ChemicalBook CAS DataBase List 3012-65-5

3012-65-5

Name	Ammonium citrate dibasic
CAS	3012-65-5
EINECS(EC#)	222-394-5
Molecular Formula	C6H14N2O7
MDL Number	MFCD00013068
Molecular Weight	226.18
MOL File	3012-65-5.mol

Synonyms

2-hydroxy-1,2,3-propanetricarboxylic acid triammonium salt AMMONIUM CITRATE AMMONIUM CITRATE, DIBASIC AMMONIUM CITRATE TRIBASIC AMMONIUM HYDROGENCITRATE CITRIC ACID AMMONIUM SALT CITRIC ACID, AMMONIUM SALT, DIBASIC CITRIC ACID, DIAMMONIUM CITRIC ACID, DIAMMONIUM, DIBASIC CITRIC ACID DIAMMONIUM SALT CITRIC ACID TRIAMMONIUM SALT DI-AMMONIUM HYDROGEN CITRATE TRI-AMMONIUM CITRATE 1,2,3-Propanetricarboxylicacid,2-hydroxy-,diammoniumsalt 2,3-propanetricarboxylicacid,2-hydroxy-diammoniumsalt ammoniummonohydrogencitrate diammoniumcitrate diammoniumcitrate(secondary) dibasicammoniumcitrate diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate

Chemical Properties

Appearance	Ammonium citrate (various forms) is a white powdery material with a slight ammonia-like odor.
Melting point	185 °C (dec.)(lit.)
Boiling point	100 °C(lit.)
bulk density	400-600kg/m3
density	1.22 g/mL at 20 °C
vapor density	1.8 (vs air)
refractive index	1.4650 (estimate)
storage temp.	Store at RT.
solubility	H₂O: 1 M at 20 °C, clear, colorless
form	Solid
color	White
Odor	Slight ammonia odor
PH	4.0-5.5 (25℃, 1M in H2O)
PH Range	5.2
Stability:	Stable.
Water Solubility	Soluble in water. Slightiy soluble in alcohol.
λmax	λ: 260 nm Amax: ≤0.05 λ: 280 nm Amax: ≤0.03
Merck	14,512
BRN	4925760
Cosmetics Ingredients Functions	BUFFERING CHELATING
Cosmetic Ingredient Review (CIR)	Ammonium citrate dibasic (3012-65-5)
InChI	1S/C6H8O7.2H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);2*1H3
InChIKey	YXVFQADLFFNVDS-UHFFFAOYSA-N
SMILES	N.N.OC(=O)CC(O)(CC(O)=O)C(O)=O \|\| N.N.OC(=O)CC(O)(CC(O)=O)C(O)=O
LogP	-2.840
Uses	Ammonium Citrate, Dibasic is a flavor enhancer and ph control agent. it is the diammonium salt of citric acid, being prepared by partially neutralizing citric acid with ammonia. it is used in nonal- coholic beverages and certain cheeses. less more
CAS DataBase Reference	3012-65-5(CAS DataBase Reference)
EPA Substance Registry System	3012-65-5(EPA Substance)

Safety Data

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319
Precautionary statements	P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes	Xi
Risk Statements	R36/37/38:Irritating to eyes, respiratory system and skin . R36/37:Irritating to eyes and respiratory system . less more
Safety Statements	S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . less more
RIDADR	UN 9087
WGK Germany	3
RTECS	GE7545000
F	8
TSCA	Yes
REACH Registrations	Active
HazardClass	9
HS Code	29212900
Storage Class	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2
Hazardous Substances Data	3012-65-5(Hazardous Substances Data)

Raw materials And Preparation Products

Hazard Information

General Description

Ammonium citrate is a white granular solid. AMMONIUM CITRATE, DIBASIC(3012-65-5) is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. AMMONIUM CITRATE, DIBASIC(3012-65-5) is used in pharmaceuticals, and in chemical analysis.

Reactivity Profile

Salts, basic, such as AMMONIUM CITRATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

Air & Water Reactions

Water soluble.

Health Hazard

Inhalation causes respiratory irritation. Ingestion causes diarrhea. Contact with eyes causes mild irritation.

Potential Exposure

It is used to make pharmaceuticals; rust-proofing compounds and plasticizers; as a food additive; stabilizing agent.

Fire Hazard

Special Hazards of Combustion Products: Toxic ammonia gas may form in fire.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Contact with strong caustics causes the release of ammonia gas.

Chemical Properties

Ammonium citrate (various forms) is a white powdery material with a slight ammonia-like odor.

Chemical Properties

white crystalline powder

Waste Disposal

May be flushed to sewer with large volumes of water.

Definition

ChEBI: A citrate salt in which two of the three carboxy groups are deprotonated and associated with ammonium ions as counter-cations.

Spectrum Detail

Well-known Reagent Company Product Information

Supplier

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