTYL 2-BROMOACETATE
T-BUTYL BROMOACETATE
TERT-BUTYL 2-BROMOACETATE
TERT-BUTYL BROMOACETATE
1-Butylbromoacetate
Acetic acid, bromo-, tert-butyl ester
aceticacid,bromo-,1,1-dimethylethylester
BrCH2C(O)OC(CH3)3
bromoacetic acid T-butyl ester
tertiary butyl bromoacetate
2-Bromoacetic acid-t-butylester
#ntert.-Butyl bromoacetate
tert-Butylbromoacetate,98%
tert-Butyl bromoacetate 98%
2-BROMOACETICACIDTERT-BUTYLESTER(TERT-BUTYLBROMOACETATE)
tert-Butyl bromoacetate, 99 %
1,1-Dimethylethyl 2-bromoacetate
EINECS(EC#)
226-133-6
Molecular Formula
C6H11BrO2
MDL Number
MFCD00000188
Molecular Weight
195.05
MOL File
5292-43-3.mol

Chemical Properties

Appearance
clear colorless to yellow liquid
Melting point 
44-47 °C
Boiling point 
50 °C10 mm Hg(lit.)

bp 
50 °C10 mm Hg(lit.)

density 
1.338
refractive index 
n20/D 1.445(lit.)

Fp 
121 °F

storage temp. 
0-6°C
form 
Liquid
color 
Clear colorless to yellow
Specific Gravity
1.333 (20/4℃)
Water Solubility 
Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.
Sensitive 
Lachrymatory
Detection Methods
GC,NMR
BRN 
1753010
InChIKey
BNWCETAHAJSBFG-UHFFFAOYSA-N
CAS DataBase Reference
5292-43-3(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
EPA Substance Registry System
5292-43-3(EPA Substance)

Safety Data

Hazard Codes 
Xi,F
Risk Statements 
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S24/25:Avoid contact with skin and eyes .
S16:Keep away from sources of ignition-No smoking .
RIDADR 
UN 1993 3/PG 3

WGK Germany 
3

F 
19
Hazard Note 
Irritant/Flammable/Lachrymatory
TSCA 
T
HazardClass 
3
PackingGroup 
III
HS Code 
29159080

Raw materials And Preparation Products

Preparation Products
(S)-4-BOC-MORPHOLINE-3-CARBOXYLIC ACID-->TERT-BUTYL 2-(N-(3-AMINOBENZYL)-N-METHYLAMINO)ACETATE-->trans-3,4-Difluorocinnamic acid-->(4-ACETYL-PIPERAZIN-1-YL)-ACETIC ACID-->MORPHOLIN-4-YL-ACETIC ACID-->DIETHYLAMINO-ACETIC ACID-->TRI-TERT-BUTYL 1 4 7 10-TETRAAZACYCLODOD

Material Safety Data Sheet(MSDS)

msds information
t-Butyl 2-bromo acetate(5292-43-3).msds

Hazard Information

Chemical Properties
clear colorless to yellow liquid
Uses
tert-Butyl Bromoacetate is a halogenated t-butyl acetate commonly used as an alkylating agent. tert-Butyl Bromoacetate is used in the synthesis of collagenase inhibitors.
General Description
tert-Butyl bromoacetate serves as building blocks during the synthesis of model N-substituted oligoglycines (peptoids) containing an N-linked lactoside side-chain.

Purification Methods
Dissolve the ester in Et2O, wash it well with ice cold 10% aqueous K2CO3, dry it over CaCl2, filter and evaporate the Et2O, then fractionate it through a Vigreux column (p 11) in a vacuum. LACHRYMATORY. [Abramovitch et al. J Am Chem Soc 64 2274 1942, Abramovitch & Hauser J Am Chem Soc 65 986 1943, Beilstein 2 III 482.]

Spectrum Detail

Spectrum Detail
tert-Butyl bromoacetate(5292-43-3)MS
tert-Butyl bromoacetate(5292-43-3)1HNMR
tert-Butyl bromoacetate(5292-43-3)13CNMR
tert-Butyl bromoacetate(5292-43-3)IR1

Well-known Reagent Company Product Information

Acros Organics
tert-Butyl bromoacetate, 99%(5292-43-3)
Alfa Aesar
tert-Butyl bromoacetate, 98%(5292-43-3)
Sigma Aldrich
5292-43-3(sigmaaldrich)
TCI AMERICA
tert-Butyl Bromoacetate,>98.0%(GC)(5292-43-3)
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