Identification Chemical Properties Safety Data Raw materials And Preparation Products Hazard Information Material Safety Data Sheet(MSDS) Well-known Reagent Company Product Information Supplier Related Products

1191-15-7

Name Diisobutylaluminium hydride
CAS 1191-15-7
EINECS(EC#) 214-729-9
Molecular Formula C8H19Al
MDL Number MFCD00008928
Molecular Weight 142.22
MOL File 1191-15-7.mol

Chemical Properties

Appearance clear solution
Melting point  -70 °C
Boiling point  65 °C
density  1.23 g/mL at 25 °C
vapor pressure  13.3Pa at 90℃
Fp  40 °F
storage temp.  2-8°C
solubility  Miscible with organic solvents.
form  Solution
color  Clear
Specific Gravity 0.858
Water Solubility  vigorous reaction
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Sensitive  Air Sensitive/Heat Sensitive
BRN  4123663
Exposure limits ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3)
InChIKey AZWXAPCAJCYGIA-UHFFFAOYSA-N
CAS DataBase Reference 1191-15-7(CAS DataBase Reference)
NIST Chemistry Reference Diisobutylaluminum hydride(1191-15-7)
EPA Substance Registry System 1191-15-7(EPA Substance)

Safety Data

Hazard Codes  F,T,C,N
Risk Statements 
R14/15:Reacts violently with water, liberating extremely flammable gases .
R17:Spontaneously flammable in air.
R35:Causes severe burns.
R40:Limited evidence of a carcinogenic effect.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R11:Highly Flammable.
R34:Causes burns.
R19:May form explosive peroxides.
R62:Possible risk of impaired fertility.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R15:Contact with water liberates extremely flammable gases.
R14:Reacts violently with water.
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S46:If swallowed, seek medical advice immediately and show this container or label .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S29:Do not empty into drains .
S16:Keep away from sources of ignition-No smoking .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S27:Take off immediately all contaminated clothing .
RIDADR  UN 3399 4.3/PG 1
WGK Germany  2
RTECS  BD0710000
1-4.3-10
TSCA  Yes
HazardClass  4.3
PackingGroup  I
HS Code  29319090
Safety Profile
Mddly toxic by inhalation. Dangerous fire hazard; iptes spontaneously in air. To fight fire, do not use water, foam, or halogenated extinguisking agents. See also HYDRIDES and ALUMINUM COMPOUNDS.
Hazardous Substances Data 1191-15-7(Hazardous Substances Data)

Hazard Information

Material Safety Data Sheet(MSDS)

Supplier