637-81-0

Name ETHYL AZIDOACETATE
CAS 637-81-0
EINECS(EC#) 211-301-3
Molecular Formula C4H7N3O2
MDL Number MFCD00190177
Molecular Weight 129.12
MOL File 637-81-0.mol
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Chemical Properties

Boiling point  44-46°C 2mm
density  1.12g/ml
refractive index  1.4330 to 1.4370
Fp  25 °C
storage temp.  Refrigerator, under inert atmosphere
solubility  Chloroform (Sparingly), Ethyl Acetate (Slightly)
form  Oil
color  Colourless to Pale Yellow
BRN  4247209
InChI InChI=1S/C4H7N3O2/c1-2-9-4(8)3-6-7-5/h2-3H2,1H3
InChIKey HVJJYOAPXBPQQV-UHFFFAOYSA-N
SMILES C(=O)(OCC)CN=[N+]=[N-]
CAS DataBase Reference 637-81-0(CAS DataBase Reference)

Safety Data

Symbol(GHS)  Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
Signal word  Warning
Hazard statements  H315-H319-H336-H351
Precautionary statements  P201-P302+P352-P305+P351+P338-P308+P313
Hazard Codes  Xn,Xi,C
Risk Statements 
R1:Explosive when dry.
R40:Limited evidence of a carcinogenic effect.
R36/37/38:Irritating to eyes, respiratory system and skin .
R10:Flammable.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R38:Irritating to the skin.
R11:Highly Flammable.
Safety Statements 
S7:Keep container tightly closed .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S35:This material and its container must be disposed of in a safe way .
S36:Wear suitable protective clothing .
S47:Keep at temperature not exceeding ... E C (to be specified by the manufacturer) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
RIDADR  UN 1593 6.1/PG 3
WGK Germany  2
Hazard Note  Irritant/Corrosive
HS Code  2929.90.5090
HazardClass  3
PackingGroup  III
Storage Class 3 - Flammable liquids
Hazard Classifications Eye Irrit. 2
Flam. Liq. 2

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