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Аценафталин
- английское имяACENAPHTHYLENE
- CAS №208-96-8
- CBNumberCB1665589
- ФормулаC12H8
- мольный вес152.19
- EINECS205-917-1
- номер MDLMFCD00003806
- файл Mol208-96-8.mol
Температура плавления | 78-82 °C(lit.) |
Температура кипения | 280 °C(lit.) |
плотность | 0.899 g/mL at 25 °C(lit.) |
давление пара | 6.68 at 25 °C (gas saturation-HPLC/UV spectrophotometry, Sonnefeld et al., 1983) |
показатель преломления | 1.6360 (estimate) |
Fp | 122°C |
температура хранения | room temp |
растворимость | Soluble in ethanol, ether, and benzene (U.S. EPA, 1985) |
форма | Solid |
Удельный вес | 0.899 |
цвет | Yellow |
Растворимость в воде | 3.93mg/L(25 ºC) |
БРН | 774092 |
констант закона Генри | 1.14 at 25 °C (gas stripping-UV spectrophotometry, Warner et al., 1987) |
Стабильность | Stable. Incompatible with oxidizing agents. |
ИнЧИКей | HXGDTGSAIMULJN-UHFFFAOYSA-N |
Справочник по базе данных CAS | 208-96-8(CAS DataBase Reference) |
Рейтинг продуктов питания EWG | 1 |
FDA UNII | 1Z25C36811 |
Система регистрации веществ EPA | Acenaphthylene (208-96-8) |
Коды опасности | Xn,N,F,T,Xi | |||||||||
Заявления о рисках | 22-36/37/38-67-65-50/53-38-11-39/23/24/25-23/24/25-20 | |||||||||
Заявления о безопасности | 26-36/37/39-62-61-60-45-36/37-16-7-37/39-33-25-9 | |||||||||
РИДАДР | UN 1145 3/PG 2 | |||||||||
WGK Германия | 3 | |||||||||
RTECS | AB1254000 | |||||||||
TSCA | Yes | |||||||||
кода HS | 29029090 | |||||||||
Банк данных об опасных веществах | 208-96-8(Hazardous Substances Data) | |||||||||
Токсичность | LC50 (21-d) for Folsomia fimetaria 145 mg/kg (Sverdrup et al., 2002). | |||||||||
NFPA 704: |
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рисовальное письмо(GHS)
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рисовальное письмо(GHS)
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сигнальный язык
предупреждение
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вредная бумага
H315:При попадании на кожу вызывает раздражение.
H319:При попадании в глаза вызывает выраженное раздражение.
H335:Может вызывать раздражение верхних дыхательных путей.
H302:Вредно при проглатывании.
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оператор предупредительных мер
P261:Избегать вдыхания пыли/ дыма/ газа/ тумана/ паров/ аэрозолей.
P264:После работы тщательно вымыть кожу.
P270:При использовании продукции не курить, не пить, не принимать пищу.
P301+P312:ПРИ ПРОГЛАТЫВАНИИ: Обратиться за медицинской помощью при плохом самочувствии.
P302+P352:ПРИ ПОПАДАНИИ НА КОЖУ: Промыть большим количеством воды.
P305+P351+P338:ПРИ ПОПАДАНИИ В ГЛАЗА: Осторожно промыть глаза водой в течение нескольких минут. Снять контактные линзы, если Вы ими пользуетесь и если это легко сделать. Продолжить промывание глаз.
Аценафталин химические свойства, назначение, производство
Описание
Acenaphthylene is a PAH with three aromatic rings. It is an intermediate chemical for the manufacture of dyes, soaps, pigments, pharmaceuticals, insecticides, fungicides, herbicides, plant growth hormones, naphthalic acids, naphthalic anhydride (pigments), and acenaphthylene (resins) and is used to manufacture plastics. The largest emissions of PAHs result from incomplete combustion of organic materials during industrial processes and other human activities. These include (1) processing of coal, crude oil, and natural gas, including coking, coal conversion, and petroleum refining; (2) production of carbon blacks, creosote, coal tar, and bitumen; (3) aluminium, iron, and steel production in plants and foundries; (4) heating in power plants and residences and cooking; (5) combustion of refuse; (6) motor vehicle traffic; and (7) environmental tobacco smoke.Химические свойства
Acenaphthylene is a flaky yellow crystalline powder or solid.Физические свойства
Colorless to white prisms or crystalline plates from alcohol with an odor similar to coal tar or aromatic hydrocarbons.Использование
Acenaphthylene has been used to investigate the photodimerization of acenaphthylene in micellar and hydrogel media.Определение
ChEBI: A ortho- and peri-fused tricyclic hydrocarbon that occurs in coal tar.Общее описание
Colorless crystalline solid. Insoluble in water. Used in dye synthesis, insecticides, fungicides, and in the manufacture of plastics.Реакции воздуха и воды
Insoluble in water.Профиль реактивности
Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as ACENAPHTHYLENE, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.Угроза здоровью
Acenapht hylene is i rritat i ng to t he sk i n a nd mucous membra nes of rabbits. Subc h ron ic oral doses of acenaphthylene caused adverse effects to the kidneys, liver, blood, reproductive system, and lungs of experimental animals. Prolonged period of inhalation at low doses caused pulmonary effects like bronchitis, pneumonia, and desquamation of the bronchial and alveolar epithelium in rats.Профиль безопасности
Moderately toxic by intraperitonealroute. Mutation data reported. When heated todecomposition it emits acrid smoke and irritating fumes.Возможный контакт
PAHs are compounds containing multiple benzene rings and are also called polynuclear aromatic hydrocarbons. Acenaphthylene is an aromatic hydrocarbon used in coal tar processing, as a dye intermediate; making insecticides, fungicides, plastics.Экологическая судьба
Biological. When acenaphthylene was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum, significant biodegradation with rapid adaptation was observed. At concentrations of 5 and 10 mg/L, 100 and 94% biodegradation, respectively, were observed after 7 d (Tabak et al., 1981). A Beijerinckia sp. and a mutant strain were able to cooxidize acenaphthylene to the following metabolites: acenaphthenequinone and a compound tentatively identified as 1,2-dihydroxyacenaphthylene. When acenaphthylene was incubated with a mutant strain (Beijerinckia sp. strain B8/36) one metabolite formed which was tentatively identified as cis-1,2-acenaphthenediol (Schocken and Gibson, 1984). This compound also formed when acenaphthylene was deoxygenated by a recombinant strain of Pseudomonas aeruginosa PAO1(pRE695) (Selifonov et al., 1996).Bossert and Bartha (1986) reported that acenaphthylene in a Nixon sandy loam soil (1 g/kg) completely disappeared in <4 months. They concluded volatilization was more important than biodegradation in the disappearance of acenaphthylene from soil.
Ozonation in water at 60 °C produced 1,8-naphthalene dialdehyde, 1,8- naphthalene anhydride, 1,2-epoxyacenaphthylene, 1-naphthoic acid, and 1,8-naphthaldehydic acid (Calvert and Pitts, 1966).
Перевозки
UN3143 Dye intermediates, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material, Hazard, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.Методы очистки
Dissolve acenaphthylene in warm redistilled MeOH, filter through a sintered glass funnel and cool to -78o to precipitate the material as yellow plates [Dainton et al. Trans Faraday Soc 56 1784 1960]. Alternatively it can be sublimed in vacuo. [Beilstein 5 H 625, 5 IV 2138.]Несовместимости
Keep away from ozone and strong oxidizing agents. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxidesУтилизация отходов
Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Product residues and sorbent media may be packaged in epoxy-lined drums, then destroyed by incineration, permanganate oxidation or microwave plasma treatment. The United States Environmental Protection Agency has investigated chemical precipitation for wastewater treatmentАценафталин запасные части и сырье
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