图谱信息 供应商 相关产品
网站主页CAS数据库列表 92-82-0更多图谱吩嗪(92-82-0)核磁图(13CNMR)

吩嗪

产品名称 吩嗪

CAS号92-82-0

分子式C12H8N2

分子量180.21

展开


  • Mass

    MS-NW-0113          
    phenazine
    C12H8N2             (Mass of molecular ion:    180)
    

       Source Temperature: 140 °C
       Sample Temperature:   0 °C
       Direct, 75 eV
    

          39.0       1.1
          50.0       5.6
          51.0       2.5
          52.0       1.9
          63.0       2.0
          74.0       1.2
          75.0       2.4
          76.0       4.5
          77.0       1.7
          90.0       5.1
         102.0       2.1
         103.0       1.9
         126.0       1.2
         127.0       1.4
         128.0       1.2
         129.0       1.5
         152.0       2.7
         153.0       4.1
         154.0       2.7
         179.0      19.2
         180.0     100.0
         181.0      13.7
    

90 MHz in CDCl3

parameter in cyclohexane

parameter in CDCl3

parameter in acetone-d6

400 MHz in CDCl3


  • 1H NMR 89.56 MHz
    C12 H8 N2 0.015 g : 0.5 ml CDCl3
    phenazine
    ChemicalStructure
        Assign.     Shift(ppm)
    A 8.249 B 7.834 CALCULATED BY LAOCN PROGRAM.

         Hz     ppm     Int.
    

        748.31   8.356     51
        746.88   8.340     80
        744.44   8.313    645
        741.06   8.275    786
        738.13   8.242    481
        737.38   8.234    551
        734.19   8.198   1000
        731.56   8.169    205
        730.81   8.161    171
        709.75   7.925    136
        709.00   7.917    169
        706.19   7.886   1000
        704.31   7.865     64
        703.19   7.852    511
        702.50   7.844    514
        699.56   7.812    773
        697.38   7.787     44
        696.13   7.773    658
        693.69   7.746     91
        692.31   7.731     66
    


  • 1H NMR 300 MHz
    C12 H8 N2 0.05 M in cyclohexane
    phenazine
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 8.158 D(B) 7.636 J(A,A') 0.38 J(A,B) 8.92 J(A,B') 1.43 J(A',B) 1.43 J(A',B') 8.92 J(B,B') 6.35 ANGERMAN,N.S. & DANYLUK,S.S. ORG.MAGN.RESON. 4, 895 (1972)

         Hz     ppm     Int.
    

       2455.91   8.186    104
       2455.28   8.184    119
       2452.71   8.176    879
       2449.27   8.164    767
       2445.80   8.153    744
       2442.36   8.141   1000
       2439.67   8.132    151
       2298.53   7.662    151
       2295.85   7.653   1000
       2292.41   7.641    741
       2288.94   7.630    768
       2285.50   7.618    877
       2282.92   7.610    119
       2282.29   7.608    104
    


  • 1H NMR 300 MHz
    C12 H8 N2 0.05 M in DMSO-d6
    phenazine
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 8.262 D(B) 7.971 J(A,A') 0.36 J(A,B) 8.90 J(A,B') 1.41 J(A',B) 1.41 J(A',B') 8.90 J(B,B') 6.37 ANGERMAN,N.S. & DANYLUK,S.S. ORG.MAGN.RESON. 4, 895 (1972)

         Hz     ppm     Int.
    

       2486.58   8.289    127
       2483.99   8.280    795
       2480.56   8.269    735
       2477.11   8.257    733
       2473.68   8.246   1000
       2470.83   8.236    196
       2399.07   7.997    196
       2396.23   7.987   1000
       2392.80   7.976    733
       2389.34   7.964    735
       2385.91   7.953    795
       2383.31   7.944    127
    


  • 1H NMR 300 MHz
    C12 H8 N2 0.05 M in acetone-d6
    phenazine
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 8.166 D(B) 7.695 J(A,A') 0.35 J(A,B) 8.91 J(A,B') 1.42 J(A',B) 1.42 J(A',B') 8.91 J(B,B') 6.38 ANGERMAN,N.S. & DANYLUK,S.S. ORG.MAGN.RESON. 4, 895 (1972)

         Hz     ppm     Int.
    

       2458.31   8.194    104
       2457.75   8.192    117
       2455.11   8.184    867
       2451.67   8.172    765
       2448.22   8.161    743
       2444.78   8.149   1000
       2442.02   8.140    156
       2316.29   7.721    156
       2313.52   7.712    998
       2310.09   7.700    743
       2306.63   7.689    765
       2303.19   7.677    865
       2300.56   7.669    117
       2299.99   7.667    105
    


  • 1H NMR 399.65 MHz
    C12 H8 N2 0.015 g : 0.5 ml CDCl3
    phenazine
    ChemicalStructure
        Assign.     Shift(ppm)
    A 8.256 B 7.848

         Hz     ppm     Int.
    

       3308.59   8.279     66
       3307.37   8.276    103
       3304.81   8.270    921
       3301.39   8.261    658
       3299.68   8.257    101
       3297.97   8.253    555
       3294.56   8.244    959
       3291.99   8.238    149
       3290.77   8.235    116
       3285.64   8.222     25
       3145.39   7.871     93
       3144.29   7.868    121
       3141.60   7.861    951
       3139.77   7.857     98
       3138.18   7.853    569
       3134.89   7.845    685
       3131.47   7.836   1000
       3128.91   7.830    123
       3127.69   7.827     94
       3123.90   7.817     22
    

in CDCl3



CCl4 solution



KBr disc



nujol mull





ANION RADICAL, ELECTROREDUCTION IN CH3CN

ANION RADICAL, REDUCTION WITH ALKALI METAL