7-OCTEN-2-OL, 2-METHYL-6-METHYLENE

Химические свойства

It is a colorless liquid with a fresh, floral, slightly lime-like odor. Due to its conjugated double bonds, it tends to polymerize; polymerization can be suppressed by adding inhibitors (e.g., antioxidants such as BHT).
Myrcenol can be prepared by treating myrcene with diethylamine to give a mixture of geranyl- and neryldiethylamine. These compounds are hydrated with a dilute acid to the corresponding hydroxydiethylamines. Deamination tomyrcenol is effected by using a palladium–phosphine–cation complex as a catalyst.
Myrcenol is used in perfumery to obtain a lifting top note in citrus and lavender compositions. It is mainly important in the production of 4-(4-hydroxy-4- methylpentyl)-3-cyclohexenecarboxaldehyde.

Использование

Myrcenol is used in perfume compositions for “lift” and freshness in floral or citrusy and “light” compositions, including soap perfumes.

Подготовка

By chlorination of Myrcene, followed by hydrolysis.

Определение

ChEBI: A monoterpenoid that is oct-7-en-2-ol substituted by a methyl group at position 2 and a methylidene group at position 6 respectively.