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  Azidoacetic acid methyl ester is widely used in the azidoclick chemistry synthesis of triazole derivatives. Some examples include the synthesis of coumarin-triazole derivatives as potential antimalarial drugs and histone deacetylase-1 (HDAC1) inhibitors containing macrocyclic triazole compounds. It can be used to synthesize various pyrrole derivatives via Knoevenagel condensation, similar to its use in the synthesis of near-infrared bispyrrole (BODIPY) donors for organic tandem solar cells. It can also be used in the hemetsberg-knittel synthesis of substituted 5-, 6-, and 7-azaindole. Highly fluorescent pyrene [2,1-b]pyrrole can be synthesized using Azidoacetic acid methyl ester as a reagent.;

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