北美黄连碱分碱

Mass

MS-NW-6981          
6-methyl-5,6,7,8-tetrahydro-1,3-dioxolo(4,5-g)isoquinolin-5-ol hydrochloride
C11H13NO3 HCl       (Mass of molecular ion:    207)

   Source Temperature: 230 °C
   Sample Temperature: 180 °C
   Direct, 75 eV

      15.0       2.8
      18.0       2.5
      27.0       1.8
      28.0       1.5
      29.0       1.1
      35.0       3.7
      36.0      23.5
      37.0       1.3
      38.0       7.2
      39.0       5.9
      40.0       1.1
      41.0       2.3
      42.0      20.9
      43.0       1.1
      50.0       3.7
      51.0       6.0
      52.0       1.8
      53.0       1.6
      62.0       3.4
      63.0       6.6
      64.0       3.0
      65.0       5.1
      65.5       4.6
      66.0       1.5
      74.0       1.2
      75.0       1.4
      76.0       1.5
      77.0       5.8
      78.0       2.2
      79.0       1.2
      80.5       1.2
      86.0       1.0
      87.0       1.5
      87.5       1.0
      88.0       2.0
      89.0      12.5
      90.0       6.6
      91.0       7.7
      92.0       1.6
      93.5       3.4
      94.0       1.1
      94.5       7.7
      95.0       2.7
     102.0       1.6
     103.0       2.8
     104.0       1.0
     105.0       1.1
     115.0       2.3
     116.0       3.5
     117.0       3.2
     118.0       2.2
     119.0       1.9
     130.0       8.0
     131.0       4.5
     132.0       4.9
     133.0       1.0
     135.0       1.2
     146.0       1.0
     147.0      27.5
     148.0     100.0
     149.0      12.8
     150.0       1.2
     159.0       1.6
     160.0       3.9
     161.0       1.9
     162.0       4.9
     163.0       1.1
     172.0       4.2
     173.0       6.8
     174.0       2.3
     175.0       3.3
     176.0       2.8
     177.0       1.6
     188.0      55.2
     189.0      17.5
     190.0      83.3
     191.0      58.2
     192.0       7.2

Assign. Shift(ppm) A 9.41 B 7.431 C 7.144 D 6.236 E 3.985 F 3.731 G 3.163

     Hz     ppm     Int.

   3759.61   9.408    121
   2970.12   7.432    376
   2855.38   7.145    257
   2492.52   6.237   1000
   1601.41   4.008     92
   1593.17   3.987    174
   1584.63   3.966    106
   1491.24   3.732    606
   1275.02   3.191    123
   1266.78   3.170    211
   1258.24   3.149    116