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MS-NW-7587 isopilocarpine nitrate C11H16N2O2 HNO3 (Mass of molecular ion: 208)
Source Temperature: 180 °C Sample Temperature: 150 °C Direct, 75 eV
27.0 2.3 28.0 2.3 29.0 1.0 30.0 3.0 39.0 3.1 41.0 5.4 42.0 6.9 46.0 7.7 53.0 2.1 54.0 3.8 55.0 2.3 66.0 1.2 67.0 1.6 68.0 2.9 81.0 1.7 82.0 1.7 83.0 2.5 94.0 1.5 95.0 100.0 96.0 51.5 97.0 3.5 109.0 1.1 121.0 1.2 208.0 11.3 209.0 1.6
400 MHz in DMSO-d6
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1H NMR 399.65 MHz C11 H16 N2 O2 0.033 g : 0.5 ml DMSO-d6 isopilocarpine nitrate Assign. Shift(ppm)
A 9.056 B 7.590 C *1 4.410 D *1 3.902 E 3.803 F *2 3.000 G *2 2.857 J 2.698 K 2.464 L 1.623 M 0.927 J(C,D)=8.5HZ J(F,G)=-15.8HZ J(G,J)=9.4HZ J(F,J)=5.0HZ J(J,K)=9.1HZ
Hz ppm Int.
3619.23 9.057 185 3033.60 7.591 173 1770.94 4.432 84 1763.15 4.412 114 1762.24 4.410 121 1754.61 4.391 93 1567.99 3.924 97 1559.45 3.903 144 1551.21 3.882 95 1520.08 3.804 1000 1210.63 3.030 43 1205.60 3.017 47 1194.92 2.990 71 1189.88 2.978 75 1153.41 2.887 66 1143.95 2.863 82 1137.70 2.847 38 1128.08 2.823 56 1089.48 2.727 30 1083.07 2.711 33 1080.63 2.704 46 1075.44 2.691 44 1073.15 2.686 33 1071.62 2.682 34 994.57 2.489 50 988.62 2.474 98 985.57 2.467 48 982.67 2.459 56 979.61 2.452 83 973.66 2.437 41 656.28 1.643 88 654.75 1.639 78 650.33 1.628 83 648.65 1.624 135 642.85 1.609 78 641.17 1.605 97 634.00 1.587 32 378.11 0.947 269 370.64 0.928 563 363.16 0.909 244