ChemicalBook CAS DataBase List 2455-24-5

2455-24-5

Name	Tetrahydrofurfuryl methacrylate
CAS	2455-24-5
EINECS(EC#)	219-529-5
Molecular Formula	C9H14O3
MDL Number	MFCD00014515
Molecular Weight	170.21
MOL File	2455-24-5.mol

Synonyms

2-METHYL-ACRYLIC ACID TETRAHYDRO-FURAN-2-YLMETHYL ESTER METHACRYLIC ACID TETRAHYDROFURFURYL ESTER (TETRAHYDRO-2-FURANYL)METHYLMETHACRYLATE TETRAHYDROFURFURYL METHACRYLATE 2-methyl-2-propenoicaci(tetrahydro-2-furanyl)methylester 2-Propenoicacid,2-methyl-,(tetrahydro-2-furanyl)methylester sartomersr203 sr203 (+/-)-TETRAHYDROFURFURYL METHACRYLATE, 9 7% METHACRYLIC ACID TETRAHYDROFURFURYL ESTER (STABILIZED WITH MEHQ) 95+% Tetrahydrofurfurylmethacrylate,96% TETRAHYDROFURFURYL-2-METHACRYLATE TETRAHYDROFURFURYLDIMETHACRYLATE Tetrahydrofurfurylmethacrylat 2-methyl-2-propenoic acid (tetrahydro-2-furanyl)methyl ester Tetrahydrofurfuryl methacrylate, 97%, stab. Methacrylic Acid Tetrahydrofurfuryl Ester (stabilized with MEHQ) Tetrahydrofuran-2-ylmethyl 2-methylprop-2-enoate 2-Methylpropenoic acid (tetrahydrofuran-2-yl)methyl ester Acryester THF

Chemical Properties

Boiling point	52 °C0.4 mm Hg(lit.)
density	1.044 g/mL at 25 °C(lit.)
vapor pressure	27Pa at 20℃
refractive index	n20/D 1.458(lit.)
Fp	195 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	clear liquid
color	Colorless to Almost colorless
Specific Gravity	1.044
Water Solubility	18.99g/L at 20℃
Sensitive	Light Sensitive
BRN	117423
Cosmetics Ingredients Functions	FILM FORMING
InChI	1S/C9H14O3/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
InChIKey	LCXXNKZQVOXMEH-UHFFFAOYSA-N
SMILES	CC(=C)C(=O)OCC1CCCO1
LogP	1.76 at 22.6℃
CAS DataBase Reference	2455-24-5(CAS DataBase Reference)
NIST Chemistry Reference	2-Propenoic acid, 2-methyl-, (tetrahydro-2-furanyl)methyl ester(2455-24-5)
EPA Substance Registry System	2455-24-5(EPA Substance)

Safety Data

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H227-H315-H319-H335
Precautionary statements	P302+P352-P305+P351+P338
Risk Statements	R10:Flammable. R36/37/38:Irritating to eyes, respiratory system and skin . less more
Safety Statements	S36:Wear suitable protective clothing . less more
RIDADR	3272
WGK Germany	1
TSCA	Yes
REACH Registrations	Active
HazardClass	3
PackingGroup	III
HS Code	29321900
Storage Class	10 - Combustible liquids
Hazardous Substances Data	2455-24-5(Hazardous Substances Data)

Hazard Information

Description

Tetrahydrofurfuryl methacrylate (THFMA) is derived from renewable resources and is obtained by chemical modification of furfural produced from hemicellulose. THFMA was used as a biobased reactive diluent that reduces the viscosity of AESO in DLP 3D printing. According to stress relaxation tests, THFMA was found to be a suitable monomer in the UV-curing of HPPA and AESO because the formed dynamic networks could rapidly undergo thermoactivated network topology rearrangements. The addition of THFMA to the resins contributed to weldability, repairability, shape memory, and reprocessability properties[2].

Chemical Properties

Colorless liquid

Uses

Tetrahydrofurfuryl methacrylate is used as methacrylic component in dental materials, such as crown and bridge products; in artificial nails.

Application

Tetrahydrofurfuryl Methacrylate (THFMA) is a clear water white to light yellow liquid. It has a 2.84 cps viscosity at 20°C. Poly(tetrahydro furfuryl methacrylate) [P(THFMA)] has been investigated as a biomaterial for encouraging articular cartilage repair because it possesses some unique characteristics with respect to its biocompatibility and behavior in water. Furthermore, its monomer was used as a tissue repair material[1].

Definition

ChEBI: Tetrahydrofurfuryl methacrylate is a member of oxolanes.

References

[1] Sang-Ha Cho, Hun-Soo Byun, Bong-Seop Lee . “Phase behavior of tetrahydrofurfuryl methacrylate and poly(tetrahydrofurfuryl methacrylate) in supercritical carbon dioxide.” Journal of CO2 Utilization 25 (2018): Pages 39-45.

Spectrum Detail

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